Boundary-layer ozone depletion as seen in the Norwegian Arctic in spring

Several years of measurements of ozone, hydrocarbons, sulphate and meteorological parameters from Spitsbergen in the Norwegian Arctic are presented. Most of the measurements were taken on the Zeppelin Mountain at an altitude of 474 m a.s.l. The focus is the episodes of ozone depletion in the lower troposphere in spring, which are studied in a climatological way. Episodes of very low ozone concentrations are a common feature on the Zeppelin Mountain in spring. The low ozone episodes were observed from late March to the beginning of June. When the effect of transport direction was subtracted, the frequenty of the low ozone episodes was found to peak in the beginning of May, possibly reflecting the seasonal cycle in the actual depletion process. Analyses based on trajectory calculations show that most of the episodes occurred when the air masses were transported from W-N. Ozone soundings show that the ozone depletion may extend from the surface and up to 3–4 km altitude. The episodes were associated with a cold boundary layer beneath a thermally stable layer, suppressing mixing with the free troposphere. The concentration of several individual hydrocarbons was much lower during episodes of low ozone than for the average conditions. The change in concentration ratio between the hydrocarbons was in qualitative agreement with oxidation of hydrocarbons by Br and Cl atoms rather than by OH radicals.     

Atmospheric concentrations of nonmethane hydrocarbons at a North European coastal site

Two years of individual nonmethane hydrocarbon (NMHC) measurements at a rural site close to the south coast of Norway show that there was a distinct annual cycle with a late winter maximum and late summer minimum in the slowly reacting NMHCs acetylene, ethane, propane and i- and n-butane. The average January—March concentrations were a factor 2–4 higher than the July-September concentrations. Also ethene, propene and the pentanes show a similar annual cycle, but the individual scatter in the measurements in particular of propene, is large. The highest concentrations of NMHC were found in winter for easterly transport on a regional scale (out to 1500 km from the site), and for southeasterly transport in the summer.     

Authigenic sericite record of a fossil geothermal system: the Offenburg trough,central Black Forest,Germany

A fossil geothermal area is hosted by the Carboniferous, Permian and Bunter sandstones of the Offenburg intramontane trough in the central Black Forest. The hydrothermal alteration is identified on the basis of newly formed sericites, which appear as pseudomorphs after feldspar and filling of pore spaces. According to K–Ar dating of sericite, serititization occurred about 145 Ma ago (Jurassic). On the basis of ¹⁸O analyses of sericite, sericite composition and vitrinite reflectance, the hydrothermal fluids had temperatures of 150–210 °C. Because their electrolyte content was low, these fluids are assumed to have derived from meteoric water. A second pulse of electrolyte-rich hydrothermal fluids resulted in quartz overgrowths. Fluid mobilization seems to be linked to the disintegration of Pangaea and to reactivated fault systems extending from the crystalline basement into the intramontane sediments.     

Rapid biotic molecular transformation of fulvic acids in a karst aquifer

The study of molecular transformation processes of dissolved organic carbon (DOC) in the environment significantly contributes to a better understanding of the global biogeochemical organic matter cycle. In an oxic karst groundwater system, in which the most powerful abiotic DOC degradative reactions, photodegradation and metal-mediated redox chemistry, are at best marginal contributors, a near complete turnover of fulvic acids (FAs) has been observed within decades (∼60 years). Depletion of oxygen for a very extensive range of aliphatic and aromatic carbon chemical environments has been confirmed as well as the formation of novel classes of compounds, suggesting a major contribution from biotic processes. From these results we infer that FAs must be perceived as a rather active participant in the global carbon cycle. Molecular-level alterations of such magnitude and rapidity on such short-time scales ought to be considered as widespread in the processing of “refractory” DOC in the environment.     

Thermal conductivity measurements of road construction materials in frozen and unfrozen state

A series of thermal conductivity measurements for various materials was performed in a large climate chamber. The size of the chamber allowed the preparation of relatively large samples in a controlled thermal environment. Three types of thermal sensors were used: (1) two needle probes; (2) a grid of temperature sensors, evenly distributed inside the sample; (3) two additional thermal probes, which were simplified versions of an instrument originally developed for measuring thermal properties of the ice/dust mixture expected to exist at the surface of a comet nucleus. They consist of a series of individual temperature sensors integrated into a glass fibre rod. Each of these sensors can be operated in an active (heated) or passive (only temperature sensing) mode. The following sample materials were used: fine-grained reddish sand, coarse-grained moist sand, gravels with various grain size distributions from < 1 cm up to about 6 cm, and for comparison and calibration pure water (with convection suppressed by adding agar-agar), compact ice, and compact granite. Of particular interest are the measurements with composite samples, like stones embedded in an agar-agar matrix. We describe the evaluation methods and present the results of the thermal conductivity measurements.     

TL age-estimates for the Middle Palaeolithic layers at Theopetra cave (Greece)

The lowest stratigraphic unit of Theopetra cave (Greece) contains a Middle Palaeolithic sequence radiocarbon dated to between 46 and 35 ka BP; at the limit of this dating method. The upper part of this sequence has yielded late Middle Palaeolithic lithic assemblages containing several early Upper Palaeolithic artifacts. To get more precise dates for the human occupation of the cave, burnt flint specimens from these Middle Palaeolithic layers were dated by thermoluminescence. The dates obtained are coherent and indicate that the first human occupation of the cave took place at the end of isotopic stage 6 or more probably at the beginning of stage 5, much earlier than previously proposed. In the light of this new evidence, it is reasonable to assume that: (a) Theopetra contains the oldest dated Middle Palaeolithic deposits of Greece and (b) that the assemblages first interpreted as “Transitional Middle/Upper Palaeolithic” industries may be the result of post-depositional mixing of cultural material.     

Spatio-temporal changes in the abundance of the populations of the gastrotrich community in a shallow lake of tropical Africa

Studies on the biodiversity and population dynamics of freshwater planktonic Gastrotricha have been carried out in conjunction with a physical–chemical analysis of the water in the Yaounde Municipal Lake (Cameroon, Central Africa) over a 14 months period (November 1996–December 1997). The results obtained allow to consider the Yaounde Municipal Lake as an eutrophic lake. It harbours eight species of Gastrotricha belonging to four genera (Chaetonotus, Dasydytes, Neogossea and Polymerurus) of the order Chaetonotida. This community was characterized by high abundances of populations, and was dominated by the genus Neogossea and Chaetonotusreaching up to 2000 ind. L⁻¹. Polymerurus was mostly abundant at the almost anoxic bottom layers. The highest abundances were found mostly during the rainy season, when there is an important sedimentation process of organic matter, and were influenced by several different environmental factors such as dissolved oxygen, temperature and pH of the water.

Finally this community which may play an important role in the water bodies, is a potential water quality indicator.     

Does variable channel morphology lead to dynamic salmon habitat?

Stream channel morphology forms the template upon which hydraulic aspects of aquatic habitat are created, yet spatial and temporal variability in habitat imposed by changing morphology is not well understood. This paper presents a conceptual model linking sediment supply patterns to spatial and temporal variability in channel form and aquatic habitat. To evaluate this model, change over time in three habitat variables is quantified using a 2D hydrodynamic modeling approach. A 45-year record of topographic data from Carnation Creek, a catchment in coastal British Columbia, is used for the flow modeling. Using the Nays2DH modeling platform, water depths and velocities are simulated in eight channel segments located at different positions relative to locations of historical colluvial input using seven flow levels ranging from 3% to 400% of mean annual discharge (0.02 to 3.31 m s ). Results indicate that habitat availability changes through time as a result of sediment supply-driven changes to channel morphology and wood loads, but patterns in habitat vary as a function of dominant channel segment morphology. Spatial and temporal variability in morphology also influences the relationship between habitat availability and river discharge, leading to non-stationary habitat-discharge rating curves. When habitat areas are predicted by applying these curves to daily flow series spanning annual dry seasons, over 50% of the variance in cumulative seasonal habitat area can be explained by year-to-year changes in channel morphology and wood loading, indicating that changing morphology is an important factor for driving temporal habitat variability. This variance is related to the morphological variability of a channel segment, which in turn is associated with the segment position relative to zones of colluvial input. Collectively, these results suggest that variability in habitat is impacted by channel morphology, and can be evaluated partly on the basis of a channel's sediment supply regime. © 2019 John Wiley & Sons, Ltd.     

A timing formula for main-sequence star binary pulsars

In binary radio pulsars with a main-sequence star companion, the spin-induced quadrupole moment of the companion gives rise to a precession of the binary orbit. As a first approximation one can model the secular evolution caused by this classical spin-orbit coupling by linear-in-time changes of the longitude of periastron and the projected semi-major axis of the pulsar orbit. This simple representation of the precession of the orbit neglects two important aspects of the orbital dynamics of a binary pulsar with an oblate companion. First, the quasiperiodic effects along the orbit, owing to the anisotropic 1/ r ³ nature of the quadrupole potential. Secondly, the long-term secular evolution of the binary orbit, which leads to an evolution of the longitude of periastron and the projected semi-major axis, which is non-linear in time.   In this paper a simple timing formula for binary radio pulsars with a main-sequence star companion is presented which models the short-term secular and most of the short-term periodic effects caused by the classical spin-orbit coupling. I also give extensions of the timing formula that account for long-term secular changes in the binary pulsar motion. It is shown that the short-term periodic effects are important for the timing observations of the binary pulsar PSR B1259–63. The long-term secular effects are likely to become important in the next few years of timing observations of the binary pulsar PSR J0045–7319. They could help to restrict or even determine the moments of inertia of the companion star and thus probe its internal structure.   Finally, I reinvestigate the spin-orbit precession of the binary pulsar PSR J0045–7319 since the analysis given in the literature is based on an incorrect expression for the precession of the longitude of periastron. A lower limit of 20° for the inclination of the B star with respect to the orbital plane is derived.