Seasonal Changes in Mayfly Communities and Abundance in Relation to Water Physicochemistry in Two Rivers at Different Elevations in Northern Peninsular Malaysia

A field study was performed at rivers in Gunung Jerai forest reserve(Kedah,Malaysia) to assess seasonal changes in mayfly community structure and abundance in relation to altitude and water physicochemistry.Rivers at lower(Batu Hampar River) and higher(Teroi River) elevations were visited through dry and wet seasons in September 2007 to August 2008.Monthly visits were made to 20 sites on each river,and water and aquatic insects were sampled using D-pond aquatic nets.Water was warmer,more acid,and more turbid in Teroi River during wet season.Ammonia was the only nutrient exhibiting significant seasonal variations(greater during wet season).Chemical oxygen demand content was higher in Teroi River where biochemical oxygen demand content was low during wet season.Species richness was higher in Batu Hampar River,but displayed seasonal variations only in Teroi River.Among the eight families encountered,Baetidae was the commonest.Baetid abundance was usually high during wet season,and those belonging to the dominant genus(Baetis) were more abundant in Teroi River.Heptageniidae was the second commonest family;its predominant genus,Thalerospyrus was more abundant in Teroi River during dry season.Caenidae,Leptophlebiidae and Oligoneuriidae were only found in Batu Hampar River where their abundances peaked during dry season,i.e.,Habrophlebiodes sp.and Isonychia sp.Ephemerellidae and Teloganodidae occurred only in Teroi River,with the first found only during dry season.Mayflies were recorded under very distinct physicochemical conditions,illustrating their potential usefulness for assessing water quality.Caenids,leptophlebids,oligoneurids ephemerellids and teloganodids seem to be particularly sensitive to temperature,acidity,turbidity,chemical oxygen demand and biochemical oxygen demand,parameters that varied with river altitude.     

Separation of Vanillin from Oil Palm Empty Fruit Bunch Lignin

The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (¹³C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.     

How effective is the new generation of GPM satellite precipitation in characterizing the rainfall variability over Malaysia?

We investigated the potential of the new generation of satellite precipitation product from the Global Precipitation Mission (GPM) to characterize the rainfall in Malaysia. Most satellite precipitation products have limited ability to precisely characterize the high dynamic rainfall variation that occurred at both time and scale in this humid tropical region due to the coarse grid size to meet the physical condition of the smaller land size, sub-continent and islands. Prior to the status quo, an improved satellite precipitation was required to accurately measure the rainfall and its distribution. Subsequently, the newly released of GPM precipitation product at half-hourly and 0.1° resolution served an opportunity to anticipate the aforementioned conflict. Nevertheless, related evidence was not found and therefore, this study made an initiative to fill the gap. A total of 843 rain gauges over east (Borneo) and west Malaysia (Peninsular) were used to evaluate the rainfall the GPM rainfall data. The assessment covered all critical rainy seasons which associated with Asian Monsoon including northeast (Nov. - Feb.), southwest (May - Aug.) and their subsequent inter-monsoon period (Mar. - Apr. & Sep. - Oct.). The ability of GPM to provide quantitative rainfall estimates and qualitative spatial rainfall patterns were analysed. Our results showed that the GPM had good capacity to depict the spatial rainfall patterns in less heterogeneous rainfall patterns (Spearman’s correlation, 0.591 to 0.891) compared to the clustered one (r = 0.368 to 0.721). Rainfall intensity and spatial heterogeneity that is largely driven by seasonal monsoon has significant influence on GPM ability to resolve local rainfall patterns. In quantitative rainfall estimation, large errors can be primarily associated with the rainfall intensity increment. 77% of the error variation can be explained through rainfall intensity particularly the high intensity (> 35 mm d^-1). A strong relationship between GPM rainfall and error was found from heavy (~35 mm d^-1) to violent rain (160 mm d^-1). The output of this study provides reference regarding the performance of GPM data for respective hydrology studies in this region.     

Downscaling and projection of precipitation from general circulation model predictors in an equatorial climate region by the automated regression-based statistical method

The authors have applied an automated regression-based statistical method, namely, the automated statistical downscaling (ASD) model, to downscale and project the precipitation climatology in an equatorial climate region (Peninsular Malaysia). Five precipitation indices are, principally, downscaled and projected: mean monthly values of precipitation (Mean), standard deviation (STD), 90th percentile of rain day amount, percentage of wet days (Wet-day), and maximum number of consecutive dry days (CDD). The predictors, National Centers for Environmental Prediction (NCEP) products, are taken from the daily series reanalysis data, while the global climate model (GCM) outputs are from the Hadley Centre Coupled Model, version 3 (HadCM3) in A2/B2 emission scenarios and Third-Generation Coupled Global Climate Model (CGCM3) in A2 emission scenario. Meanwhile, the predictand data are taken from the arithmetically averaged rain gauge information and used as a baseline data for the evaluation. The results reveal, from the calibration and validation periods spanning a period of 40 years (1961–2000), the ASD model is capable to downscale the precipitation with reasonable accuracy. Overall, during the validation period, the model simulations with the NCEP predictors produce mean monthly precipitation of 6.18–6.20 mm/day (root mean squared error 0.78 and 0.82 mm/day), interpolated, respectively, on HadCM3 and CGCM3 grids, in contrast to 6.00 mm/day as observation. Nevertheless, the model suffers to perform reasonably well at the time of extreme precipitation and summer time, more specifically to generate the CDD and STD indices. The future projections of precipitation (2011–2099) exhibit that there would be an increase in the precipitation amount and frequency in most of the months. Taking the 1961–2000 timeline as the base period, overall, the annual mean precipitation would indicate a surplus projection by nearly 14~18 % under both GCM output cases (HadCM3 A2/B2 scenarios and CGCM3 A2 scenario). According to the model simulation, the September–November periods might be the more significant months projecting the increment of the precipitation amount around over 50 %, while the precipitation deficit would be seen in March–May periods.     

Changes to the Surface Level Solar Ultraviolet-B Radiation Due to Haze Perturbation

The South-East Asian region experienced a haze episode in 1994 which was widely believed to be due to widespread forest fires in Sumatra and Kalimantan (Indonesia). Broadband measurements of the surface level solar ultraviolet-B, UV-A and Global radiation at Penang (Malaysia) are used to study the effect of the 1994 haze on effective UV-B irradiance. We find that during the haze episode, there is enhanced absorption of surface level UV-B radiation. The effect of haze on UV-A and Global radiation is much less. The reduction in absolute noon time UV-B irradiance (mostly cloud free) during the 1994 haze period was 23% relative to the UV-B irradiance during thecorresponding haze-free period in 1995. Even though the noon time radiation data minimizes the cloud effect in the results presented some cloud effect is still present.     

Study of isotopic seasonality to assess the water source of proglacial stream in Chhota Shigri Glaciated Basin,Western Himalaya

The impact of surface melt patterns and the Indian summer monsoon (ISM) is examined on the varying contributions of end member (snow, glacier ice, and rain) to proglacial streamflow during the ablation period (June–October) in the Chhota Shigri glaciated basin, Western Himalaya. Isotopic seasonality observed in the catchment precipitation was generally reflected in surface runoff (supraglacial melt and proglacial stream) and shows a shift in major water source during the melt season. Isotopically correlated (δ¹⁸O–δD) high deuterium intercept in the surface runoff suggests that westerly precipitation acts as the dominant source, augmenting the other snow- and ice-melt sources in the region. The endmember contributions to the proglacial stream were quantified using a three-component mixing. Overall, glacier ice melt is the major source of proglacial discharge. Snowmelt is the predominant source during the early ablation season (June) and the peak ISM period (August and September), whereas ice melt reaches a maximum in the peak melt period (July). The monthly contribution of rain is on the lower side and shows a steady rise and decline with onset and retreat of the monsoon. These results are persistent with the surface melt pattern observed in Chhota Shigri glacier, Upper Chandra basin. Moreover, the role of the ISM in Chhota Shigri glacier is unvarying to that observed in other glacierized catchments of Upper Ganga basin. Thus, this study augments the significant role of the ISM in glacier mass balance up to the boundary of the central-western Himalayan glaciated region.     

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.     

Quantifying deformation in North Borneo with GPS

The existence of intra-plate deformation of the Sundaland platelet along its eastern edge in North Borneo, South-East Asia, makes it an interesting area that still is relatively understudied. In addition, the motion of the coastal area of North-West Borneo is directed toward a frontal fold-and-thrust belt and has been fueling a long debate on the possible geophysical sources behind it. At present this fold-and-thrust belt is not generating significant seismic activity and may also not be entirely active due to a decreasing shelfal extension from south to north. Two sets of Global Positioning System (GPS) data have been used in this study; the first covering a time period from 1999 until 2004 (ending just before the Giant Sumatra–Andaman earthquake) to determine the continuous Sundaland tectonic plate motion, and the second from 2009 until 2011 to investigate the current deformations of North Borneo. Both absolute and relative positioning methods were carried out to investigate horizontal and vertical displacements. Analysis of the GPS results indicates a clear trend of extension along coastal regions of Sarawak and Brunei in North Borneo. On the contrary strain rate tensors in Sabah reveal that only insignificant and inconsistent extension and compression occurs throughout North-West Borneo. Moreover, station velocities and rotation rate tensors on the northern part of North Borneo suggest a clockwise (micro-block) rotation. The first analysis of vertical displacements recorded by GPS in North-West Borneo points to low subsidence rates along the western coastal regions of Sabah and inconsistent trends between the Crocker and Trusmadi mountain ranges. These results have not been able to either confirm or reject the hypothesis that gravity sliding is the main driving force behind the local motions in North Borneo. The ongoing Sundaland–Philippine Sea plate convergence may also still play an active role in the present-day deformation (crustal shortening) in North Borneo and the possible clockwise rotation of the northern part of North Borneo as a micro-block. However, more observations need to be collected to determine if the northern part of North Borneo indeed is (slowly) moving independently.