Structure and chemistry of (111) twin boundaries in MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript> spinel crystals from Mogok

The atomic scale structure and chemistry of (111) twins in MgAl₂O₄ spinel crystals from the Pinpyit locality near Mogok (Myanmar, formerly Burma) were analysed using complementary methods of transmission electron microscopy (TEM). To obtain a three-dimensional information on the atomic structure, the twin boundaries were investigated in crystallographic projections and Using conventional electron diffraction and high-resolution TEM (HRTEM) analysis we have shown that (111) twins in spinel can be crystallographically described by 180° rotation of the oxygen sublattice normal to the twin composition plane. This operation generates a local hcp stacking in otherwise ccp lattice and maintains a regular sequence of kagome and mixed layers. In addition to rotation, no other translations are present in (111) twins in these spinel crystals. Chemical analysis of the twin boundary was performed by energy-dispersive X-ray spectroscopy (EDS) using a variable beam diameter (VBD) technique, which is perfectly suited for analysing chemical composition of twin boundaries on a sub-nm scale. The VBD/EDS measurements indicated that (111) twin boundary in spinel is Mg-deficient. Quantitative analyses of HRTEM (phase contrast) and HAADF-STEM (Z-contrast) images of (111) twin boundary have confirmed that Mg²⁺ ions are replaced with Be²⁺ ions in boundary tetrahedral sites. The Be-rich twin boundary structure is closely related to BeAl₂O₄ (chrysoberyl) and BeMg₃Al₈O₁₆ (taaffeite) group of intermediate polysomatic minerals. Based on these results, we conclude that the formation of (111) twins in spinel is a preparatory stage of polytype/polysome formation (taaffeite) and is a result of thermodynamically favourable formation of hcp stacking due to Be incorporation on the {111} planes of the spinel structure in the nucleation stage of crystal growth. The twin structure grows as long as the surrounding geochemical conditions allow its formation. The incorporation of Be induces a 2D-anisotropy and exaggerated growth of the crystal along the (111) twin boundary.     

Lessons Learned from the 2011 Great East Japan Tsunami: Performance of Tsunami Countermeasures, Coastal Buildings, and Tsunami Evacuation in Japan

In 2011, Japan was hit by a tsunami that was generated by the greatest earthquake in its history. The first tsunami warning was announced 3 min after the earthquake, as is normal, but failed to estimate the actual tsunami height. Most of the structural countermeasures were not designed for the huge tsunami that was generated by the magnitude M = 9.0 earthquake; as a result, many were destroyed and did not stop the tsunami. These structures included breakwaters, seawalls, water gates, and control forests. In this paper we discuss the performance of these countermeasures, and the mechanisms by which they were damaged; we also discuss damage to residential houses, commercial and public buildings, and evacuation buildings. Some topics regarding tsunami awareness and mitigation are discussed. The failures of structural defenses are a reminder that structural (hard) measures alone were not sufficient to protect people and buildings from a major disaster such as this. These defenses might be able to reduce the impact but should be designed so that they can survive even if the tsunami flows over them. Coastal residents should also understand the function and limit of the hard measures. For this purpose, non-structural (soft) measures, for example experience and awareness, are very important for promoting rapid evacuation in the event of a tsunami. An adequate communication system for tsunami warning messages and more evacuation shelters with evacuation routes in good condition might support a safe evacuation process. The combination of both hard and soft measures is very important for reducing the loss caused by a major tsunami. This tsunami has taught us that natural disasters can occur repeatedly and that their scale is sometimes larger than expected.     

Possible variation in methane flux caused by gas hydrate formation on the northeastern continental slope off Sakhalin Island, Russia

The Sakhalin Slope Gas Hydrate Project (SSGH) is an international collaborative effort by scientists from Japan, Korea, and Russia to investigate natural gas hydrates (GHs) that have accumulated on the continental slope off Sakhalin Island, Okhotsk Sea. From 2009 to 2011, field operations of the SSGH-09, -10, and -11 projects were conducted. GH-bearing and -free sediment cores were retrieved using steel hydro- and gravity corers. The concentrations of sulfate ions in sediment pore waters were measured to investigate sulfate concentration–depth profiles. Seventeen cores showed linear depth profiles of sulfate concentrations. In contrast, eight cores and two cores showed concave-up and -down profiles plausibly explained by sudden increase and decrease in methane flux from below, respectively, presumably caused by the formation of gas hydrate adjacent to the core sampling sites.     

Estimation of Sediment Properties during Benthic Impact Experiments

Sediment properties, such as water content and density, have been used to estimate the dry and wet weights, as well as the volume of sediment recovered and discharged, during benthic impact experiments conducted in the Pacific and Indian Oceans. The estimates show that the weights of dry (355-1332 t) and wet sediment (1651-4888 t) recovered during the experiments, are not only a function of the total duration and distance covered during the experiment, but also depend on water content and density of the sediment. Estimation of dry sediment and its volumetric ratio in the discharge, are key parameters for calculating the discharged volume. The estimated volume of wet sediment recovered (1427-4049 m 3 ) as well as discharged (2693-6951 m 3 ) during the experiments, provide important inputs to evaluate the sediment resettlement and migration. Using these estimates, the average depth of excavation on the seafloor, can also been calculated. However, the stages of sediment recovery and discharge are expressed differently in some of the experiments. In order to standardize these, different stages have been identified, and definitions of certain terms have been suggested, for use in the future. The methods of calculating different properties, as well as weight and volume of discharged sediment are described in the paper for use in other applications concerning deep-sea discharges.     

Seismic response control using electromagnetic inertial mass dampers

This paper presents a new type of electromagnetic damper with rotating inertial mass that has been developed to control the vibrations of structures subjected to earthquakes. The electromagnetic inertial mass damper (EIMD) consists of a ball screw that converts axial oscillation of the rod end into rotational motion of the internal flywheel and an electric generator that is turned by the rotation of the inner rod. The EIMD is able to generate a large inertial force created by the rotating flywheel and a variable damping force developed by the electric generator. Device performance tests of reduced‐scale and full‐scale EIMDs were undertaken to verify the basic characteristics of the damper and the validity of the derived theoretical formulae. Shaking table tests of a three‐story structure with EIMDs and earthquake response analyses of a building with EIMDs were conducted to demonstrate the seismic response control performance of the EIMD. The EIMD is able to reduce story drifts as well as accelerations and surpasses conventional types of dampers in reducing acceleration responses. Copyright © 2013 John Wiley & Sons, Ltd.     

Migration of a volcanic front inferred from K–Ar ages of late Miocene to Pliocene volcanic rocks in central Japan

K–Ar ages have been determined for 14 late Miocene to Pliocene volcanic rocks in the north of the Kanto Mountains, Japan, for tracking the location of the volcanic front through the time. These samples were collected from volcanoes located behind the trench–trench–trench (TTT) triple junction of the Pacific, Philippine Sea, and North American plates. This junction is the site of subduction of slabs of the Pacific and the Philippine Sea plates, both of which are thought to have influenced magmatism in this region. The stratigraphy and K–Ar ages of volcanic rocks in the study area indicate that volcanism occurred between the late Miocene and the Pliocene, and ceased before the Pleistocene. Volcanism in adjacent areas of the southern NE Japan and northern Izu–Bonin arcs also occurred during the Pliocene and ceased at around 3 Ma with the westward migration of the volcanic front, as reported previously. Combining our new age data with the existing data shows that before 3 Ma the volcanic front around the TTT junction was located about 50 km east of the preset‐day volcanic front. We suggest that northward subduction of the Philippine Sea Plate slab ended at ～3 Ma as a result of collision between the northern margin of the plate with the surface of the Pacific Plate slab. This collision may have caused a change in the subduction vector of the Philippine Sea Plate from the original north‐directed subduction to the present‐day northwest‐directed subduction. This indicates that the post ～3 Ma westward migration of the volcanic front was a result of this change in plate motion.     

Assessing flood disaster impacts in agriculture under climate change in the river basins of Southeast Asia

Natural Hazards - This study focused on flood damage assessment for future floods under the impact of climate change. Four river basins of Southeast Asia were selected for the study. They included...     

Phreatomagmatic eruptions associated with the caldera collapse during the Miyakejima 2000 eruption,Japan

The 2000 AD eruption of Miyakejima was characterized by a series of phreatomagmatic eruptions from the subsiding caldera. Six major eruptive events occurred, and they can be divided into the first and second periods separated by a 25-day hiatus. The phreatomagmatic eruptions produced a total of ~ 2 × 10¹⁰ kg of tephra, which mainly comprised fine-grained volcanic ash. The tephra layers could be divided into six fall units corresponding to the six major eruptive events.     

Metallicity Distributions of Elliptical Galaxies and Globular Cluster Systems

Gradients of absorption line indices are studied and mean stellar metallicities are estimated for 46 elliptical galaxies. The mean stellar metallicities range from 〈 [Fe/H] 〉 ≃ =0.8 to +0.2 and ellipticals with smaller central velocity dispersions tend to have lower 〈 [Fe/H] 〉 thus the mass-metallicity relation holds not only for the galaxy center but also for the whole part of the galaxy. There is an evidence that the magnesium is enhanced systematically in all ellipticals by 0.2 dex with respect to the iron. Giant elliptical galaxies show lack of metal-poor stars (the G-dwarf problem). Metal-poor globular clusters of ellipticals formed well in advance of the formation of metal-rich ones which formed simultaneously with the bulk of stars of mother galaxies under the influence of galaxy chemical enrichment. The bimodal [Fe/H] distribution of globular clusters does not necessarily mean that elliptical galaxies formed by the mergers of disc galaxies. This revised version was published online in July 2006 with corrections to the Cover Date.     

Correlation study between suspended particulate matter and DOAS data

Continuous data of aerosol optical thickness monitored using differential optical absorption spectroscopy (DOAS) are correlated with the concentration of ground-measured suspended particulate matter (SPM). A high correlation is found between the DOAS and the ground SPM data, making it possible to calculate the mass extinction efficiency of the aerosols in the atmosphere. It is found that the value of mean mass extinction efficiency (MEE) varies over a range of 2.6–13.7m2 g?1, with smaller and larger values occurring for size distributions dominated by coarse and fine particles, respectively.