The diagenesis of the late Dinantian Derbyshire-East Midland carbonate shelf, central England

Carbonate cements in late Dinantian (Asbian and Brigantian) limestones of the Derbyshire carbonate platform record a diagenetic history starting with early vadose meteoric cementation and finishing with burial and localized mineral and oil emplacement. The sequence is documented using cement petrography, cathodoluminescence, trace element geochemistry and C and O isotopes. The earliest cements (Pre-Zone 1) are locally developed non-luminescent brown sparry calcite below intrastratal palaeokarsts and calcretes. They contain negligible Fe, Mn and Sr but up to 1000 ppm Mg. Their isotopic compositions centre around δ¹⁸O =?8.5‰, δ¹³C=?5.0‰. Calcretes contain less ¹³C. Subsequent cements are widespread as inclusion-free, low-Mg, low-Fe crinoid overgrowths and are described as having a‘dead-bright-dull’cathodoluminescence. The‘dead’cements (Zone 1) are mostly non-luminescent but contain dissolution hiatuses overlain by finely detailed bright subzones that correlate over several kilometres. Across‘dead'/bright subzones there is a clear trend in Mg (500–900 ppm), Mn (100–450 ppm) and Fe (80-230 ppm). Zone 1 cements have isotopic compositions centred around δ¹⁸O =?8.0‰ and δ¹³C=?2.5‰. Zone 2 cement is bright, thin and complexly subzoned. It is geochemically similar to bright subzones of Zone 1 cements. Dull Zone 3 cement pre-dates pressure dissolution and fills 70% or more of the pore space. It generally contains little Mn, Fe and Sr but can have more than 1000 ppm Mg, increasing stratigraphically upwards. The δ¹⁸O compositions range from ?5.5 to ?15‰ and the δ¹³C range is ?1 to + 3.2^0/00. Zone 4 fills veins and stylolite seams in addition to pores. It is synchronous with Pb, Ba, F ore mineralization and oil migration. Zone 4 is ferroan with around 500 ppm Fe, up to 2500 ppm Mg and up to 1500 ppm Mn. Isotopic compositions range widely; δ¹⁵O =?2.7 to ?9‰ and δ¹³C=?3.8 to+2.50‰. Unaltered marine brachiopods suggest a Dinantian seawater composition around δ¹⁵O = 0‰ (SMOW), but vital isotopic effects probably mask the original δ¹³C (PDB) value. Pre-Zone 1 calcites are meteoric vadose cements with light soil-derived δ¹³C and light meteoric δ¹⁸O. An unusually fractionated‘pluvial’δ¹⁵O(SMOW) value of around — 6‰ is indicated for local Dinantian meteoric water. Calcrete δ¹⁸O values are heavier through evaporation. Zone 1 textures and geochemistry indicate a meteoric phreatic environment. Fe and Mn trends in the bright subzones indicate stagnation, and precipitation occurred in increments from widespread cyclically developed shallow meteoric water bodies. Meteoric alteration of the rock body was pervasive by the end of Zone 1 with a general resetting of isotopic values. Zone 3 is volumetrically important and external sources of water and carbonate are required. Emplacement was during the Namurian-early Westphalian by meteoric water sourced at a karst landscape on the uplifted eastern edge of the Derbyshire-East Midland shelf. The light δ¹⁸O values mainly reflect burial temperatures and an unusually high local heat flow, but an input of highly fractionated hinterland-derived meteoric water at the unconformity is also likely. Relatively heavy δ¹³C values reflect the less-altered state of the source carbonate and aquifer. Zone 4 is partly vein fed and spans burial down to 2000 m and the onset of tectonism. Light organic-matter-derived δ¹³C and heavy δ¹⁸O values suggest basin-derived formation water. Combined with textural evidence of geopressures, this relates to local high-temperature ore mineralization and oil migration. Low water-to-rock ratios with host-rock buffering probably affected the final isotopic compositions of Zone 4, masking extremes both of temperature and organic-matter-derived CO₂.     

Tidal inlet sequence, Sundance Formation (Upper Jurassic), north-central Wyoming

The sandstones and coquinas of the upper 20 m of the Sundance Formation are interpreted as a tidal inlet, back-barrier shoal and sandy tidal-flat sequence deposited at the close of marine Jurassic sedimentation in north-central Wyoming. The barrier strandline maintained a generally E-W trend as it prograded to the north. The lateral migration of inter-barrier tidal inlets along the regressive shoreline of the late Sundance sea caused the coquinas and sandstones of the uppermost Sundance Formation to be deposited as tabular, laterally-extensive units. Tidal bundles, sigmoidal reactivation surfaces, herringbone cross-lamination and abundant mud drapes within the sandstones are evidence of considerable tidal influence during the deposition of the uppermost Sundance Formation. Earlier models, which attach an offshore environment of deposition to the sequence, do not explain the tabular geometries of the sandstone and coquina units and their conformable stratigraphic relationship with the overlying non-marine sediments of the Morrison Formation.     

Melt Extraction during Formation of K-Feldspar + Sillimanite Migmatites, West of Revelstoke, British Columbia

An exposure of sillimanite-rich, strongly deformed, stromatic,K-feldspar-bearing migmatites in the Monashee Terrane west ofRevelstoke, British Columbia, has been examined to determinethe process of migmatization and to evaluate whether the systemwas open or closed during leucosome formation. An anatecticorigin for the migmatites is supported by: (1) the minimum meltcomposition of the leucosomes; (2) textures suggesting a fluidbehavior of the leucosomes and local pegmatitic textures; and(3) P–T estimates (720–820C; 75–9 kbar)above vaporabsent melting conditions of muscovitt + quartz. To establish whether melt was extracted or added during migmatization,measured volume percents of leucosome were compared with estimatesof melt production modeled by muscovite + quartz dehydrationmelting. Quantitative estimates of volume percent of leucosomeat present in the outcrop are between 20 and 30%. The amountof melt produced from the model muscovite dehydration meltingreaction is constrained by measured modal percent of sillimanite(15–25%) in the outcrop and is dependent on modal proportionof muscovite in the unmelted protolith and the melt water contentUsing a muscovite-rich protolith and a melt water content of4 wt%, complete dehydration melting of muscovite results ina production of 54 vol % melt and 25 vol % sillmanite, indicatinga melt loss of 29 vol %. A melt water content of 6 wt% resultsin production of 41 vol % melt and 23 vol % sillimanite, indicatinga melt loss of 16 vol %. Melt loss may have occurred by meltmovement along foliation planes during flattening, during formationof shear bands or locally along subvertical fractures. Spatialproximity of the outcrop to the Monashee dcollement suggeststhat thrusting was localized to zones of high melt production,which in turn facilitated melt migration. KEY WORDS: migmatites; British Columbia; Monashee Tarrane; anatexis; melt extraction ^*Corresponding author. Present address: Department of Earth and Planetary Sciences, The Univenity of New Mexico, Albuquerque, NM 817131, USA     

Glauconitization of detrital silica substrates in the Barton Formation (upper Eocene) of the Hampshire Basin, southern England

Upper Eocene detrital silica grains (chert and quartz) of the Hampshire Basin display alteration and replacement fabrics by glauconite. Silica grains have etched surfaces due to glauconitization which appear green in reflected light and thin section. Quartz grains were glauconitized by surface nucleation and replacement, which spreads from the margin with progressive glauconitization, replacing the quartz grain interior. Chert grains were glauconitized by surface replacement and nucleation internally along cracks and in pores. Different forms of glauconite are associated with the two minerals; glauconite associated with quartz is generally highly-evolved whereas glauconite associated with chert is of the evolved variety. This is interpreted as being due to different surface-reaction control mechanisms associated with the two forms of silica. There is no evidence to suggest that glauconite evolved in stages from a nascent form. Two crystalline morphological forms of glauconite are found associated with both quartz and chert. Glauconite growing within a confined space has a laminated morphology whilst glauconite occurring on the surface has a rosette morphology.     

Combined flow origin of edgewise intraclast conglomerates: Sellick Hill Formation (Lower Cambrian), South Australia

Unusually thick, coarse grained edgewise intraclast conglomerates occur at eight or more horizons within subtidal nodular and ribbon bedded wackestones and packstones of the Lower Cambrian Sellick Hill Formation, South Australia. The intraclast beds are flat based and laterally discontinuous, forming bar-like structures that must have exhibited bathymetric relief of as much as 1 m. The internal fabrics of these beds are variable. Thinner beds are dominated by flat-lying intraclasts; thicker beds contain both chaotic, randomly oriented, steeply inclined intraclasts and clusters of fan-shaped, vertically stacked edgewise intraclasts. The Sellick Hill Formation intraclast conglomerates are inferred to have been formed by intense, storm-generated combined flows on a broad, subtidal carbonate ramp. Superimposition of wave-induced oscillatory motions on geostrophic bottom flows during large storms generates short-lived, but exceptionally high instantaneous shear stresses in the bottom boundary layer. Entrainment of the relatively large intraclasts occurs through sliding, rather than pivoting. Edgewise fabrics are a product of asymmetric acceleration and deceleration of intraclasts during passage of waves and the chaotic nature of collisions between intraclasts moving within the boundary layer. Collisions between intraclasts impart a rotating moment, causing intraclasts to tip up during maximum fluid shear stress. Lodgement or packing of clasts in vertical or steeply inclined positions occurs within scours, where intraclasts can wedge between other vertically inclined clasts, or where intraclasts are pinned in steep orientations by collisions with shallowly inclined intraclasts. Differential erosional resistance of the intraclast deposits probably led to the development of sharp lateral changes in thickness. The Sellick Hill Formation intraclast conglomerates record erosion and reworking of subtidal, subfairweather wave base environments by exceptionally intense and presumably rare storm flows. The intraclast horizons represent a substantial loss in stratigraphic resolution due to widespread erosion of the ramp.     

A LIMITED-LENGTH-SCALE k-ε MODEL FOR THE NEUTRAL AND STABLY-STRATIFIED ATMOSPHERIC BOUNDARY LAYER

Analytical and numerical models of the neutral and stably-stratifiedatmospheric boundary layer are reviewed. Theoretical arguments andcomputational models suggest that a quasi-steady state is attainable in aboundary layer cooled from below and it is shown how this may be incorporatedwithin a time-steady, one-dimensional model. A new length-scale-limitedk- model is proposed for flows where a global maximum mixing length isimposed by the finite boundary-layer depth or, in stably-stratifiedconditions, by the Obukhov length, whilst still reducing to a form consistentwith the logarithmic law in the surface layer. Simulations compare favourablywith data from the Leipzig experiment and from Cardington airfield inEngland.