The composition and concentration of dissolved free amino acid (DFAA) of seawater samples collected in May 2016 from the surface to the hadal zone of the northern region of the Yap Trench were analyzed by pre-column derivatization of o-phthalaldehyde. Results show that the average concentration of DFAA in the study area was 0.47±0.36 µmol/L. In different sampling stations, the concentrations of DFAA with water depth showed complex variation patterns. At the sediment-seawater interface, the concentrations of DFAA in the western side of the trench were obviously higher than that in its eastern side. In the study area, there were no significant correlations between the concentrations of DFAA and the environmental parameters such as concentrations of chlorophyll a (Chl a), dissolved oxygen (DO), pH, and dissolved inorganic nitrogen (DIN), indicating that the concentrations of DFAA in seawater of the trench are affected by many factors, such as photosynthesis, respiration, temperature, pressure, illumination, and circulation. The dominant DFAA are similar in different water layers of sampling stations, including aspartic acid (Asp), glutamic acid (Glu), glycine (Gly), and serine (Ser). The composition of different amino acids, and the relative abundance of acidic, basic, and neutral amino acids might be related to the sources and consumption of various amino acids. Nine pairs of amino acids in the DFAA showed significantly positive relationship by correlation matrix analysis, suggesting that they might share similar biogeochemical processes. The degradation index (DI) of the DFAA in seawater of the Yap Trench could reflect the degradation, source, and freshness of DFAA in the trench to some extents. This is a preliminary study of amino acids from sea surface to hadal zone in the ocean, more works shall be done in different trenches to reveal their biogeochemical characteristics in extreme marine environments.
Piled embankments, which offer many advantages, are increasingly popular in construction of high-speed railways in China. Although the performance of piled embankment under static loading is well-known, the behavior under the dynamic train load of a high-speed railway is not yet understood. In light of this, a heavily instrumented piled embankment model was set up, and a model test was carried out, in which a servo-hydraulic actuator outputting M-shaped waves was adopted to simulate the process of a running train. Earth pressure, settlement, strain in the geogrid and pile and excess pore water pressure were measured. The results show that the soil arching height under the dynamic train load of a high-speed railway is shorter than under static loading. The growth trend for accumulated settlement slowed down after long-term vibration although there was still a tendency for it to increase. Accumulated geogrid strain has an increasing tendency after long-term vibration. The closer the embankment edge, the greater the geogrid strain over the subsoil. Strains in the pile were smaller under dynamic train loads, and their distribution was different from that under static loading. At the same elevation, excess pore water pressure under the track slab was greater than that under the embankment shoulder. 相似文献
After the Wenchuan earthquake, the overall post-reconstruction of the affected area was completed in 2 years with significant achievements in a top-down fashion. However, the secondary large-scale mass movements and floods that followed the earthquake have shattered mountain settlements and resulted in serious loss of life and property over the last ten years. Local people have taken their own initiative for house reconstruction and recovery. Having taken the tremendous government-driven reconstruction into consideration, the current study aims to understand the contribution of bottom-up approach in whole reconstruction process in Jianjiang River, Longmen Mountain Town of Sichuan, China. This study reveals that in the process of individual rebuilding, local households have tried to construct houses by using more contemporary structures and local resources to rebuild smaller buildings. Such reconstruction activities have changed their lifestyle and source of income to cope with future disasters and adapt with the post-disaster recovery process. Rural households shifted their income sources from tourism to labour migration while revitalizing farming for food and additional income. More than half of residents have no worry about the risk of disasters in reconstruction areas. The bottom-up adaptation can be more sustainable in Longmen Mountain area and provide a reference for other rural areas under recovery after disasters.
Adsorption by nanoporous media is critically involved in many fundamental geological and geochemical processes including chemical weathering,element migration and enrichment,environmental pollution,etc.Yet,the adsorption behavior of metal ions on nanoporous materials has not been systematically investigated.In this study,MCM-41 material with a monodisperse pore size(4.4 nm)and a large BET specific surface area(839 m^2/g)was hydrothermally prepared and used as a model silica adsorbent to study the adsorption characteristics of Cu^2+as a representative metal ion.The Cu^2+adsorption capacity was found to increase with increasing suspension pH in the range from 3 to 5 and to decrease in the presence of NaNO3.At 25℃,pH=5,and a solid-to-liquid ratio of 5 g/L,the adsorption capacity was determined to be 0.29 mg/g,which can be converted to a dimensionless partition coefficient of 45,indicating a strong enriching effect of nanoporous silica.The adsorption isotherm and kinetic data were fitted to several commonly used thermodynamic,kinetic,and diffusion models.The adsorption mechanism was also studied by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy and synchrotron-based X-ray absorption spectroscopy.The results suggest that Cu2+ion adsorption is an entropy-driven endothermal process,possibly involving both outer-sphere and inner-sphere complexes. 相似文献
Nitrification is a key step in the global nitrogen cycle.Compared with autotrophic nitrification,heterotrophic nitrification remains poorly understood.In this study,Halomonas venusta MA-ZP17-13,isolated from seawater in shrimp aquaculture (Penaeus vannamei),could simultaneously undertake nitrification and denitrification.With the initial ammonium concentration at 100 mg/L,the maximum ammonium-nitrogen removal rate reached98.7%under the optimal conditions including C/N concentration ratio at 5.95,p H at 8.93,and Na Cl at 2.33%.The corresponding average removal rate was 1.37 mg/(L·h)(according to nitrogen) in 3 d at 11.2°C.By whole genome sequencing and analysis,nitrification-and denitrification-related genes were identified,including ammonia monooxygenase,nitrate reductase,nitrite reductase,nitric oxide dioxygenase and nitric oxide synthase;while no gene encoding hydroxylamine oxidase was identified,it implied the existence of a novel nitrification pathway from hydroxylamine to nitrate.These results indicate heterotrophic bacterium H.venusta MA-ZP17-13 can undertake simultaneous nitrification and denitrification at low temperature and has potential forNH_4~+-N/NH3-N removal in marine aquaculture systems. 相似文献