A demonstration of an affinity between pyrite and organic matter in a hydrothermal setting

One of the key-principles of the iron-sulphur world theory is to bring organic molecules close enough to interact with each other, using the surface of pyrite as a substrate in a hydrothermal setting. The present paper explores the relationship of pyrite and organic matter in a hydrothermal setting from the geological record; in hydrothermal calcite veins from Carboniferous limestones in central Ireland. Here, the organic matter is accumulated as coatings around, and through, pyrite grains. Most of the pyrite grains are euhedral-subhedral crystals, ranging in size from ca 0.1-0.5 mm in diameter, and they are scattered throughout the matrix of the vein calcite. The organic matter was deposited from a hydrothermal fluid at a temperature of at least 200°C, and gives a Raman signature of disordered carbon. This study points to an example from a hydrothermal setting in the geological record, demonstrating that pyrite can have a high potential for the concentration and accumulation of organic materials.     

Climate change and infectious diseases: Can we meet the needs for better prediction?

The next generation of climate-driven, disease prediction models will most likely require a mechanistically based, dynamical framework that parameterizes key processes at a variety of locations. Over the next two decades, consensus climate predictions make it possible to produce forecasts for a number of important infectious diseases that are largely independent of the uncertainty of longer-term emissions scenarios. In particular, the role of climate in the modulation of seasonal disease transmission needs to be unravelled from the complex dynamics resulting from the interaction of transmission with herd immunity and intervention measures that depend upon previous burdens of infection. Progress is also needed to solve the mismatch between climate projections and disease projections at the scale of public health interventions. In the time horizon of seasons to years, early warning systems should benefit from current developments on multi-model ensemble climate prediction systems, particularly in areas where high skill levels of climate models coincide with regions where large epidemics take place. A better understanding of the role of climate extremes on infectious diseases is urgently needed.     

The origin of large varioles in flow-banded pillow lava from the Hooggenoeg Complex,Barberton Greenstone Belt,South Africa

Exceptionally well-preserved pillowed and massive phenocryst-free metabasaltic lava flows in the uppermost part of the Palaeoarchaean Hooggenoeg Complex of the Barberton Greenstone Belt exhibit both flow banding and large leucocratic varioles. The flow banding is defined by blebs and bands of pale and dark green metabasalt and was the result of mingling of two types of basalt (Robins et al. in Bull Volcanol 72:579–592, 2010a). Varioles occur exclusively in the dark chlorite-, MgO- and FeO-rich metabasalt. Varioles are absent in the outermost rinds of pillows and increase in both abundance and size towards the centres of pillows. In the central parts of some pillows, they impinge to form homogeneous pale patches, bands or almost homogenous cores. Individual varioles consist essentially of radially orientated or outwardly branching dendritic crystals of albite. Many varioles exhibit concentric zones and finer-grained rims. Some varioles seem to have grown around tiny vesicles and vesicles appear to have been trapped in others between a core and a finer-grained rim. The matrix surrounding the ocelli contains acicular pseudomorphs of actinolite and chlorite after chain-like, skeletal Ca-rich pyroxenes that are partly overgrown by the margins of varioles. Varioles are enriched in the chemical constituents of feldspar but contain concentrations of immobile TiO₂, Cr, Zr and REE that are similar to the host metabasalts. The shape, distribution, texture and composition of the varioles exclude liquid immiscibility and support an origin by spherulitic crystallisation of plagioclase from severely undercooled basalt melt and glass. Nucleation of plagioclase was strongly inhibited and took place on vesicles, on the bases of drainage cavities and along early fractures. Eruption in deep water and retention of relatively high concentrations of volatiles in the melt may be the principal cause of spherulitic crystallisation in the interiors of pillows rather than only in their margins as in younger submarine flows.     

Age and origin of groundwater resources in the Ararat Valley,Armenia: a baseline study applying hydrogeochemistry and environmental tracers

Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ²H, δ¹⁸O) and radioactive (³⁵S, ³H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (³⁵S), the detected ³H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.

     

Wintertime Cyclone Activity and Its Relation to Precipitation over China

The authors examined the variability in wintertime cyclone activity and storm tracks and their relation to precipitation over China for the period 1951–2006 using the observational data.Two apparent modes of variability were assumed for the cyclone activity and storm tracks.The first mode describes the oscillation in the strength of the storm tracks in East Asia,which significantly increased since the mid-1980s,whereas the second mode describes a seesaw oscillation in the storm track strength between the Central-Southeast China and northern East Asia.The storm tracks over the Central-Southeast China have increased since the late 1960s.The possible causes for the variation of the cyclone activity and storm tracks are also explored.It is shown that wintertime precipitation,which has increased since the mid-1980s,concentrates in Central-Southeast China.The enhancement may be caused by the first mode of variability of storm tracks,whereas the interannual variability of precipitation may be linked to the second mode of the storm track variability.     

Distribution of lunar impacts by objects in parabolic low inclination orbits

This paper presents a computer investigation extending to the case of parabolic orbits, an earlier investigation conducted by Barricelli and Metcalfe (1969) on lunar impacts by external low eccentricity satellites as a means to interpret the asymmetric distribution of lunar maria. Parabolic orbits can be approximated by two kinds of objects:

1. High eccentricity external satellites may, near periapsis, approach the Moon with orbital velocity and other characteristics closely resembling those of a parabolic orbit.
2. Asteroids and meteoroids approaching the Earth-Moon system with a low velocity may have moved in a nearly parabolic orbit when they reached the lunar distance from the Earth at the time when the impacts which carved the lunar maria took place.

The investigation gives, therefore, not only additional information relevant to the interpretation of the distribution of lunar maria by the satellite impacts hypothesis (in this case high eccentricity ones), but also information about the alternative hypothesis (Wood, 1973) that asteroid impacts rather than satellite impacts were involved.     

Morphology and dynamics of the intertidal floodplain along the Amazon tidal river

Depositional environments along the tidal river downstream of Óbidos have been proposed as important sinks for up to one third of the sediment discharge from the Amazon River. However, the morphology of the intertidal floodplain and the dynamics of sediment exchange along this reach have yet to be described. River-bank surveys in five regions along the Amazon tidal river reveal a distinct transition in bank morphology between the upper, central and lower reaches of the tidal river. The upper tidal-river floodplain is defined by prominent natural levees that control the transfer of water and sediment between the mainstem Amazon River and its floodplain. Greater tidal influence in the central tidal river suppresses levee development, and tidal currents increase sediment transport into the distal parts of the floodplain. In the lower tidal river, the floodplain morphology closely resembles marine intertidal environments (e.g. mud flats, salt marshes), with dendritic tidal channels incising elevated vegetated flats. Theory, morphology and geochronology suggest that the dynamics of sediment delivery to the intertidal floodplain of the Amazon tidal river vary along its length due to the relative influence and coupling of fluvial and tidal dynamics. © 2018 John Wiley & Sons, Ltd.     

Flow dynamics,sedimentation and erosion of glacial lake outburst floods along the Middle Pleistocene Scandinavian Ice Sheet (northern central Europe)

During the Middle Pleistocene late Saalian glaciation of northern central Europe numerous pro‐glacial lakes formed along the southwestern margin of the Scandinavian Ice Sheet. Little is known about the drainage history of these lakes, the pathways of glacial lake outburst floods and their impacts on erosion, sedimentation and landscape evolution. This study investigated the impact of the late Saalian Weser and Münsterland Lake (Germany) outburst floods. In particular, we reconstructed the routing and flow dynamics of the lake outburst flood and analysed the flood related sediments. We employed one‐dimensional hydraulic modelling to calculate glacial lake outburst flood hydrographs. We modelled the flow pathway and local flow conditions along the pathway based on the boundary conditions of two different hydrographs and two different ice‐margin positions. The modelling results were compared with geomorphological and sedimentological field data in order to estimate the magnitude and impact of the flood on erosion and sedimentation. Two major lake drainage events are reconstructed for the study area, during which approximately 90–50 km³ of water was released. Modelling results indicate that the lake outburst floods created a high‐energy flood wave with a height of 35–50 m in confined valley areas that rapidly spread out into the Lower Rhine Embayment eventually flowing into the North Sea basin. The sedimentary record of the outburst floods comprises poorly sorted coarse‐grained gravel bars, long‐wavelength bedforms and sandy bedforms deposited by supercritical and subcritical flows. Some parts of the sandy flood deposits are rich in reworked mammoth bones or mammoth and horse teeth, pointing to reworking of older fluvial sediments, hydraulic concentration and subsequent re‐sedimentation of vertebrate remains. These deposits are preserved in sheltered areas or at high elevations, well above the influence of postglacial fluvial erosion. The flood‐related erosional features include up to 80‐m‐deep scour pools, alluvial channels and streamlined hills.     

Developing a model of climate change behavior among adolescents

Research on adolescent climate change perceptions has uncovered key insights about how knowledge, concern, and hope might relate to behavior and the potential for educational interventions to influence these factors. However, few of these studies have employed treatment/control designs that might address causality and none have addressed how these factors might interact to influence behavior. We developed a model of behavior change where a climate education treatment impacted knowledge, knowledge impacted hope and concern, and hope and concern together impacted behavior. We empirically tested the utility of this model and the causal relationships within it using a pre/post, treatment/control evaluation of climate education among adolescents in North Carolina, USA (n?=?1041). We found support for a causal relationship between the treatment and gains in knowledge, but not between treatment and behavior. However, we did find support for a path model in which climate change knowledge positively relates to increased climate change concern and hope, and increases in concern and hope predict changes in pro-environmental behavior. Low SES was related to smaller gains in knowledge, concern, and behavior. Our results contribute to a theoretical understanding of climate change behaviors among adolescents and suggest that climate education aiming to change behavior should focus on building hope and concern.