Organochlorine pesticides in soil and air at and around a compound contaminated site: vertical distribution,soil–air exchange and risk evaluation

The control of soil pollution in China has become an issue, and in this study, a compound contaminated site was selected and focus on the site and its nearby environment, organochlorine pesticides (OCPs) were investigated in both soil (top and deep soil) and air samples. The main pollutants in top soils at site are dichlorodiphenyltrichloroethane (DDTs, 0.05–104 mg/kg d.w., avg: 14.5 mg/kg d.w.) and hexachlorobenzene (HCB, 0.02–4.85 mg/kg d.w., avg: 0.72 mg/kg d.w.) which is in accordance with its production history. As for the deep soils, ΣOCPs at site were found concentrated at workshops especially the technical pesticide workshop (5.29–22.1 mg/kg d.w., avg: 9.15 mg/kg d.w.) and the history DDTs’ workshop (4.00–64.8 mg/kg d.w., avg: 20.4 mg/kg d.w). Around site, OCPs were mainly concentrated at layers of −20 cm and the −40 cm and decreased with distance being far away, at 5000 m, the ΣOCPs was comparable with normal agriculture soil (22.1−91.4 ng/g d.w., avg: 55.4 ng/g d.w.). ΣOCPs in the air samples ranged 64.6–823 ng/m³ (avg: 459 ng/m³) at site and 9.93–176 ng/m³ (avg: 50.8 ng/m³) around site which are all dominated with DDTs and HCHs. Soil–air exchange fugacity was calculated to judge the transportation of the OCPs and the results showed soils at the site and its nearby areas (within 5000 m) are releasing most of the OCPs into air, and accordingly through evaluation, inhalation was found to be the major source for human health risk, which is a great threat to the workers at site and the nearby residents.

     

几种海水贝类甲醛浸渍标本DNA的提取及rRNA基因ITS序列的扩增

从中国科学院海洋生物标本馆收藏的8种甲醛浸渍的海水贝类标本中提取DNA并对其rRNA编码基因的ITS序列进行特异性扩增,在牡蛎Crassostrea sp．、长肋日月贝Amussium pleurondectes (Linnaeus)、扇贝Volachlamys ringaporinug(Sowerby)与华贵栉孔扇贝Chlamys nobilis(Reeve)等4个物种的标本中成功获得扩增产物。利用图片分析软什得出牡蛎标本的ITS-1和ITS-2扩增片段分别为408bp和524bp,长肋日月贝标本分别521bp和537bp,而扇贝Volachlamys ringaporinug(Sowerby)与华贵栉孔扇贝标本只获得ITS-1扩增片段,长度均为545bp。     

基于手机位置数据的地震灾情指标选择

选取四川阿坝州九寨沟县MS7.0地震、新疆博尔塔拉州精河县MS6.6地震、四川广元市青川县MS5.4地震作为案例分析,绘制活跃Wi Fi数量、无线网络联网设备数量、汇总在线设备数量、活跃基站数量等4种地震灾情指标在地震发生前后数量变化的折线图。根据与地震前1天变化情况的对比分析,验证地震灾情指标的可用性,选取出效果好的指标,这对进一步研究震后快速获取极震区位置、影响场方向等具有重要意义。     

Adsorption characteristics of copper ion on nanoporous silica

Adsorption by nanoporous media is critically involved in many fundamental geological and geochemical processes including chemical weathering,element migration and enrichment,environmental pollution,etc.Yet,the adsorption behavior of metal ions on nanoporous materials has not been systematically investigated.In this study,MCM-41 material with a monodisperse pore size(4.4 nm)and a large BET specific surface area(839 m^2/g)was hydrothermally prepared and used as a model silica adsorbent to study the adsorption characteristics of Cu^2+as a representative metal ion.The Cu^2+adsorption capacity was found to increase with increasing suspension pH in the range from 3 to 5 and to decrease in the presence of NaNO3.At 25℃,pH=5,and a solid-to-liquid ratio of 5 g/L,the adsorption capacity was determined to be 0.29 mg/g,which can be converted to a dimensionless partition coefficient of 45,indicating a strong enriching effect of nanoporous silica.The adsorption isotherm and kinetic data were fitted to several commonly used thermodynamic,kinetic,and diffusion models.The adsorption mechanism was also studied by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy and synchrotron-based X-ray absorption spectroscopy.The results suggest that Cu2+ion adsorption is an entropy-driven endothermal process,possibly involving both outer-sphere and inner-sphere complexes.     

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An analysis of the causes of decadal variations of rainfall in Shandong in summer

The precipitation in Shandong in July, August as well as the whole summer (JJA) and the corresponding 500hPa geopotential height fields are analyzed by means of the SVD (singular value decomposition) methodology. It is found that the general circulations in East Asia and the Western Pacific underwent decadal changes around 1979. The geopotential height, in particular over key areas like the South China Sea and the Philippines, increased after 1979. Corresponding to the changes in the geopotential height, the rainfall in Shandong started to decrease around 1979. The synthesized analysis shows that when the geopotential height at 500hPa level decreases in the key areas, the Western Pacific subtropical high shifts northward and an anticyclonic anomalous cell enforces the southerly flow over Shandong-Korea-Japan, Shandong could experience a wet period. A dry period is likely to occur when the geopotential height increases in these key areas, the subtropical high moves southward or expands westward to a great distance, and a cyclonic anomalous cell controls Shandong. Respective conceptual models for the causative mechanism are obtained for the cases of July, August and the whole summer (JJA).     

CICE5.0与BCC_CSM2.0模式的耦合及对北极海冰的模拟评估

本文将美国Los Alamos国家实验室发展的最新海冰模式CICE5.0引入国家气候中心气候系统模式BCC_CSM2.0,替代原有的海冰模式SIS,形成一个新的耦合模式。在此基础上,评估新耦合模式对1985-2009年北极海冰的模拟性能,检验引入CICE5.0后对耦合模式中北极海冰、海洋和大气模拟结果的改进。结果表明,引入CICE5.0后,模式能较好地模拟出北极海冰的空间分布、季节以及年际变化特征。相比于旧版本耦合模式,新耦合模式模拟的北极多年冰增多、一年冰减少,同时,海冰增厚、海冰流速减慢,模拟效果得到显著改进,对波弗特涡流模拟的改善尤为明显。进一步分析发现,相比于SIS,CICE5.0对北极海冰特别是海冰厚度模拟性能的提升,在耦合进入BCC_CSM2.0后,会触发冰-温的正反馈机制,改进了模式对海平面气压场、表层气温和海表温度的模拟,由此进一步提高了模式对北极海冰的模拟能力。     

Dye adsorption on electrochemical exfoliated graphene oxide nanosheets: pH influence,kinetics and equilibrium in aqueous solution

Graphene oxide nanosheets were synthesized by electrochemical exfoliation. X-ray diffraction, scanning electron microscopy, atomic force microscopy, Raman spectrometry and Fourier transform infrared spectrometry were used to characterize crystal structure, particle size, thickness and function groups of the nanosheets. The nanosheets were examined for adsorption of methyl orange, an anionic dye, in aqueous solution at different pHs and temperatures. The maximum adsorption capacity of methyl orange on graphene oxide nanosheets obtained from the Langmuir isotherm was 138.69 mg/g at pH 2.0, which is larger than that of other carbonaceous adsorbents. The large adsorption affinity of graphene oxide nanosheets to methyl orange might be due to the presence of hydrogen bonding and π–π interaction between methyl orange and graphene oxide nanosheets. Adsorption kinetics followed a pseudo-second-order kinetic model, and the isotherm adsorption results were fitted with Langmuir isotherm model in a monolayer adsorption manner. The thermodynamic studies indicated that the adsorption reaction was a spontaneous physisorption process.     

The diagenetic geochemistry and contamination assessment of iron,cadmium, and lead in the sediments from the Shuangtaizi estuary,China

Sediment and pore water samples have been collected from the coastal tidal flat in the Shuangtaizi estuary, China, in order to investigate the geochemical behavior of iron, cadmium, and lead during diagenesis and to assess the degree of contamination. The calculated enrichment factors and geoaccumulation indices for separate elements show that anthropogenic activities have had no significant influence on the distribution of Fe and Pb in the study area, whereas the distribution of Cd has been closely influenced in this way. The high percentage of exchangeable Cd (average of 56.34%) suggests that Cd represents a potential hazard to benthic organisms in the estuary. The calculated diffusive fluxes of metals show that the most mobilized metal is Fe (9.22 mg m^?2 a^?1), followed by Cd (0.54 mg m^?2 a^?1) and Pb (0.42 mg m^?2 a^?1). Low Fe²⁺ contents in surface pore water, alongside high chromium-reducible sulfur contents, and low acid-volatile sulfur, and elemental sulfur contents at 0–25 cm depth in sediments show that Fe²⁺ is formed by the reduction of Fe oxides and is transformed first to a solid phase of iron monosulfides (FeS) and eventually to pyrite (FeS₂). The release of adsorbed Pb due to reductive dissolution of Fe/Mn oxides during early diagenesis could be a source of Pb²⁺ in pore water. From the relatively low total organic carbon contents measured in sediments (0.46–1.28%, with an average of 0.94%) and the vertical variation of Cd²⁺ in pore water, sulfide or Fe/Mn oxides (instead of organic matter) are presumed to exert a significant influence on carrying or releasing Cd by the sediments.     

A distributed parameter model of a frame pin‐supported wall structure

Many reinforced‐concrete frames collapse via a soft‐story mechanism during severe earthquakes. Such collapses are mainly attributed to concentrated deformation in a soft story. Deformation control is thus important in preventing collapse. The frame pin‐supported wall structure is a type of rocking structure that releases constraints at the bottom of the wall. Previous research has obtained good results for the deformation control of this type of structure. However, the interior forces and strength demands of the pin‐supported wall have not been systematically explored. In this paper, a distributed parameter model is developed to investigate the strength demand of the wall in a frame pin‐supported wall structure. In the model, the pin‐supported wall is simplified as a bending beam and the frame is simplified as a shear beam. The two beams are joined by distributed shear connectors, so that the shear force can be transferred at any location on the interface. The model can be solved using differential equations based on equilibrium and compatibility. The accuracy of the model is verified using SAP2000 (Computers and Structures Inc., Berkeley, CA, USA). Displacement distribution of the structure and distributions of the moment and shear force within the pin‐supported wall are obtained for two typical external force profiles. It is found that the pin‐supported wall can effectively reduce the drift concentration factor. Distributions of the displacement, moment, and shear force are closely correlated with the relative stiffness of the wall and frame. Finally, recommendations on the stiffness and strength of a pin‐supported wall are made. Copyright © 2015 John Wiley & Sons, Ltd.