A simulation study of capillary transport,preferential retention and distribution of salts in historic sandstone buildings

Salt crystallisation is a major problem of deterioration in historic stone buildings, monuments and sculptures. The capillary rise of soil water is one of the primary sources of salts in stone structures, which evaporates leaving the salts behind. It has been noted that the spatial distribution profile of different species of salts crystallised in historic stone buildings is not homogeneous, i.e. different salts crystallise at different locations. The capillary transport and inhomogeneous spatial distribution of different salts in the porous building materials has been considered to be a result of solubility-dependent crystallisation; however, the factors responsible for this phenomenon are not clearly known. This paper aims to investigate the factors influencing the differential distribution of salts during capillary rise of soil water. In this study, the capillary transport of salts was simulated on two different sandstones—Locharbriggs, a Permo–Triassic, red sandstone and Stoke Hall, a Carboniferous, buff sandstone. The experiments were carried out under controlled environmental conditions to eliminate the possibility of evaporation-driven crystallisation of salts depending on their solubilities. The results indicate that fractionation or differential distribution of salts takes place even in the absence of evaporation and crystallisation. The sandstones exhibit properties like an ion exchange column, and ionic species present in the salt solution show differential distribution within the porous network of sandstone.     

Markov Chain Random Fields for Estimation of Categorical Variables

Multi-dimensional Markov chain conditional simulation (or interpolation) models have potential for predicting and simulating categorical variables more accurately from sample data because they can incorporate interclass relationships. This paper introduces a Markov chain random field (MCRF) theory for building one to multi-dimensional Markov chain models for conditional simulation (or interpolation). A MCRF is defined as a single spatial Markov chain that moves (or jumps) in a space, with its conditional probability distribution at each location entirely depending on its nearest known neighbors in different directions. A general solution for conditional probability distribution of a random variable in a MCRF is derived explicitly based on the Bayes’ theorem and conditional independence assumption. One to multi-dimensional Markov chain models for prediction and conditional simulation of categorical variables can be drawn from the general solution and MCRF-based multi-dimensional Markov chain models are nonlinear.     

一种改进的基于非高斯性最大化的预测反褶积算法

The predictive deconvolution algorithm （PD）, which is based on second-order statistics, assumes that the primaries and the multiples are implicitly orthogonal. However, the seismic data usually do not satisfy this assumption in practice. Since the seismic data （primaries and multiples） have a non-Gaussian distribution, in this paper we present an improved predictive deconvolution algorithm （IPD） by maximizing the non-Gaussianity of the recovered primaries. Applications of the IPD method on synthetic and real seismic datasets show that the proposed method obtains promising results.     

REXEL: computer aided record selection for code-based seismic structural analysis

In code-based seismic design and assessment it is often allowed the use of real records as an input for nonlinear dynamic analysis. On the other hand, international seismic guidelines, concerning this issue, have been found hardly applicable by practitioners. This is related to both the difficulty in rationally relating the ground motions to the hazard at the site and the required selection criteria, which do not favor the use of real records, but rather various types of spectrum matching signals. To overcome some of these obstacles a software tool for code-based real records selection was developed. REXEL, freely available at the website of the Italian network of earthquake engineering university labs (), allows to search for suites of waveforms, currently from the European Strong-motion Database, compatible to reference spectra being either user-defined or automatically generated according to Eurocode 8 and the recently released new Italian seismic code. The selection reflects the provisions of the considered codes and others found to be important by recent research on the topic. In the paper, record selection criteria are briefly reviewed first, and then the algorithms implemented in the software are discussed. Finally, via some examples, it is shown how REXEL can effectively be a contribution to code-based real records selection for seismic structural analysis.     

The Geology and Petroleum Resources of Kansas: A Review From Alpha to Omega or From the Pleistocene to the Precambrian

The geological story of Kansas is told through the rocks that are present. It is a simple story in generalities but complex in detail. Knowing the story, gives insight into understanding the occurrence and location of possible economic valuable minerals, such as petroleum. This is a brief review of Kansas geology with respect to the known occurrence of oil and gas. Kansas is part of the Midcontinent oil province with oil having been discovered 150 years ago and commercial production commencing in 1873. Although many prospects remain in Kansas, the state has gone from the number 1 producer in the U.S. in 1916 to 8th today. Exploration for new oil and gas production therefore is going to have to be more imaginative and utilize new approaches and techniques to find the elusive petroleum. There are possibilities however for the prospector who can search diligently. Although the big fields probably have been discovered, the prospects today are deeper, in more undetectable traps, and in essentially untested places.     

Unique isoprene oxidation products demonstrate chlorine atom chemistry occurs in the Houston,Texas urban area

As part of the 2000 Texas Air Quality Study (TexAQS), we studied the isoprene oxidation process under ambient conditions to discern the presence of chlorine atom (Cl) chemistry in the Houston, Texas urban area. By measuring chloromethylbutenone (CMBO) and an isomer of chloromethylbutenal (CMBA), we clearly observed sixteen episodes of active Cl chemistry during the 24-day experiment. Estimated median Cl concentration during each of these episodes was between the detection limit of ~10² atoms cm⁻³ and 50 _{- 30} ^{+ 70} ×10⁴ 50_{ - 30}^{ + 70} \times {10^4} atoms cm⁻³. Cl concentration during all the episodes averaged 7.6 _{- 2.0} ^{+ 4.7} ×10⁴ 7.6_{ - 2.0}^{ + 4.7} \times {10^4} atoms cm⁻³ and thus amounted to less than 3% of the OH concentration during the same periods. During the episodes, the fraction of oxidation chemistry initiated by Cl ranged from 3–43% and was strongly dependent on the quantity and type of hydrocarbons present in the atmosphere. Because of its intermittent presence and low concentration, Cl is not a broadly influential oxidant in the Houston, Texas urban area.     

Preface

Climate change is one of the most challenging issues faced by human beings. Although many remarkable achievements have been made in climate change research,there is still a tremendous amount of uncertainty in     

Late Quaternary paleoenvironments of an ephemeral wetland in North Dakota,USA: relative interactions of ground-water hydrology and climate change

This study of fossils (pollen, plant macrofossils, stomata and fish) and sediments (lithostratigraphy and geochemistry) from the Wendel site in North Dakota, USA, emphasizes the importance of considering ground-water hydrology when deciphering paleoclimate signals from lakes in postglacial landscapes. The Wendel site was a paleolake from about 11,500 ¹⁴C yr BP to 11,100 ¹⁴C yr BP. Afterwards, the lake-level lowered until it became a prairie marsh by 9,300 ¹⁴C yr BP and finally, at 8,500 ¹⁴C yr BP, an ephemeral wetland as it is today. Meanwhile, the vegetation changed from a white spruce parkland (11,500 to 10,500 ¹⁴C yr BP) to deciduous parkland, followed by grassland at 9,300 ¹⁴C yr BP. The pattern and timing of these aquatic and terrestrial changes are similar to coeval kettle lake records from adjacent uplands, providing a regional aridity signal. However, two local sources of ground water were identified from the fossil and geochemical data, which mediated atmospheric inputs to the Wendel basin. First, the paleolake received water from the melting of stagnant ice buried under local till for about 900 years after glacier recession. Later, Holocene droughts probably caused the lower-elevation Wendel site to capture the ground water of up-gradient lakes.     

ARMA order model detection using minimum of Kurtosis: application on seismic data

The objective of this study is to find the order and coefficients of non-low-phase causal filters for ARMA (auto regressive moving average) filter model, using the Kurtosis minimization criterion. This method is based on the Kurtosis calculation of the treated sample at the input level and its identification at the output of the ARMA model. For this purpose, the order and coefficients of the AR (auto regressive) part are identified using the Yule-Walker algorithm at order two and then extended to order four. To obtain the MA (moving average) part, the AR components are calculated at first from the ARMA filter by deconvolution. Then, spectrally equivalent and minimum phase (SEMP) MA filter is identified using the Durbin algorithm at second and fourth order. Finally, the correct filter is found when the Kurtosis value of the output ARMA filter reconstituted is the closest to the Kurtosis of introduced signal. The proposed method is then tested on simulated processes and applied to real seismic data to perform blind deconvolution and obtain the reflectivity coefficients of subsoil studied.