Geochronology,stratigraphy and geochemistry of Cambro-Ordovician,Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean–island magmatism

International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were...     

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.     

The Oeschinensee rock avalanche,Bernese Alps,Switzerland: a co-seismic failure 2300 years ago?

Landslide deposits dam Lake Oeschinen (Oeschinensee), located above Kandersteg, Switzerland. However, past confusion differentiating deposits of multiple landslide events has confounded efforts to quantify the volume, age, and failure dynamics of the Oeschinensee rock avalanche. Here we combine field and remote mapping, topographic reconstruction, cosmogenic surface exposure dating, and numerical runout modeling to quantify salient parameters of the event. Differences in boulder lithology and deposit morphology reveal that the landslide body damming Oeschinensee consists of debris from both an older rock avalanche, possibly Kandertal, as well as the Oeschinensee rock avalanche. We distinguish a source volume for the Oeschinensee event of 37 Mm³, resulting in an estimated deposit volume of 46 Mm³, smaller than previous estimates that included portions of the Kandertal mass. Runout modeling revealed peak and average rock avalanche velocities of 65 and 45 m/s, respectively, and support a single-event failure scenario. ³⁶Cl surface exposure dating of deposited boulders indicates a mean age for the rock avalanche of 2.3 ± 0.2 kyr. This age coincides with the timing of a paleo-seismic event identified from lacustrine sediments in Swiss lakes, suggesting an earthquake trigger. Our results help clarify the hazard and geomorphic effects of rare, large rock avalanches in alpine settings.     

Detecting Clay Minerals in Hydrothermal Alteration Areas with Integration of ASTER Image and Spectral Data in Kösedag-Zara (Sivas), Turkey

Remote sensing technology and its terrestrial components are more useful than classical geological investigation in mineral exploration and mapping the hydrothermal alteration areas and help to investigate larger areas in short time. Intrusive and volcanic rocks, namely Kösedag syenite and Karatas volcanics in Kösedag (Zara) area shows argillic alteration zones. Two different test area were chosen and sampled for mineralogical studies. XRD-CF investigations showed that kaolinite and illite are the dominant clay minerals in test areas of A and B respectively. The spectroradiometer measurements were carried out 5 times on different surfaces of clayey samples with self-illuminated contact-probe lens within the wavelength range of 350-2500 nm. The spectroradiometer measurements used as endmember were resampled to ASTER short wave infrared (SWIR) bandwidths. Band ratio, principal component and decorrelation stretching analysis were performed to visualize the distribution of clay minerals. In spectral classification method, matched filtering (MF) was used for integrating the satellite image and spectroradiometer measurement data. It was concluded that co-interpretations of the band ratio, principal component, decorrelation stretching analysis, MF results and geological map are very useful in determining, classifying and mapping of the argillic alteration zones related to hydrothermal processes on ASTER image and they seem to be very useful to identify the target areas for mineral exploration.     

New results concerning the pedo- and chronostratigraphy of the loess–palaeosol sequence Attenfeld (Bavaria,Germany) derived from a multi-methodological approach

Loess–palaeosol sequences (LPS) represent important records of palaeoenvironmental dynamics throughout the Quaternary. During the Pleistocene's dry and cold phases, the Danube's riverbed was one of the major sources for loess sediments that built up LPS in southern Germany and southeastern Europe. Surprisingly, studies addressing Bavarian LPS along the Danube River often lack actuality. The Attenfeld site was one of them and is often cited as a typical LPS. Nevertheless, the site's previous interpretations are based on a few empirical data and field observations. Considering the site's closeness to the sediment's source area, the Alps, and the region's importance in Middle and Upper Palaeolithic migrational movements, those former renditions needed an evaluation. Therefore, we applied a multi-proxy approach (including analyses of grain-size distribution, element composition, and sediment colour attributes) combined with optically stimulated luminescence. Based on our findings, we conclude that the Attenfeld site's former interpretations might be too generalised. We identified units that were not mentioned by previous studies (e.g. Early Glacial dark greyish horizon). Field observations, sediment characteristics, and age estimates indicate sediment deposition of the dated units partly before MIS 4, which contrasts with previous interpretations. The results further demonstrate how sensitive LPS are to environmental settings and dynamics.     

Extreme waves induced by cyclone Nargis at Myanmar coast: numerical modeling versus satellite observations

Natural Hazards - The deltaic coast of Myanmar was severely hit by tropical cyclone Nargis in May 2008. In the present study, a top-down numerical simulation approach using the Weather Research and...     

Quantitative 3D imaging of partially saturated granular materials under uniaxial compression

Acta Geotechnica - Gauging the mechanical effect of partial saturation in granular materials is experimentally challenging due to the very low suctions resulting from large pores. To this end, a...     

Using Statistical Downscaling to Quantify the GCM-Related Uncertainty in Regional Climate Change Scenarios： A Case Study of Swedish Precipitation

There are a number of sources of uncertainty in regional climate change scenarios. When statistical downscaling is used to obtain regional climate change scenarios, the uncertainty may originate from the uncertainties in the global climate models used, the skill of the statistical model, and the forcing scenarios applied to the global climate model. The uncertainty associated with global climate models can be evaluated by examining the differences in the predictors and in the downscaled climate change scenarios based on a set of different global climate models. When standardized global climate model simulations such as the second phase of the Coupled Model Intercomparison Project （CMIP2） are used, the difference in the downscaled variables mainly reflects differences in the climate models and the natural variability in the simulated climates. It is proposed that the spread of the estimates can be taken as a measure of the uncertainty associated with global climate models. The proposed method is applied to the estimation of global-climate-model-related uncertainty in regional precipitation change scenarios in Sweden. Results from statistical downscaling based on 17 global climate models show that there is an overall increase in annual precipitation all over Sweden although a considerable spread of the changes in the precipitation exists. The general increase can be attributed to the increased large-scale precipitation and the enhanced westerly wind. The estimated uncertainty is nearly independent of region. However, there is a seasonal dependence. The estimates for winter show the highest level of confidence, while the estimates for summer show the least.     

Boosting for Mineral Prospectivity Modeling: A New GIS Toolbox

With an increasing demand for raw materials, predictive models that support successful mineral exploration targeting are of great importance. We evaluated different machine learning techniques with an emphasis on boosting algorithms and implemented them in an ArcGIS toolbox. Performance was tested on an exploration dataset from the Iberian Pyrite Belt (IPB) with respect to accuracy, performance, stability, and robustness. Boosting algorithms are ensemble methods used in supervised learning for regression and classification. They combine weak classifiers, i.e., classifiers that perform slightly better than random guessing to obtain robust classifiers. Each time a weak learner is added; the learning set is reweighted to give more importance to misclassified samples. Our test area, the IPB, is one of the oldest mining districts in the world and hosts giant volcanic-hosted massive sulfide (VMS) deposits. The spatial density of ore deposits, as well as the size and tonnage, makes the area unique, and due to the high data availability and number of known deposits, well-suited for testing machine learning algorithms. We combined several geophysical datasets, as well as layers derived from geological maps as predictors of the presence or absence of VMS deposits. Boosting algorithms such as BrownBoost and Adaboost were tested and compared to Logistic Regression (LR), Random Forests (RF) and Support Vector machines (SVM) in several experiments. We found performance results relatively similar, especially to BrownBoost, which slightly outperformed LR and SVM with respective accuracies of 0.96 compared to 0.89 and 0.93. Data augmentation by perturbing deposit location led to a 7% improvement in results. Variations in the split ratio of training and test data led to a reduction in the accuracy of the prediction result with relative stability occurring at a critical point at around 26 training samples out of 130 total samples. When lower numbers of training data were introduced accuracy dropped significantly. In comparison with other machine learning methods, Adaboost is user-friendly due to relatively short training and prediction times, the low likelihood of overfitting and the reduced number of hyperparameters for optimization. Boosting algorithms gave high predictive accuracies, making them a potential data-driven alternative for regional scale and/or brownfields mineral exploration.

     

Phase center modeling for LEO GPS receiver antennas and its impact on precise orbit determination

Most satellites in a low-Earth orbit (LEO) with demanding requirements on precise orbit determination (POD) are equipped with on-board receivers to collect the observations from Global Navigation Satellite systems (GNSS), such as the Global Positioning System (GPS). Limiting factors for LEO POD are nowadays mainly encountered with the modeling of the carrier phase observations, where a precise knowledge of the phase center location of the GNSS antennas is a prerequisite for high-precision orbit analyses. Since 5 November 2006 (GPS week 1400), absolute instead of relative values for the phase center location of GNSS receiver and transmitter antennas are adopted in the processing standards of the International GNSS Service (IGS). The absolute phase center modeling is based on robot calibrations for a number of terrestrial receiver antennas, whereas compatible antenna models were subsequently derived for the remaining terrestrial receiver antennas by conversion (from relative corrections), and for the GNSS transmitter antennas by estimation. However, consistent receiver antenna models for space missions such as GRACE and TerraSAR-X, which are equipped with non-geodetic receiver antennas, are only available since a short time from robot calibrations. We use GPS data of the aforementioned LEOs of the year 2007 together with the absolute antenna modeling to assess the presently achieved accuracy from state-of-the-art reduced-dynamic LEO POD strategies for absolute and relative navigation. Near-field multipath and cross-talk with active GPS occultation antennas turn out to be important and significant sources for systematic carrier phase measurement errors that are encountered in the actual spacecraft environments. We assess different methodologies for the in-flight determination of empirical phase pattern corrections for LEO receiver antennas and discuss their impact on POD. By means of independent K-band measurements, we show that zero-difference GRACE orbits can be significantly improved from about 10 to 6 mm K-band standard deviation when taking empirical phase corrections into account, and assess the impact of the corrections on precise baseline estimates and further applications such as gravity field recovery from kinematic LEO positions.