Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Quantitative elemental mapping of granulite-facies monazite: Textural insights and implications for petrochronology

Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving P–T conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes.     

Integrative taxonomic description of Plakina kanaky,a new polychromatic sponge species from New Caledonia (Porifera: Homoscleromorpha)

Four similar sponges of different colors, all unknown to science, were collected in submarine caves of New Caledonia. We aimed at determining whether the four chromotypes represented different species or phenotypic variations of a unique new species. We used an integrative taxonomic approach combining morphologic, molecular and metabolomic analyses. The main traits that define these specimens are a skeleton made of monolophose, trilophose and tetralophose calthrops only, high chemical diversity and a high abundance and diversity of prokaryotic symbionts. The symbiotic community includes two unique prokaryote morphotypes, which are described for the first time in Homoscleromorpha, and appeared to be vertically transmitted. Although several features slightly differ among chromotypes, the most parsimonious conclusion was to propose a single new species Plakina kanaky sp. nov. Our phylogenetic analysis indicated the paraphyly of the Plakina genus, with P. kanaky sp. nov. belonging to a clade that includes Plakina jani and Plakina trilopha. The present work demonstrates that integrative taxonomy should be used in order to revise the entire Plakinidae family and especially the non‐monophyletic genus Plakina.     

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.     

Seismic hazard analysis in zones of time and space interdependence: An application to São Miguel Island,Azores

The Azores Islands are located in the mid-Atlantic region near the triple junction where the Euro-Asiatic-African-American plates join together. Seismic activity in the area is very high, as can be observed either from historical events since the fifteenth century, from present day microseismicity, and from direct and indirect measurements of recent tectonic deformation. Volcanic activity is also present throughout the region. All available information, even data exhibiting low quality, was used to develop hazard models of São Miguel Island. Source zones were established based on both the global tectonic behaviour of the region and on the local active fault structures. Recurrence laws for São Miguel Island, for which historical information seemed quite incomplete, were obtained from the large events in the entire archipelago and from their remarkable pattern of time and space dependence, and complimented by information on long-term fault deformation (for the longer recurrence periods) and on high precision instrumental network (for the very short recurrence periods). Attenuation laws were derived from data on events felt and/or recorded in the Island. Hazard maps were obtained through a modified version of McGuire's algorithm for several geometries of source areas and results compared with the maximum observed intensity of historical events.     

A ‘mathematical’ spider living on gravel plains of the Namib Desert

In certain areas of the Namib gravel plains a new Ariadna sp. was discovered. It rims its vertical burrow with a stone circle, made on average of seven quartz stones. Some mathematical relationships between hole diameter, stone sizes and weight, and animal size were studied. A correlation was found, and stone selection by this spider postulated. Different hypotheses on the adaptive value of stone circle are suggested.     

Late variscan tectonic evolution by thinning of earlier thickened crust. An Ar---Ar study of the Montagne Noire, southern Massif Central, France

⁴⁰Ar---³⁹Ar age determinations on samples selected on deformational criteria form the basis of a proposal of a new detailed tectonometamorphic history of the Montagne Noire (the southern part of the Massif Central, France).

This range is classically divided into a cover and an axial gneissic and migmatitic core which was metamorphosed under high T/medium P conditions. The basement is structurally overlain by epimetamorphic Paleozoic sediments in the north. In the south, equivalent rocks form a well-known pile of recumbent nappes. The Variscan history of this area comprises early shortening and thickening of the continental crust. The climax of this event took place around 320 Ma ago, as is shown by previous Rb---Sr data and by ⁴⁰Ar---³⁹Ar measurements. New developments in structural analyses have led to a better understanding of the late evolution of the area in terms of diapiric uplift of the core. South-southwestwards verging recumbent nappes have been emplaced and were weakly metamorphosed in their lower parts. This movement was accompanied and followed by dextral extensional wrenching of the Paleozoic cover along the northern and southern margins of the axial zone. Attendantly, ductile shear zones were formed.

In order to decipher the complex history, three structural levels have been dated with the ⁴⁰Ar---³⁹Ar method. These levels are: (1) The migmatitic and gneissic series in the axial core, where micas yield ages of c. 315 Ma; (2) Mylonites from the northern and southern shear zones where biotites and muscovites yield ages of c. 310 Ma; (3) Muscovites and biotites from the epimetamorphic nappe structures yielding ages of c. 297 Ma. The later ages may represent a younger thermal pulse. These data are compared and discussed in the light of previous radiometric studies of the area and precise biostratigraphic constraints. A detailed geodynamic evolution of the studied segment is proposed.     

根据天气类型划分欧洲中期天气预报中心的集合预报产品

该研究的主要目的是找出一种对集合预报产品进行释用的新方法。其基本假定是集合预报要素在一定程度上代表了未来可能发生的天气形势。为了解决天气尺度在中期预报的不可预报性问题 ,引入了天气类型的概念。对集合预报进行划分的方法是 Diday提出的动力模糊法 ,初始划分时的重心由天气类型定义 ,划分用到的距离是位移和最大相关方法。根据城市块 (City- Block)距离找出了影响中国的按冬夏两季划分的天气类型 ,初步划分结果表明 ,欧洲中期天气预报中心的集合预报系统可以预报出横槽转竖型天气类型的演变情况 ,在夏天的预报效果则没有冬天好。     

Surveillance for previously unmonitored organic contaminants in the San Francisco Estuary

The San Francisco Estuary Regional Monitoring Program initiated surveillance monitoring to identify previously unmonitored synthetic organic contaminants in the San Francisco Estuary. Organic extracts of water samples were analyzed using gas chromatography-mass spectrometry in full scan mode. The major contaminant classes identified in the samples were fire retardants, pesticides, personal care product ingredients, and plasticizers. Evidence from the literature suggests that some of these contaminants can persist in the environment, induce toxicity, and accumulate in marine biota and in higher food chain consumers. The major sources of these contaminants into the marine environment are the discharge of municipal and industrial wastewater effluents, urban stormwater, and agricultural runoff. As a proactive effort, it is suggested that surveillance studies be used routinely in monitoring programs to identify and prevent potential problem contaminants from harming the marine environment.