Effects of Compost Addition on Pyrene Removal from Soil Cultivated with Three Selected Plant Species

A greenhouse pot experiment was conducted to investigate the effect of compost addition on the phytoremediation ability of Medicago sativa, Brassica napus, and Lolium perenne in soils contaminated with pyrene. Pyrene concentrations were evaluated after 90 days in contaminated uncultivated amended‐soil, cultivated amended‐soils, and shoots and roots of the three plant species. The addition of compost enhances significantly pyrene dissipation from 16 to 26% in uncultivated soil, whereas in cultivated soils it appears not to have any significant effect on pyrene dissipation, neither pyrene was detectable in shoots and roots of the three species examined. The high partition coefficient of pyrene to compost dissolved organic matter (DOM) and the molar absorptivity values at 280 nm (ε₂₈₀) indicate a high affinity of pyrene to compost DOM molecules, likely due to their aromatic character. These results suggest that compost improves pyrene removal from soil, possibly by promoting its adsorption onto compost DOM. This property is very important in indicating that compost can be used, besides for its amendment capacity, also as a potential tool for remediation of contaminated soils.     

Perfluorinated compounds in blood of Caretta caretta from the Mediterranean Sea

Perfluorinated compounds (PFCs), widely used for their hydro-oil repellent properties, are almost non-degradable in the environment; there is scientific evidence that indicate bioaccumulation. They represent a threat to many organisms, because they are toxic and are endocrine disruptors. Scientific studies have demonstrated the presence of PFCs in blood and liver samples of fish, turtles, birds and mammals of marine ecosystems in different geographical areas. The aim of this study was to determine the distribution of PFOS and PFOA in blood samples of the marine turtle Caretta caretta, using a minimally invasive sampling procedure. 49 blood samples of marine turtle, taken from several Italian marine turtle rescue centers, were analyzed. While PFOA was never detected, measurable concentrations of PFOS were found in 15 blood samples; the values show a range from 1.14 ng/g to 28.51 ng/g (wet wt.). No differences between groups of samples taken from different areas were found.     

Reactive Transport Modeling of ZVI Column Experiments for Nickel Remediation

MIN3P, a multicomponent reactive transport model for variably saturated porous media, is used to simulate the outputs of column tests carried out using zero valent iron (ZVI) for nickel contaminated groundwater remediation. The objective of this study is to investigate the main chemical reactions involved in contaminant removal and the main causes of the reactivity decline of ZVI over time. According to the results of the model the major causes of ZVI reactivity loss is identified in the mineral precipitation of α‐FeOOH on iron surface that probably caused ZVI passivation and led to a decline of the electron transfer rate. An existing empirical relationship between mineral precipitation and the reactivity loss of ZVI, included in the model, reproduced the changes in nickel removal observed during different laboratory column tests.     

Hässeldala – a key site for Last Termination climate events in northern Europe

The Last Termination (19 000–11 000 a BP) with its rapid and distinct climate shifts provides a perfect laboratory to study the nature and regional impact of climate variability. The sedimentary succession from the ancient lake at Hässeldala Port in southern Sweden with its distinct Lateglacial/early Holocene stratigraphy (>14.1–9.5 cal. ka BP) is one of the few chronologically well‐constrained, multi‐proxy sites in Europe that capture a variety of local and regional climatic and environmental signals. Here we present Hässeldala's multi‐proxy records (lithology, geochemistry, pollen, diatoms, chironomids, biomarkers, hydrogen isotopes) in a refined age model and place the observed changes in lake status, catchment vegetation, summer temperatures and hydroclimate in a wider regional context. Reconstructed mean July temperatures increased between c. 14.1 and c. 13.1 cal. ka BP and subsequently declined. This latter cooling coincided with drier hydroclimatic conditions that were probably associated with a freshening of the Nordic Seas and started a few hundred years before the onset of Greenland Stadial 1 (c. 12.9 cal. ka BP). Our proxies suggest a further shift towards colder and drier conditions as late as c. 12.7 cal. ka BP, which was followed by the establishment of a stadial climate regime (c. 12.5–11.8 cal. ka BP). The onset of warmer and wetter conditions preceded the Holocene warming over Greenland by c. 200 years. Hässeldala's proxies thus highlight the complexity of environmental and hydrological responses across abrupt climate transitions in northern Europe.     

Modelling air pollution data by the skew-normal distribution

Particulate matter with an aerodynamic equivalent diameter of up 10 μm is commonly referred to as PM₁₀ and its harmful effects on human health are well known. We model annual means of daily concentrations of PM₁₀ in Italy by the skew-normal distribution, giving theoretical as well as empirical motivations for the model’s choice. Its adequacy is checked through Anderson–Darling statistic. The skew-normal distribution gives a very good fit to the data and it is particularly useful in estimating probabilities of high PM₁₀ concentrations.     

Capacity models for shear strength of exterior joints in RC frames: state-of-the-art and synoptic examination

Damage observed in existing structures after recent earthquake events pointed out the key importance of beam-to-column joints in influencing the global response of reinforced concrete structures. In the last two decades several theoretical and empirical models have been proposed for evaluating shear strength of beam-to-column joints. The present paper reports an overview of the models currently available in the scientific literature for evaluating shear capacity of exterior beam-to-column joints. The present study is the first step of a wide analysis aimed at assessing such models and improving them. Moreover, the uncertainties deriving by applying the mentioned models will be also quantified therein, by means of well-established procedures for probabilistic seismic analysis of structures. The final results of that study are reported within a companion paper.     

Capacity models for shear strength of exterior joints in RC frames: experimental assessment and recalibration

Several theoretical models are currently available in the scientific literature for evaluating the shear capacity of both exterior and interior beam-to-column joints in reinforced concrete (RC) frames. A reasonably wide set of those models, based on either analytical or empirical formulations, has been summarised within a companion work. The present paper firstly presents a wide database which collects results obtained in about two-hundred experimental tests carried out on RC joints. Those results are employed for assessing the above mentioned capacity models by considering a set of experimental data much wider than those usually utilised in the original formulation of such models. Accuracy and reliability of the various models are measured by quantifying some statistical parameters actually describing the relationship between the experimental evidence and the prediction of the various capacity models under consideration. Three relevant classes of joints (namely unreinforced, under reinforced and code-compliant) are considered with the aim of emphasising that the various models perform in a rather different way when applied to those different classes. Finally, a possible recalibration of the various models is proposed with the objective of enhancing their predictive capacity with respect to both the database as a whole and the three classes of RC joints mentioned above.     

Effectiveness of nonlinear static procedures for slender masonry towers

This paper investigates the accuracy of pushover-based methods in predicting the seismic response of slender masonry towers, through comparison with the results from a large number of nonlinear time-history dynamic analyses. In particular, conventional pushover analyses, in both their force- and displacement-based variants, are considered, and seismic assessment through the well-established N2 method is also addressed. The study is conducted by applying a simple non-linear elastic model recently developed and implemented in the computational code MADY to represent slender masonry structures. The model enables both pushover analyses and non-linear dynamic analyses to be performed with a minimum of effort. A multi-record incremental dynamic analysis carried out for a quite large number of structural cases, each of which is subjected to a comprehensive set of dynamic nonlinear analyses, is used to evaluate the accuracy of pushover methods in predicting the global structural response, as represented by the usual capacity curve together with a damage curve, both of which are compared with dynamic envelopes. Local responses, in terms of lateral displacements and the distribution of damage along the tower height are also compared. The results reveal that the key issue in the accuracy of pushover methods is the nature of the lateral load applied, that is, whether it is a force or a displacement. Different ranges of expected deformation are suggested for adopting each type of lateral load to better represent the actual behaviour of masonry towers and their damage under seismic events through pushover methods.     

Internal multiple attenuation by Kirchhoff extrapolation

Surface‐related multiple elimination is the leading methodology for surface multiple removal. This data‐driven approach can be extended to interbed multiple prediction at the expense of a huge increase of the computational burden. This cost makes model‐driven methods still attractive, especially for the three dimensional case. In this paper we present a methodology that extends Kirchhoff wavefield extrapolation to interbed multiple prediction. In Kirchhoff wavefield extrapolation for surface multiple prediction a single round trip to an interpreted reflector is added to the recorded data. Here we show that interbed multiples generated between two interpreted reflectors can be predicted by applying the Kirchhoff wavefield extrapolation operator twice. In the first extrapolation step Kirchhoff wavefield extrapolation propagates the data backward in time to simulate a round trip to the shallower reflector. In the second extrapolation step Kirchhoff wavefield extrapolation propagates the data forward in time to simulate a round trip to the deeper reflector. In the Kirchhoff extrapolation kernel we use asymptotic Green's functions. The prediction of multiples via Kirchhoff wavefield extrapolation is possibly sped up by computing the required traveltimes via a shifted hyperbola approximation. The effectiveness of the method is demonstrated by results on both synthetic and field data sets.     

Combining the standardized precipitation index and climatic water deficit in characterizing droughts: a case study in Romania

This paper characterizes droughts in Romania using the approach of both the standardized precipitation index (SPI) and climatic water deficit (WD). The values of the main climatic factors (rainfall, temperature, reference evapotranspiration, etc.) were obtained from 192 weather stations in various regions of Romania. Penman–Monteith reference evapotranspiration (ET_o-PM) was used to calculate WD as the difference between precipitation (P) and ET_o-PM. SPI was calculated from precipitation values. There is a clear difference between drought and aridity. Drought occurrence determines higher WD values for plains and plateaus and lower climatic excess water (EW) values for high mountains in Romania, depending on the aridity of the specific region considered and drought severity. WD calculated as mean values for both normal conditions and, for all locations studied, various types of drought was correlated with mean annual precipitation and temperature, respectively. The combined approach of WD and SPI was mainly carried out for periods of 1 year, but such studies could also be done for shorter periods like months, quarters, or growing season. The most arid regions did not necessarily coincide with areas of the most severe drought, as there were no correlations between WD and SPI and no altitude-based SPI zones around the Carpathian Mountains, as is the case for other climate characteristics, soils and vegetation. Water resource problems arise where both SPI values characterize extremely droughty periods and WD values are greatly below ?200 mm/year. This combined use of SPI and WD characterizes the dryness of a region better than one factor alone and should be used for better management of water in agriculture in Romania and also other countries with similar climate characteristics.