The carbohydrates in relation to mineralogic and granulometric composition of surface sediments in the karst estuary (River Krka estuary,Yugoslavia)

The investigation of mineral, granulometric and chemical composition of sediments of the River Krka estuary (Yugoslavia) were performed in order to elucidate the origin of the sediments and the pattern of sedimentation. Estuarine surface sediments were found to be fine-grained with a bimodal distribution. Environmental conditions in estuarine sediments favour conservation of the organic matter (anoxic conditions). The carbohydrates in the sediments were investigated to determine whether they are of terrigenous or authigenous origin. Glucose, galactose, mannose, xylose, rhamnose, glucosamine and glucuronic acid were detected in the sediments. Their mutual relationship indicates a preferentially terrigenous source of sedimented organic material in estuarine sediments.     

In situ Raman observation of the crystallization in NaNO3–Na2SO4–H2O solution droplets

Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO₃–Na₂SO₄ system including the formation of the double salt darapskite, Na₃NO₃SO₄·H₂O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na₂SO₄(III), Na₂SO₄(V) and darapskite. The experimental observations are discussed on the basis of the NaNO₃–Na₂SO₄–H₂O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures.     

A bilinear approximation of the surface relief in terrain correction computations

A new method is presented for the computation of the gravitational attraction of topographic masses when their height information is given on a regular grid. It is shown that the representation of the terrain relief by means of a bilinear surface not only offers a serious alternative to the polyhedra modeling, but also approaches even more smoothly the continuous reality. Inserting a bilinear approximation into the known scheme of deriving closed analytical expressions for the potential and its first-order derivatives for an arbitrarily shaped polyhedron leads to a one-dimensional integration with – apparently – no analytical solution. However, due to the high degree of smoothness of the integrand function, the numerical computation of this integral is very efficient. Numerical tests using synthetic data and a densely sampled digital terrain model in the Bavarian Alps prove that the new method is comparable to or even faster than a terrain modeling using polyhedra.     

Possibility for hydroenergetic utilization of relatively researched water streams

Small mountain water streams are lately more interesting from the aspect of hydroenergetic exploitation. Catchments area of smaller rivers and creeks are mostly not enough researched from hydroenergetic aspect, so the most difficult task for small hydropower plant designers is to determine hydroenergetic potential of discussed water streams, from short period of hydrological observations. Very often happens that existing measurement stations on discussed water streams are placed few kilometers from potentially place of water intake and the value of flow is drastically different on these two locations. In this work, two methods for determination of hydrological picture for the chosen location of water intake on discussed river are shown, correlation method and analogy method. Using these methods it is possible to use data that describes measured values of discharge from the old measurement stations, that is exists on the same or adjacent river, to determine flow duration curve on the place of interests. Results given from these two methods are compared with measured values of discharge and precipitation from last period that are collected from location of planed intake. Based on the good agreement of theoretical and measured values, it was concluded that these two methods can be also applied to the adjacent basins. Suggestion of hydroenergetic utilization of discussed water stream and its economic justification is also presented in this work.     

Correlations of natural radionuclides in sediment from Danube

The correlation between specific activities of some natural radionuclides (²³⁸U, ²²⁶Ra, ²³²Th, ⁴⁰K) measured in sediment taken from river bottom was studied. The sediment was taken from the Serbian part of the Danube River. Good correlation between some of the isotopes is observed, so that their specific activity ratios are spread over a lower range than specific activities themselves. This suggests that evaluation of specific activity ratios of some natural radionuclides could be a more sensitive method for the determination of increased levels of some of them than the straightforward analysis of specific activities.     

Dolomitmarmor in der Umgebung der Stadt Prilep und die in ihm vorkommenden Minerale

Zusammenfassung In der Umgebung der Stadt Prilep in Mazedonien kommen an mehreren Stellen in einer hochmetamorphen, aus Glimmerschiefern und Amphiboliten bestehenden Zone Calcit- und Dolomitmarmore vor. In den letzterwähnten wurden bisher Dolomit, Calcit, Korund, Diaspor, -Zoisit, Rutil, Fluorit, Achroit, Pyrit, Muskovit, Illit, Margarit und Chlorit (vonErdmannnsdörfer auch Kossmatit) festgestellt. Diese Paragenese ist regionalmetamorph entstanden.

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Dolomite-marble in the surroundings of the town prilep, macedonia, and its minerals

Summary Calcite- and dolomite-marbles occur in a highly metamorphic series together with micaschists and amphibolites at several localities in the surroundings of Prilep, Macedonia. In the dolomite-marbles, dolomite, calcite, corundum, diaspore, -zoisite, rutile, fluorite, achroite pyrite, muscovite, illite, margarite, chlorite, and kossmatite (the last only byErdmannsdörffer) have been found. The paragenesis is of regional metamorphic origin.

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Spectral analysis of the “Koshava” wind

Summary “Koshava” is a gusty wind of changeable intensity, blowing from a south-easterly direction, over Serbia, Romania and Bulgaria. It is caused by the interaction between the synoptic circulation and the orography of the Carpathian and the Balkan mountains. This paper analyzes wind data measured at the Belgrade-Observatory during the longest period of consecutive days of “Koshava” which occurred from 14 January to 13 February 1972. Mean hourly wind speed data has been examined using spectral analysis. The power spectra are calculated using autocorrelation spectral analysis, the multi-taper method and wavelet transform. The maximum of which is about 122 h (5 days) corresponds to the time span of synoptic processes.     

Prediction of the abiotic degradability of organic compounds in the troposphere

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.     

A note on the performance of the multiply-upstream semi-Lagrangian advection schemes for one-dimensional nonlinear momentum conservation equation

Summary Two-time-level multiply-upstream semi-Lagrangian schemes were examined in the case of the self-advecting, one-dimensional nonlinear momentum conservation equation. The shock formation process was analyzed. It is pointed out that the shocks cannot be created in the truncated systems satisfying the Pudykiewicz, Benoit and Staniforth criterion.The numerical integrations were restricted to 12 h. It was shown that, at least in the sub-CFL range, increased complexity of the scheme can compensate reduced horizontal resolution. A considerable sensitivity of the schemes with respect to the time step was detected. In the super-CFL mode, several windows on various time scales were found within which the Pudykiewicz, Benoit and Staniforth criterion was satisfied. The time step of 1.44 times the maximum time step allowed by the CFL criterion was used in the semi-Lagrangian runs.The super-CFL, semi-Lagrangian solutions were diverging progressively from the sub-CFL ones as the forecasts advanced. This was also reflected in the energy spectra.Unacceptably large energy losses were encountered in the super-CFL, semi-Lagrangian runs. Most of these losses could be explained by the reduced mean wind speed, i.e., the amplitude of the zero wavenumber wave. At the same time, the energy content in the shorter waves increased. In a more complex model, such a situation would resemble a loss of zonal, and an increase of transient eddy kinetic energy.A trajectory error measure was defined as the maximum absolute value of the distance between the actual arriving point of the particle originating at the estimated departure point, and the grid point assumed to be the arrival point in the semi-Lagrangian procedure. In contrast to the sub-CFL regime, this measure could reach a considerable fraction of the grid distance in the computations with the super-CFL time steps.In the physical system considered, the trajectories are determined only by the velocities at the departure points. With the semi-Lagrangian schemes the distances traveled by the particles are estimated on the basis of the velocities at the points downstream with respect to the departure points. Thus, unless the solution is smooth (in space and time) on the scales of the extrapolation distances/times, the upstream extrapolation does not promise the convergence of the solution.With 16 Figures     

Dynamics of the Kopački Rit (Croatia) wetland floodplain water regime

Kopa?ki Rit Nature Park is part of the Danube River natural floodplain and one of the last oases of wild life in the Danube River Basin. Due to its extraordinary value, it was inscribed on the list of Wetlands of International Importance in 1993. More than 2,000 species have been registered in this area, which consists of lakes, canals, grassland, marshland and forests. Even the number of investigations which have been performed on its biological and ecological features, hydrological and water resources characteristics, as a prerequisite for ecohydrological analyses, are still rather unknown in the scientific community. Mainly the Danube River and partly the River Drava cause flooding of Kopa?ki Rit and inundations enter the area from both the northern and southern parts. Results of hydrological and meteorological analysis show a decreasing trend of both mean and minimum, annual water levels in the Rivers Drava and Danube (respectively 1.8 and 1.38 cm/year). These reductions in water level can reduce the replenishment periods of Kopa?ki Rit Nature Park. In addition, a significant rise of mean annual air temperature and consequently water temperature (data 1988–2011) may be causing increasing evapotranspiration and loss of water within Kopa?ki Rit. But an encouraging counteracting finding is that, the results of frequency analysis show, even a discharge of 5-years’ return period on the River Danube inundates 70 % of the Danube floodplain and Kopa?ki Rit Nature Park.