Origin and Distribution of Hydrogen Sulfide in Oil-Bearing Basins,China

Abstract: The concentration of hydrogen sulfide gas (H2S) varies greatly in the oil-bearing basins of China, from zero to 90%. At present, oil and gas reservoirs with high H2S concentration have been discovered in three basins, viz. the Bohai Bay Basin, Sichuan Basin and the Tarim Basin, whereas natural gas with low H2S concentration has been found in the Ordos Basin, the Songliao Basin and the Junggar Basin. Studies suggest that in China H2S origin types are very complex. In the carbonate reservoir of the Sichuan Basin, the Ordos Basin and the Tarim Basin, as well as the carbonate-dominated reservoir in the Luojia area of the Jiyang depression in the Bohai Bay Basin, Wumaying areas of the Huanghua depression, and Zhaolanzhuang areas of the Jizhong depression, the H2S is of Thermochemical Sulfate Reduction (TSR) origin. The H2S is of Bacterial Sulphate Reduction (BSR) origin deduced from the waterflooding operation in the Changheng Oilfield (placanticline oil fields) in the Songliao Basin. H2S originates from thermal decomposition of sulfur-bearing crude oil in the heavy oil area in the Junggar Basin and in the Liaohe heavy oil steam pilot area in the western depression of the Bohai Bay Basin. The origin types are most complex, including TSR and thermal decomposition of sulfcompounds among other combinations of causes. Various methods have been tried to identify the origin mechanism and to predict the distribution of H2S. The origin identification methods for H2S mainly comprise sulfur and carbon isotopes, reservoir petrology, particular biomarkers, and petroleum geology integrated technologies; using a combination of these applications can allow the accurate identification of the origins of H2S. The prediction technologies for primary and secondary origin of H2S have been set up separately.     

Mechanism of Varve Formation and Paleoenvironmental Research at Lake Bolterskardet, Svalbard, the Arctic

On the basis of observation of thin sections and 137Cs data, laminations in sediment are interpreted to be varves in Bolterskardet Lake (78°06' N, 16°01' E), Svalbard, the Arctic. Varves appear under a petrologic microscope as couplets of dark-silt and light-clay layers. The mechanism of varve formation is surmized as follows: each silt layer is the production of sediment inflow interpreted as mainly derived from snowmelt during summer; each clay layer was deposited in a stillwater environment during an ice-cover period. A light -clay layer provides an important index bed to identify the annual interface. The high accumulation rates, long period of ice cover, and topographically closed basin are probably all critical factors in forming and preserving varves. Varve thickness is known to be controlled mainly by summer temperature. The variation of varve thickness in Lake Bolterskardet can then be used to reconstruct summer temperature. The varve series show that there has been distinct decade-scale variability of summer temperature over the past 150 years. Warm periods occurred in the 1860s, around 1900, the 1930s, 1950s, and 1970s, and in the last 20 years. The varved sediments of Lake Bolterskarde preserve an ideal record for high-resolution paleoclimatic and paleoenvironmental research in this data-sparse area.     

一种新型人工“流体包裹体”：融合二氧化硅毛细管技术

利用融合二氧化硅毛细管技术制作了纯H2O体系、纯CO2体系、H2O-NaCl体系和H2O-CO2体系的人工包裹体样品,并对样品进行了显微测温和激光拉曼光谱测试工作。实验结果显示毛细管样品中的流体成分具有代表性,而且常规的流体包裹体显微测温和显微激光拉曼光谱分析技术完全适于毛细管样品的测试。对样品的显微测温和拉曼光谱研究...     

库车前陆褶皱—冲断带前缘大型盐推覆构造

塔里木盆地北部库车前陆褶皱-冲断带构造-地层层序可划分为中生界盐下层序、古新统一始新统盐层层序和渐新统一第四系盐上层序。盐岩层序的岩性主要为灰白色、浅灰色盐岩、膏岩、泥灰岩和紫红色碎屑岩,厚110～3000 m。盐岩层的存在使库车前陆褶皱-冲断带发育-系列盐相关构造,其中最引人注目的是盐推覆构造。野外地质调查、地震资料解释、遥感资料和钻井资料揭示,沿库车前陆褶皱-冲断带前缘西秋立塔克山发育大型盐推覆构造,总体呈近东西走向,并略呈往西南凸出的弧形展布,沿走向延伸超过200km,由北往南逆冲推覆距离达30km以上。主断层沿古新统-始新统盐岩层发育,外来推覆体由古新统-始新统盐层层序和渐新统-第四系盐上层序组成,表现为受断层控制的单面山,逆冲推覆在原地中生代-新生代地层之上。地质分析和剖面复原结果表明,盐推覆构造主要形成于新近纪末期以来的喜马拉雅晚期阶段,现今仍具有强烈的活动性。由于不均匀推覆作用,在盐推覆构造的不同地段,逆冲推覆距离、冲断层产状、外来岩系和原地岩系的叠置关系以及盐相关构造的发育都有较大差异,显示出走向上分段性特点。库车前陆褶皱-冲断带前缘盐推覆构造的形成演化受区域挤压作用、重力滑动和重力扩展作用控制。     

南海西部浮游有孔虫含量与水深关系定量研究

南海西部4°～18°N,1085～115°E海域表层沉积物中有孔虫定量分析表明,从陆架至深海盆区,随着水深增加,底栖有孔虫丰度总体呈下降趋势;而浮游有孔虫在上陆坡区水深200～2 000 m处最丰富,向浅水和深水方向,其丰度均下降,浮游有孔虫百分含量（P）与水深（D）有明显的相关关系。但在陆架区和陆坡－深海盆区,两者关系完全不同：在陆架区随水深增加浮游有孔虫百分含量明显增大,而在陆坡－深海盆区,两者呈负相关关系。经定量拟合水深小于200 m的陆架区,浮游有孔虫含量与水深满足关系式：lnD＝0.021P＋3.208;而在水深大于200 m的陆坡－深海盆区,两者满足D＝－5263P＋52 105.2。这主要是由于陆架区随水深增加,浮游有孔虫增加,但水深大于200 m后,碳酸盐的溶解起主要作用,浮游有孔虫比底栖有孔虫更易于溶解,造成其含量随水深增加而下降。     

渤海湾盆地济阳坳陷热历史及构造—热演化特征

根据镜质组反射率和磷灰石裂变径迹古温标方法模拟的济阳坳陷地温演化情况表明,地温梯度在坳陷的演化过程中是逐渐降低的。在孔店组-沙河街组沉积期间地温梯度是较高的,最高可达5.5～6.0℃/100m,但在此期间地温梯度下降较快,在东营组沉积时期降为3.5～4.5℃/100m;在馆陶组沉积时期地温梯度变化很小,至第三纪末地温梯度已降至目前的3.5℃/100m左右。济阳坳陷的构造沉降特征表现为孔店组至沙四段沉积期间(65～43Ma)的快速构造沉降阶段和沙三段沉积(43Ma)以后的热沉降阶段,盆地的地热史模拟结果和构造沉降所揭示的坳陷演化阶段具有很好的对应关系。坳陷热历史研究为渤海湾盆地的构造-热演化提供了重要的认识。     

三峡地区震旦系碳酸盐岩碳氧同位素特征

本文对三峡地区秭归庙河陡山沱组第一段至第三段，宜昌棺材崖陡山沱组第三段上部至灯影组底部以及四溪灯影组石板滩段和白马沱段碳酸盐岩碳氧同位素组成特点的研究结果表明，三峡地区震旦系碳同位素组成与全球新元古代广布的后Martinoan冰期地层δ^13C的分布模式基本一致，本文还讨论了地层中碳同位素组成与生物演化和地层层序发展的关系，指出陡山沱组一段白云岩中δ^13C的负异常可以作为震旦系底界划分的标志，最晚Varanger冰期在三峡地区由陡山沱组三段上部出现的三级层序界面所替代，震旦系内部陡山沱组一段和三段可能形成于Marinoan冰期之后，伊迪卡拉生物分异发展之前，而陡山沱组四段及上覆灯影峡组则大致与国外伊迪卡拉期地层对比。     

华北东濮凹陷异常高压与流体活动及其对储集砂岩成岩作用的制约

Basin-Mod软件模拟显示东濮凹陷35Ma左右孔隙流体已出现较高异常压力，综合分析表明欠压实作用是发育异常高压的主要机制，处于异常高压带内的泥岩存在微裂隙带，是异常高压流体压裂的直接结果并可以成为流体运移的通道，通过典型研究区砂岩压实（溶）量，压实－胶结关系，沉积参数－储集物性的对比，表明异常高压流体的确对砂岩的压实作用具有抑制作用，另一方面，自生石英流体包体均一温度大部分在105－145℃之间，频数呈多峰式展布，可能显示幕式流体活动。该温度范围内由于没有有机酸的大规模生产，泥岩频繁发生的幕式流体泄压活动，使得富含CO3^2-的高压流体在注入砂岩（低压区）孔隙后易与Ca^2 ,Mg^2 ,Fe^2 等离子结合，导致砂岩储层发生强烈的（晚期）碳酸盐沉淀和胶结作用。     

青藏高原及邻区三阶段构造演化与成矿演化

青藏高原具有典型的三分时空结构和3种尺度动力学体系.青藏高原由3个构造结调整的3个盆山体系组成, 北部、东部和南部3个盆山体系分别受控于古亚洲洋及西伯利亚、西太平洋和特提斯三大构造域, 经历了前寒武纪超大洋一超大陆耦合、加里东期-印支期-燕山期和喜马拉雅早期自北而南的洋陆耦合和板内盆山耦合三大构造发展过程, 形成于地核流层驱动的地核(或全球) 动力学过程、地幔流层驱动的地幔(或岩石圈) 动力学过程和地壳流层驱动的地壳(或大陆) 动力学过程, 构成历史地球系统动力学系统.青藏高原不是印度板块与欧亚板块碰撞的结果, 而是形成于下地壳流动驱动的板内盆山作用, 可分为以中、新生代有序向南迁移式构造隆升、水平运动、地质作用和成矿作用为特征的板内造山阶段和以脉动式快速隆升、垂直运动、地理作用和环境变化为特征的均衡成山阶段.构造谱系决定了成矿谱系, 区域构造叠加演化造成地壳成熟度的不断增加和矿床密集度的不断提高.青藏高原3个构造成矿演化阶段包括1.8~1.4Ga、500~420Ma、300~260Ma、180~120Ma、65~30Ma、23~7Ma等6个主金属成矿期, 1.8~1.4Ga超大陆裂解事件形成与深地幔火山岩浆作用有关的大红山式海相火山喷流沉积改造型铁铜矿、金川式与镁铁-超镁铁质岩有关的铜镍硫化物浆矿床, 500~420Ma、300~260Ma和180~120Ma特提斯裂解环境下形成罗布莎式地幔剪切-改造脉型(豆荚状) 铬铁矿床、呷村式海相火山成因块状硫化物矿床等, 180~120Ma、65~30Ma和23~7Ma是青藏高原自北而南板内伸展环境下大规模成矿期, 形成驱龙式斑岩铜矿床、哀牢山式剪切带型金矿床、金顶式陆相盆地沉积型铅锌矿床, 构成一个完整的地球系统成矿动力学演化体系.      

NATURE OF PRECIPITATION AND ACTIVITY OF CUMULUS CONVECTION DURING THE 1991 MEIYU SEASON OF CHANGJIANG-HUAIHE RIVER BASIN

Seasonal variability regarding the nature of precipitation and the activity of cumulus convectionduring the 1991 Meiyu season of Changjiang-Huaihe River Basin(Jianghuai)has been investigatedby calculating apparent heat source/apparent moisture sink and analyzing TBB(cloud-topblackbody radiation temperature)data.It is found that three periods of strong ascending motionduring the Meiyu season lead to three episodes of heavy rain,and the latent heat due to theprecipitation is of the sole heat source of the atmosphere.The nature of precipitation showsdistinct seasonal variability,from frontal precipitation of the first episode to the extremely strongconvective precipitation of the third episode.TBB field of East Asia may well reflect not only theintensity of convection and rainfall,but also the movement of rain belt and convection belt.In thewhole Meiyu season.convection belt mainly stays in Jianghuai.but may shift within the domain ofEast Asia.Its locating in Jianghuai or not determines the maintenance or break of Meiyu.In thethird episode,the narrow convection belt over Jianghuai is mainly caused by southwest monsoonwhich takes moist and convective atmosphere from tropical ocean.