Are Visible Fractures Accurate Predictors of Flow and Mass Transport in Fractured Till?

Tracer experiments conducted in the laboratory on undisturbed core samples (<7.3-cm-diameter) have been a standard method for estimating hydraulic and transport properties of fractured till since the 1980s. This study assesses the relationship between visible fractures on the top and bottom of core samples and the resulting hydraulic and mass transport properties of the core. We hypothesized that more visible fractures would indicate the presence of a well-connected fracture network, leading to greater hydraulic conductivity (K) values and earlier chemical breakthrough times. To test this hypothesis, water flow and bromide (Br-) tracer experiments were performed on 10, 16-cm diameter, 16-cm-tall samples of fractured Dows Formation till from central Iowa. Visually identifiable fractures were present on the top and bottom of every sample. Results indicate that the visual identification of fractures does not predict a connected fracture network, as some samples produced breakthrough curves showing rapid first arrival times and shapes characteristic of solute transport in a fractured medium, while others appeared similar to an unfractured medium. No correlation was found between the number of visible fractures and K (Pearson's r = 0.25), or Br- first arrival time (r = −0.33), but a strong negative correlation between K and first arrival time (r = −0.92). Results indicate that the sample volume was not large enough to reliably contain a connected fracture network. Thus, testing large volumes of till at the field scale coupled with fracture-flow modeling likely represents the best approach for estimating hydraulic and mass transport properties for fractured till.     

Removal of ammonia toxicity in marine sediment TIEs: a comparison of Ulva lactuca,zeolite and aeration methods

Toxicity Identification Evaluations (TIEs) can be used to determine the specific toxicant(s), including ammonia, causing toxicity observed in marine sediments. Two primary TIE manipulations are available for characterizing and identifying ammonia in marine sediments: Ulva lactuca addition and zeolite addition. In this study, we compared the efficacy of these methods to (1) remove NH(x) and NH(3) from overlying and interstitial waters and (2) reduce toxicity to the amphipod Ampelisca abdita and mysid Americamysis bahia using both spiked and environmentally contaminated sediments. The utility of aeration for removing NH(x) and NH(3) during a marine sediment TIE was also evaluated preliminarily. In general, the U. lactuca and zeolite addition methods performed similarly well at removing spiked NH(x) and NH(3) from overlying and interstitial waters compared to an unmanipulated sediment. Toxicity to the amphipod was reduced approximately the same by both methods. However, toxicity to the mysid was most effectively reduced by the U. lactuca addition indicating this method functions best with epibenthic species exposed to ammonia in the water column. Aeration removed NH(x) and NH(3) from seawater when the pH was adjusted to 10; however, very little ammonia was removed at ambient pHs ( approximately 8.0). This comparison demonstrates both U. lactuca and zeolite addition methods are effective TIE tools for reducing the concentrations and toxicity of ammonia in whole sediment toxicity tests.     

EVALUATING THE SIMILARITY OF GEOGRAPHIC FLOWS*

The problem of comparing geographic flows is explored. We present a simple statistical method and compare it to a cartographic method. Each is applied to a specific example in which migration flows are contrasted with fiscal transfers. The analysis suggests that while neither method is adequate by itself, there might be great advantages to using them in tandem.     

Was there ice along the shore of the Sea of Galilee during the last 12,000?—Reply to a comment by Prange et al. (2007) and a comment by Friedman (2007)

Prange et al. (2007) question our reconstruction of the Sea of Galilee (Lake Kinneret) paleoclimate and argue that a “careful” analysis of the paleoclimatic analysis leads to much smaller cooling events than we have considered. By and large, their “careful” analysis is based on correlating the paleotemperatures of the Lake with those of the northern Red-Sea that (geographically) is much closer to the Lake than the two Mediterranean cores that we used. Ironically, their argument contradicts Friedman’s (2007) statements (the second comment on our original paper), which are based on still-closer cores and support our larger cooling choices. This issue alone would be enough to dismiss the uniqueness of PAL argument but there is another issue with their work that we wish to comment on. In support of their own small cooling argument, PAL present winter correlation maps that indeed show a stronger correlation of the northern Red-Sea SST to the lake SST than the correlation of Mediterranean SST with the lake SST. This seemingly correct correlation argument of PAL is totally false (for both daily and millennial time scales) because it has no climatological basis. On the daily time scale, all the storms that reach the Lake originate in the Mediterranean Sea (to the west of the lake), not the Red-Sea (which lies 700 km south of the lake). Also, although the lake and the Red-Sea are only 700 kilometers apart, their climates are very different because they are subject to two totally different air masses. While the climate of the Red-Sea region is desert-like, the climate of the region surrounding the lake is a typical wet Mediterranean climate. Seasonal correlation maps (and even monthly maps) such as those presented by the authors filter out the storms that control the winter climate in the lake region because these storms occur on a daily scale. With this filtering, all that one is left with is the low frequency first baroclinic mode, which merely reflects the Rossby radius scale (measured from the lake). On the millennial time scale, cold events in the lake regions (from an earlier period) have been attributed to Bond cycles and Heinrich events both of which are global and not local processes. As such, they are probably forced by variability in the solar radiation rather than a local process implied by PAL. Overall, all that the PAL correlation shows for both daily and millennial time scales is that changes in the temperature in the Red-Sea occur at the same time as they do in the Lake. But this does not say anything about the dynamics in question and does not imply that it is better to use records from the Red-Sea (which does not lie within the path of the zonal winds reaching the Lake). Neglecting this issue (as proposed by PAL) distorts the physics and reminds us of the classical statistical example for the limitations involved in the interpretation of correlation—the incidence of lung cancer is strongly correlated with the incidence of carrying matches in ones pocket even though the matches do not cause the cancer and the cancer does not force one to carry matches.     

To what extent can a long-term temperature target guide near-term climate change commitments?

The question of appropriate timing and stringency of future greenhouse gas (GHG) emission reductions remains an issue in the discussion of mitigation responses to the climate change problem. It has been argued that our near-term action should be guided by a long-term vision for the climate, possibly a long-term temperature target. In this paper, we review proposals for long-term climate targets to avoid ‘dangerous’ climate change. Using probability estimates of climate sensitivity from the literature, we then generate probabilistic emissions scenarios that satisfy temperature targets of 2.0, 2.5, and 3.0°C above pre-industrial levels with no overshoot. Our interest is in the implications of these targets on abatement requirements over the next 50 years. If we allow global industrial GHG emissions to peak in 2025 at 14 GtCeq, and wish to achieve a 2.0°C target with at least 50% certainty, we find that the low sensitivity estimate in the literature suggests our industrial emissions must fall to 9 GtCeq by 2050: equal to the level in 2000. However, the average literature sensitivity estimate suggests the level must be less than 2 GtCeq; and in the high sensitivity case, the target is simply unreachable unless we allow for overshoot. Our results suggest that in light of the uncertainty in our knowledge of the climate sensitivity, a long-term temperature target (such as the 2.0°C target proposed by the European Commission) can provide limited guidance to near-term mitigation requirements.     

From partial melting to retrogression in the Pointe Geologie migmatitic complex: a history of heterogeneous distribution of fluids

In the Pointe Géologie area (66°40 S; 140°00 E; Terre Adélie, East Antarctica), the Paleoproterozoic basement consists in a migmatitic complex of metasedimentary origin. Metasediments underwent a thermal event, leading to the high-grade amphibolite facies assemblages biotite–cordierite–sillimanite and to dehydration melting reactions at 4–6 kbar and 700±50 °C, followed by retrogression in greenschist facies.

In most of the archipelago, K-feldspar gneisses (KFG) are characterized by a Sil+Crd+Kfs+Bt assemblage and many K-feldspar-rich leucosomes. Locally, a spectacular rock type occurs as North dipping bands of about 10 m thick and consists in nodular gneisses (NG) that display less abundant, K-feldspar-poor leucosomes.

Commonly, the retrograde imprint facies is quite weak in KFG and only expressed by sporadic Bt–Ms±And equilibrium assemblage, whereas it developed more extensively in NG. A pseudosection calculated at constant P=4 kbar shows that the differences between NG and KFG assemblages can be considered to be mainly driven by difference in H₂O proportions and much less by differences in FeO/MgO or K₂O/MgO ratios. The hydrated assemblage (Bt–Ms nodules) in NG requires at least 10–20% more H₂O than the Crd+Kfs+Sil/And assemblage does in KFG. Parageneses and mineral compositions indicate that this difference in H₂O occurred early in the history, at least as early as the anatectic stage. Therefore, differences between NG and KFG are related to the variation in partial melting features (water distribution, proportion of melt extraction), which appears to be spatially controlled by cryptic tectonic structures. The particular shape and orientation of NG bands are interpreted as a complex history of melt extraction in the Pointe Géologie area which could involve a two stage melting process.     

Direct observation of adakite melts generated in the lower continental crust, Fiordland, New Zealand

Adakites have a distinct chemistry that links them to melting of a mafic source at high pressure. They have been attributed to melting of subducted oceanic crust or melting of the mafic crustal roots of thick continental arcs, and are an important contrast to mantle wedge melting as a means of generating continental crust. We report the first direct evidence for the generation of adakitic melts in mafic lower continental crust, in an exhumed Cretaceous arc in the South Island of New Zealand. The lower crustal Pembroke Granulite has the bulk chemistry and partial melting textures involving peritectic garnet appropriate for a source region for an adakitic melt. The melt migrated from the area through a fracture network now filled with trondhjemitic veins. Emplacement of the melt was in the upper crust of the Cretaceous section, illustrated by the presence of coeval adakites in the upper crustal Nelson-Westland region.     

Iron distribution in the octahedral sheet of dioctahedral smectites. An Fe K-edge X-ray absorption spectroscopy study

The distribution of iron atoms in the octahedral sheet of a series of dioctahedral smectites with varying unit-cell composition and iron content was investigated by Fe K-edge XAS spectroscopy. First-step analysis reveals that the patterns corresponding to backscattering by atoms located between 3 and 4 Å from the absorbing atom are very sensitive to the relative amount of light (Si, Al, Mg) and heavy (Fe) atoms. Detailed modelling of this domain then provides valuable information on the number of iron atoms surrounding octahedral iron. By comparing the number of iron neighbours deduced from EXAFS with that determined from unit-cell composition assuming a statistical distribution, three groups of montmorillonites can be distinguished: (1) clay samples from Wyoming display an ordered distribution of iron atoms; (2) clay samples from Georgia, Milos, China and Washington exhibit a close to random distribution of iron atoms; (3) clay samples from North Africa, Germany, Texas and Arizona display extensive iron clustering. These results complement previously obtained IR results and show that the combination of these two spectroscopic techniques could provide an additional crystal-chemistry-based framework for typological analysis of montmorillonite deposits.     

Differential effects of salinity and soil saturation on native and exotic plants of a coastal salt marsh

In many southern California salt marshes, increased freshwater inflows have promoted the establishment of exotic plant species. A comparative study showed that a native, perennial, high marsh dominant,Salicornia subterminalis, and an invasive, exotic annual grass,Polypogon monspeliensis, responded differently to soil salinity and saturation.Salicornia subterminalis seeds and young plants were more salt tolerant, and the native grew best at high salinities (23 g 1^?1 and 34 g 1^?1) in greenhouse experiments. In contrast, the exotic had reduced growth at high salinities relative to nonsaline controls. The native,S. subterminalis, grew poorly as the duration of soil saturation increased from 2 wk to 32 wk, butP. monspeliensis grew equally well for all durations tested. The response ofS. subterminalis andP. monspeliensis to increased salinity indicated that salt applications might be used to protect native vegetation in salt marshes where salt-sensitive exotics are a problem. A field experiment verified that a salt application of 850 g m^?2 mo^?1 for 3 mo was sufficient to control the exotic, while not noticeably affecting the native. Thus, salt applications may be a practical method for controllingP. monspeliensis invasions in areas receiving urban runoff or other unwanted freshwater inflows.