Floodplain sedimentation: Quantities,patterns and processes

This paper presents the result of measurements of floodplain sedimentation using sediment traps. The study was carried out on two embanked floodplains along the Rivers Rhine and Meuse in The Netherlands during a 3 day flood in January 1993. Raster maps of sediment accumulation were made by interpolating the measurements from the traps using block kriging. The sediment maps show clear patterns in sediment accumulation, together with the estimated interpolation errors. Average sediment accumulation ranges between 0·57 and 1·0 kg m^?2. High sediment accumulation is found on the levees (4 kg m^?2 or more) and on low lying areas (1·6 kg m^?2); sediment accumulation decreases with distance from the main channel. The sedimentation patterns are related to floodplain topography and sediment transporting mechanisms. Sediment transport by turbulent diffusion as well as by convection can be recognized. Also, flood duration and the process of sediment settling out in ponding water in closed depressions are important. The applied method allows comparison of the results with raster-based sedimentation models.     

Detection of underground cavities with monofrequency electromagnetic tomography between boreholes in the frequency range 100 MHz to 1 GHz1

In order to detect underground cavities, we have designed a geophysical method based on the interaction of a monochromatic electromagnetic wave in the frequency band 100 MHz to 1 GHz with the ground situated between two boreholes. Three different approaches are involved in the design of this EM tomographic method.

• 1 The application of an ‘exact’ theory is used to calculate artificial data, based on an integral equation method. These data are inverted using a tomographic algorithm whose basic assumptions are rather coarse. The results show that, however, cavities can very well be detected and their position recovered.
• 2 Data are obtained with a physical reduced-scale model in a water tank, in which all parameters are known in advance. The inversion process confirms the validity of the method.
• 3 Underground cavities are actually detected.

The above approaches are described and discussed and results are shown. The equipment involved and its operation is quite simple: the surface devices are commercially available and only the transmitter and receiver antennae must be specially built. The method is shown to be quite efficient and its cost should be reasonably low.     

The Effects of Climate Change on the Hydrology and Water Resources of the Colorado River Basin

The potential effects of climate change on the hydrology and water resources of the Colorado River basin are assessed by comparing simulated hydrologic and water resources scenarios derived from downscaled climate simulations of the U.S. Department of Energy/National Center for Atmospheric Research Parallel Climate Model (PCM) to scenarios driven by observed historical (1950–1999) climate. PCM climate scenarios include an ensemble of three 105-year future climate simulations based on projected `business-as-usual'(BAU) greenhouse gas emissions and a control climate simulation based on static 1995 greenhouse gas concentrations. Downscaled transient temperature and precipitation sequences were extracted from PCM simulations, and were used to drive the Variable Infiltration Capacity (VIC) macroscale hydrology model to produce corresponding streamflow sequences. Results for the BAU scenarios were summarized into Periods 1, 2, and 3 (2010–2039,2040–2069, 2070–2098). Average annual temperature changes for the Colorado Riverbasin were 0.5 °C warmer for control climate, and 1.0, 1.7, and 2.4 °C warmer for Periods 1–3, respectively, relative to the historicalclimate. Basin-average annual precipitation for the control climate was slightly(1%) less than for observed historical climate, and 3, 6, and 3%less for future Periods 1–3, respectively. Annual runoff in the controlrun was about 10% lower than for simulated historical conditions, and 14, 18, and 17% less for Periods 1–3, respectively. Analysis of watermanagement operations using a water management model driven by simulated streamflows showed that streamflows associated with control and future BAU climates would significantly degrade the performance of the water resourcessystem relative to historical conditions, with average total basin storage reduced by 7% for the control climate and 36, 32 and 40% for Periods 1–3, respectively. Releases from Glen Canyon Dam to the LowerBasin (mandated by the Colorado River Compact) were met in 80% of years for the control climate simulation (versus 92% in the historical climate simulation), and only in 59–75% of years for the future climate runs. Annual hydropower output was also significantly reduced for the control and future climate simulations. The high sensitivity of reservoir system performance for future climate is a reflection of the fragile equilibrium that now exists in operation of the system, with system demands only slightly less than long-term mean annual inflow.     

Distribution of sterol and fatty alcohol biomarkers in particulate matter from the frontal structure of the Alboran Sea (S.W. Mediterranean Sea)

Sterol and fatty alcohol biomarkers were analyzed in suspended and sinking particles from the water column (20–300 m) of the Almeria–Oran frontal zone to characterize the biogenic sources and biogeochemical processes. Diatom- and haptophyte-related sterols were predominant at all sites and vertical distributions of sterol, and fatty alcohol biomarkers in sinking particles were markedly different from suspended particles. In contrast to the relatively fresh sinking particles with elevated concentrations of phyto- and zooplanktonic sterols, suspended particles were extensively degraded with increasing depth and exhibited a more terrestrial and zooplanktonic signature with depth.Sterol and alcohol biomarkers distributions and δ¹³C values from the jet core and the associated gyre of Atlantic waters showed a decoupling between the sinking particles of 100- and 300-m depth, demonstrating the influence of lateral advection in the frontal zone. In contrast, vertical transport of the particulate organic matter in Mediterranean waters was interpreted from the similar isotopic and molecular composition at both depths. The high abundance of phytosterols and phytol below the euphotic zone at 100 m signified that downwelling of biomass occurred on the downstream side of the gyre. The high concentrations of phytosterols and POC, in combination with the high phytosterols/phytol ratio, indicated the accumulation of detrital plant material in the oligotrophic Mediterranean waters near the frontal zone.A higher contribution of phytol in the sinking particles collected during the night at the surface of the jet and at the upstream side of the gyre provided evidence of diel vertical zooplankton migration and important grazing by herbivorous zooplankton.Carbon isotope ratios of sterols confirmed that the 24-ethylcholest-5-en-3β-ol, commonly associated with terrestrial sources, was a substantial constituent of the phytoplankton in this area. However, the more δ¹³C depleted values obtained for this compound in suspended particles suggested that there was some terrestrial contribution that only becomes evident after degradation of the more labile marine organic matter.     

Massive Upland to Wetland Conversion Compensated for Historical Marsh Loss in Chesapeake Bay,USA

Sea level rise leads to coastal transgression, and the survival of ecosystems depends on their ability to migrate inland faster than they erode and submerge. We compared marsh extent between nineteenth-century maps and modern aerial photographs across the Chesapeake Bay, the largest estuary in North America, and found that Chesapeake marshes have maintained their spatial extent despite relative sea level rise rates that are among the fastest in the world. In the mapped region (i.e., 25% of modern Chesapeake Bay marshland), 94 km² of marsh was lost primarily to shoreline erosion, whereas 101 km² of marsh was created by upland drowning. Simple projections over the entire Chesapeake region suggest that approximately 100,000 acres (400 km²) of uplands have converted to wetlands and that about a third of all present-day marsh was created by drowning of upland ecosystems since the late nineteenth century. Marsh migration rates were weakly correlated with topographic slope and the amount of development of adjacent uplands, suggesting that additional processes may also be important. Nevertheless, our results emphasize that the location of coastal ecosystems changes rapidly on century timescales and that sea level rise does not necessarily lead to overall habitat loss.     

Potential Orthopyroxene,Clinopyroxene and Olivine Reference Materials for In Situ Lithium Isotope Determination

Over 1400 electron probe and 700 ion probe microanalyses were performed on eleven mineral separates to evaluate their potential as reference materials for in situ Li isotopic determination. Our results suggest the homogenous distributions of major elements, Li and its isotopes for each sample. Hence, these samples are suitable to be used as reference materials for in situ measurements of Li abundance and Li isotopes by secondary ion mass spectrometry (SIMS) or laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS). These samples have the advantage of mitigating probable matrix effects during calibration owing to the wide range of compositions. The effect of composition on the δ⁷Li of olivine measured by SIMS is a linear function of composition, with δ⁷Li increasing by 1.0‰ for each mole per cent decrease in forsterite component.     

Impact of Non-Methane Hydrocarbons on Tropospheric Chemistry and the Oxidizing Power of the Global Troposphere: 3-Dimensional Modelling Results

The impact of natural and anthropogenicnon-methane hydrocarbons (NMHC) on troposphericchemistry is investigated with the global,three-dimensional chemistry-transport model MOGUNTIA.This meteorologically simplified model allows theinclusion of a rather detailed scheme to describeNMHC oxidation chemistry. Comparing model resultscalculated with and without NMHC oxidation chemistryindicates that NMHC oxidation adds 40–60% to surfacecarbon monoxide (CO) levels over the continents andslightly less over the oceans. Free tropospheric COlevels increase by 30–60%. The overall yield of COfrom the NMHC mixture considered is calculated to beabout 0.4 CO per C atom. Organic nitrate formationduring NMHC oxidation, and their transport anddecomposition affect the global distribution of NO _x and thereby O₃ production. The impact of theshort-lived NMHC extends over the entire tropospheredue to the formation of longer-lived intermediateslike CO, and various carbonyl and carboxyl compounds.NMHC oxidation almost doubles the net photochemicalproduction of O₃ in the troposphere and leads to20–80% higher O₃ concentration inNO _x -rich boundarylayers, with highest increases over and downwind ofthe industrial and biomass burning regions. Anincrease by 20–30% is calculated for the remotemarine atmosphere. At higher altitudes, smaller, butstill significant increases, in O₃ concentrationsbetween 10 and 60% are calculated, maximizing in thetropics. NO from lightning also enhances the netchemical production of O₃ by about 30%, leading to asimilar increase in the global mean OH radicalconcentration. NMHC oxidation decreases the OH radicalconcentrations in the continental boundary layer withlarge NMHC emissions by up to 20–60%. In the marineboundary layer (MBL) OH levels can increase in someregions by 10–20% depending on season and NO _x levels.However, in most of the MBL OH will decrease by10–20% due to the increase in CO levels by NMHCoxidation chemistry. The large decreases especiallyover the continents strongly reduce the markedcontrasts in OHconcentrations between land and oceanwhich are calculated when only the backgroundchemistry is considered. In the middle troposphere, OHconcentrations are reduced by about 15%, although dueto the growth in CO. The overall effect of thesechanges on the tropospheric lifetime of CH₄ is a 15%increase from 6.5 to 7.4 years. Biogenic hydrocarbonsdominate the impact of NMHC on global troposphericchemistry. Convection of hydrocarbon oxidationproducts: hydrogen peroxides and carbonyl compounds,especially acetone, is the main source of HO _x in theupper troposphere. Convective transport and additionof NO from lightning are important for the O₃ budgetin the free troposphere.