Primary Ca-rich carbonatite magma and carbonate-silicate-sulphide liquid immiscibility in the upper mantle

A primary carbonate phase with Ca/(Ca+Mg) in the range 0.85–0.95 has been identified in a metasomatized, depleted harzburgite nodule from Montana Clara Island, Canary Islands; textural relations show that this carbonate represents a quenched liquid. Although magnesian carbonate melts have been described from upper mantle peridotites, this is the first reported occurrence of a primary magma within peridotite nodules which has the composition of calciocarbonatite, by far the most common carbonatite type occurring in crustal complexes. The carbonate in the Montana Clara harzburgite host is restricted to wehrlitic alteration zones and is intimately associated with a second generation of minerals, mainly olivine, clinopyroxene and spinel, with glass of syenitic composition, and with Fe−Cu-rich sulphides. The metasomatic assemblage was formed by reaction of a sodiumbearing dolomitic melt, derived from a somewhat deeper level in the upper mantle, with the harzburgite mineral assemblage at a pressure of 15 kbars, or lower. As a result of the reaction the residual carbonatite melt became more enriched in calcium. The calciocarbonatite and sulphide phases almost invariably form globules in the silicate glass, indicating the existence of three immiscible liquids under upper mantle conditions. Several alkaline complexes contain carbonatites occurring with syenitic rock types and its seems feasible that the formation of such close associations might have been influenced by processes of liquid immiscibility which took place under upper mantle conditions. Editorial responsibility: I. Parsons     

X-ray absorption near-edge spectra of transition metal disulfides FeS2 (pyrite and marcasite), CoS2, NiS2 and CuS2, and their isomorphs FeAsS and CoAsS

Metal K- and L₃-, sulfur K- and arsenic K- and L₃-edge X-ray absorption near-edge spectra of a series of metal disulfides, FeS₂ (both pyrite and marcasite), CoS₂, NiS₂, and CuS₂, and their isomorphs, FeAsS and CoAsS, are presented. The features in this region of these spectra are interpreted using band structure and molecular orbital calculations in terms of the transitions from the 1s or 2p_3/2 state to unoccupied states. The 3d transition metal L₃-edge spectra of these materials show dependence on the degree of multiplet splitting in the final state, and thus offer less information on the electronic ground state. There are substantial differences in the spectra of the isostructural materials, whereas the spectra of the isotopes pyrite and marcasite show several similarities, illustrating the dependence of near-edge region on electronic structure.     

Greenhouse,gaia and global change: a personal view of the pitfalls of interdisciplinary research

Recognition of the possible consequences of global‐scale pollution has spawned research programs loosely termed ‘global change’. These programs are hampered by the problems of academic apartheid first identified by those attempting to examine the Gaia hypothesis. Global change is, in many ways, a synonym for global geography: the study of processes and their consequences at the human/environment interface. Assessment of highly complex systems demands integrative, interdisciplinary research; the search for, and recognition of, negative feedbacks; and, most importantly, the courage to formulate hypotheses which bridge many single disciplines. I illustrate some of the pitfalls of interdisciplinary research with reference to my own research in atmospheric science, by the application of atmospheric science to the study of climatic impacts and consideration of the integration of climatic impacts into global change.     

A fracture-mechanical cellular automaton model of seismicity

We present a cellular automaton model which simulates the process of seismogenesis using rules for evolution which are derived from the field of fracture mechanics, and include an interplay of positive and negative feedbacks. We describe the implementation of this model, and its analysis, in a massively parallel environment using the Connection Machine. Starting from a lattice with a fractal distribution of fracture toughnesses, theb value evolves in a way which closely mimics both the evolutions ofb value observed in the laboratory and derived from earthquake catalogues, reaching a broad and irregular maximum in the period preceding a major event, and declining rapidly during catastrophic failure. We conclude that the processes modelled are a reasonable representation of those occurring in Nature, and that the cellular automaton paradigm is a valuable way of simulating these processes on a large scale in an economical manner.     

Late Palaeozoic arc flank and fore‐arc basin sequence of the New England fold belt in the stanage bay region,central Queensland

Devonian and Carboniferous (Yarrol terrane) rocks, Early Permian strata, and Permian‐(?)Triassic plutons outcrop in the Stanage Bay region of the northern New England Fold Belt. The Early‐(?)Middle Devonian Mt Holly Formation consists mainly of coarse volcaniclastic rocks of intermediate‐silicic provenance, and mafic, intermediate and silicic volcanics. Limestone is abundant in the Duke Island, along with a significant component of quartz sandstone on Hunter Island. Most Carboniferous rocks can be placed in two units, the late Tournaisian‐Namurian Campwyn Volcanics, composed of coarse volcaniclastic sedimentary rocks, silicic ash flow tuff and widespread oolitic limestone, and the conformably overlying Neerkol Formation dominated by volcaniclastic sandstone and siltstone with uncommon pebble conglomerate and scattered silicic ash fall tuff. Strata of uncertain stratigraphic affinity are mapped as ‘undifferentiated Carboniferous’. The Early Permian Youlambie Conglomerate unconformably overlies Carboniferous rocks. It consists of mudstone, sandstone and conglomerate, the last containing clasts of Carboniferous sedimentary rocks, diverse volcanics and rare granitic rocks. Intrusive bodies include the altered and variably strained Tynemouth Diorite of possible Devonian age, and a quartz monzonite mass of likely Late Permian or Triassic age.

The rocks of the Yarrol terrane accumulated in shallow (Mt Holly, Campwyn) and deeper (Neerkol) marine conditions proximal to an active magmatic arc which was probably of continental margin type. The Youlambie Conglomerate was deposited unconformably above the Yarrol terrane in a rift basin. Late Permian regional deformation, which involved east‐west horizontal shortening achieved by folding, cleavage formation and east‐over‐west thrusting, increases in intensity towards the east.     

Recent advances in isotopes as palaeolimnological proxies

Isotope geochemistry is an essential part of environmental and climate change research and over the last few decades has contributed significantly to our understanding of a huge array of environmental problems, not least in palaeolimnology and limnogeology. Here we describe some of the recent developments in the use of stable isotopes in palaeo-lake research. These are: better preparation, analysis, and interpretation of biogenic silica oxygen and silicon isotopes; extraction and characterisation of specific compounds such as leaf waxes and algal lipids for isotope analysis; determining the excess of ¹³C–¹⁸O bonds in clumped isotopes; and the measurement of multiple isotope ratios in chironomid chitin. These advances have exciting prospects and it will be interesting to see how these techniques develop further and consequently offer a real advancement in our science over the next decade.     

Genetic diversity and metal tolerance of two marine species: a comparison between populations from contaminated and reference sites

Long-term contamination of the marine environment surrounding a lead smelter offered a unique opportunity to examine how pollutants might have acted to alter genetic characteristics of populations of organisms in the receiving system. This study used random amplified polymorphic DNA analysis to compare the genetic diversity of populations of the prawn, Leander intermedius, and the isopod, Platynympha longicaudata from the smelter discharge site with reference populations. The genetic diversity of the prawn population from the smelter discharge site (Port Pirie) was lower than that found in one reference population, and not significantly different from the other two reference populations. Genetic diversity of the Port Pirie population of isopods was found to be significantly lower than that of all reference populations. Prawns and isopods were also exposed to metal mixtures in the laboratory in a similar ratio to that found in seston near the smelter effluent discharge site. Both pre-exposed and reference populations of prawns tolerated elevated levels of metals and exhibited no significant difference in response. This contrasted with the isopods, with the pre-exposed isopod population showing greater tolerance to elevated metal levels compared with the reference population. These results highlight the need to include a number of reference populations for comparative purposes in genetic diversity studies, and the need to assess the influence of pollution on the genetic diversity of more than one species if genetic diversity analyses are to be used to gauge remediation success.     

Biological data from sharks landed within the United Arab Emirates artisanal fishery

Landing site and market surveys of sharks landed along the Arabian Gulf coast of the United Arab Emirates were undertaken between October 2010 and September 2012 to obtain biological data from this artisanal fishery. Data were collected on the size and sex of 12 482 individuals representing 30 species. Maximum sizes of Carcharhinus sorrah, C. amblyrhynchoides and Hemipristis elongata were extended by at least 300?mm total length (TL) compared with published global maxima. The size at 50% maturity was determined for males of five species and this indicated that the males of smaller shark species (<1 000 mm maximum TL) in the fishery were largely mature. For many species, including Loxodon macrorhinus and Mustelus mosis, overall sex ratios were male-biased, indicating that sexual segregation is likely in those species. Furthermore, sex ratios for several species, such as Rhizoprionodon acutus, showed differences across seasons. Overall, the landings contained a high proportion of juveniles, causing concerns about the sustainability of this fishery. Biological parameters of a number of species differed from those recorded earlier for the region, demonstrating a need for additional local data collection to support the development of management measures.