Contamination of surface waters by mining wastes in the Milluni Valley (Cordillera Real,Bolivia): Mineralogical and hydrological influences

This study is one of very few dealing with mining waste contamination in high altitude, tropical-latitude areas exploited during the last century. Geochemical, mineralogical and hydrological characterizations of potentially harmful elements (PHEs) in surface waters and sediments were performed in the Milluni Valley (main reservoir of water supply of La Paz, Bolivia, 4000 m a.s.l.), throughout different seasons during 2002–2004 to identify contamination sources and sinks, and contamination control parameters. PHE concentrations greatly exceeded the World Health Organization water guidelines for human consumption. The very acidic conditions, which resulted from the oxidation of sulfide minerals in mining waste, favoured the enrichment of dissolved PHEs (Cd > Zn ? As ? Cu ∼ Ni > Pb > Sn) in surface waters downstream from the mine. Stream and lake sediments, mining waste and bedrock showed the highest PHE content in the mining area. With the exception of Fe, the PHEs were derived from specific minerals (Fe, pyrite; Zn, Cd, sphalerite, As, Fe, arsenopyrite, Cu, Fe, chalcopyrite, Pb, galena, Sn, cassiterite), but the mining was responsible for PHEs availability. Most of the PHEs were extremely mobile (As > Fe > Pb > Cd > Zn ∼ Cu > Sn) in the mining wastes and the sediments downstream from the mine. pH and oxyhydroxides mainly explained the contrasted availability of Zn (mostly in labile fractions) and As (associated with Fe-oxyhydroxides). Unexpectedly, Pb, Zn, As, and Fe were significantly attenuated by organic matter in acidic lake sediments.     

Channel and floodplain sediment dynamics in a reach of the tropical meandering Rio Beni (Bolivian Amazonia)

The study investigates interactions, water and sediment exchanges, between a rapidly migrating meander and its associated floodplain at fine temporal and spatial scales. The Beni River, an Amazonian free meandering river, makes the transition between Andean ranges and Amazonian lowlands. For the period 2002–2006, an assemblage of tools and methods (water and sediment discharges, topometric and bathymetric surveys, sedimentation rate estimations from unsupported ²¹⁰Pb and sediment trapping system) was used to jointly analyse the influence on the sediment budget of external factors (mainly water and sediment discharge) and the inherent behaviour of the system. The main issue addressed is the investigation of the complex relationship between ‘morphological conditioning’ of fluvial landform and process. The first part of the study was undertaken with the aim of linking erosion–deposition in an active meander with water and sediment fluxes. The three inter‐annual evolutions are characterized by very unequal sediment budgets; the first two intervals underwent predominant erosion, and the latter slight accumulation. Digital elevation models, evaluated for the active meander, demonstrate that sedimentation on the point bar depends more on external factors than erosion of the concave bank, which fluctuates slightly. The second part of the study, focusing on water and sediment exchanges between active bend and floodplain, examines the respective parts played by overbank flow and by an abandoned channel on the diffusion and sequestration of sediment. The association of short‐ and long‐term estimation of sedimentation rates suggests that floodplain construction is associated with two different processes and rhythms of sediment transportation. Finally, a sediment budget is proposed for the Beni River in the upper part of the Amazonian lowlands. Copyright © 2010 John Wiley & Sons, Ltd.     

Parametrization of peatland hydraulic properties for the Canadian land surface scheme

Abstract

A hydraulic parametrization is developed for peatland environments in the Canadian Land Surface Scheme (CLASS). Three ‐wetland soil classes account for the typical variation in the hydraulic characteristics of the uppermost 0.5 m of organic soils. Review of the literature reveals that saturated hydraulic conductivity varies from a median of 1.0 × 10^?7m/s in deeply humified sapric peat to 2.8 × 10^?4 m/s in relatively undecomposed fibric peat. Average pore volume fraction ranges from 0.83 to 0.93. Parameters have been designed for the soil moisture characteristic curves for fibric, hemic and sapric peat using the Campbell (1974) equation employed in CLASS, and the van Genuchten (1980) formulation. There is little difference in modelled soil moisture between the two formulations within the range of conditions normally found in peatlands. Validation of modelled water table depth and peat temperature is performed for a fen in northern Québec and a bog in north‐central Minnesota. The new parametrization results in a more realistic simulation of these variables in peatlands than the previous version of CLASS, in which unrealistic mineral soil “equivalents “ were used for wetland soil climate modelling.