Evidences of Holocene transgression on Domingos Petrolini Swamp, southern coastal plain, Rio Grande do Sul, Brazil

The Domingos Petrolini Swamp, located on the Southern Coastal Plain of Rio Grande do Sul, near the town of Rio Grande, constitutes an ample holocene lagoonal deposit. Events related to the holocene transgression and their diverse phases of glacial-eustatic ocillations were found through palynological analysis. Bases on these palynological data, four distinct phases to the paleoenvironmental evolution of the ecosystem were identified. It has also shown a transgressive restricted marine sequence on the base, which suggests the existence of a coastal brackish lagoon or a marisme type of environment. Later, there was a gradation for continentality conditions along with a scarce pollinical record. The third phase is characterized by the presence of marine components and halophyte vegetation, showing another transgressive event in that place. Lastly, the end of direct marine influence over the swamp was recorded and also the vegetation development as it appears these days.     

Bearing capacity of strip footings on spatially random soils using sparse polynomial chaos expansion

A probabilistic model is presented to compute the probability density function (PDF) of the ultimate bearing capacity of a strip footing resting on a spatially varying soil. The soil cohesion and friction angle were considered as two anisotropic cross‐correlated non‐Gaussian random fields. The deterministic model was based on numerical simulations. An efficient uncertainty propagation methodology that makes use of a non‐intrusive approach to build up a sparse polynomial chaos expansion for the system response was employed. The probabilistic numerical results were presented in the case of a weightless soil. Sobol indices have shown that the variability of the ultimate bearing capacity is mainly due to the soil cohesion. An increase in the coefficient of variation of a soil parameter (c or φ) increases its Sobol index, this increase being more significant for the friction angle. The negative correlation between the soil shear strength parameters decreases the response variability. The variability of the ultimate bearing capacity increases with the increase in the coefficients of variation of the random fields, the increase being more significant for the cohesion parameter. The decrease in the autocorrelation distances may lead to a smaller variability of the ultimate bearing capacity. Finally, the probabilistic mean value of the ultimate bearing capacity presents a minimum. This minimum is obtained in the isotropic case when the autocorrelation distance is nearly equal to the footing breadth. However, for the anisotropic case, this minimum is obtained at a given value of the ratio between the horizontal and vertical autocorrelation distances. Copyright © 2012 John Wiley & Sons, Ltd.     

Analysis of drought condition and risk in Peninsular Malaysia using Standardised Precipitation Index

Contrary to the belief that Peninsular Malaysia experiences wet condition throughout the year, prolonged dry condition has lately become a recurrent phenomenon in this region. As a result, country's agricultural sector and water resources have been under severe constraints from this situation. To get a clearer picture of the dry condition in Peninsular Malaysia, the Standardised Precipitation Index, based on the data of monthly rainfall from 50 stations, is derived. Spatial analysis is used to illustrate the percentage of occurrences of dry and very dry events. To evaluate the potential risk due to the dry conditions, we modelled the joint distribution of severity and duration of dry condition by means of bivariate copula. Several copula models were tested, and the model, which best represents the relationship between severity and duration, is determined using Akaike information criterion. Based on the results, the return period for the drought severity, based on the longest duration of drought at each station, can be estimated. This enables the drought risk to be calculated, thus planning on the measures to minimise the impact of a prolonged drought to the societies, which can be done by the relevant authorities.     

The effects of diagenesis on the reservoir characters in sandstones of the Late Cretaceous Pab Formation,Kirthar Fold Belt,southern Pakistan

The Maastrichtian Pab Formation in the southern part of Pakistan is composed of fine- to very coarse-grained texturally mature quartz arenite and subordinate sublitharenite varieties. The sandstones have undergone intense and complex diagenetic episodes due to burial and uplift. Diagenetic modifications were dependent mainly on the clastic composition of sandstone, burial depth and thrust tectonics. Diagenetic events identified include compaction, precipitation of calcite, quartz, clay minerals and iron oxide/hydroxide, dissolution and alteration of unstable clastic grains as feldspar and volcaniclithic fragments as well as tectonically induced grain fracturing. The unstable clastic grains like feldspar and lithic volcanic fragments suffered considerable alteration to kaolinite and chlorite. Dissolution and alteration of feldspar and volcanic lithic fragments and pressure solution were the main sources of quartz cements. Mechanical compaction and authigenic cements like calcite, quartz and iron oxide/hydroxide reduced the primary porosity, whereas dissolution of clastic grains and cements has produced secondary porosity. Chlorite coatings on clastic grains have prevented quartz cementation. Coarse-grained, thick bedded packages of fluviodeltaic, shelf delta lobe and submarine channels facies have higher average porosity than fine-grained, thin bedded and bioturbated sandstone of deeper shelf and abyssal plain environments and these facies are concluded to be possible future hydrocarbon prospects.     

Equivalent granular state parameter and undrained behaviour of sand�Cfines mixtures

State parameter defined using void ratio, e, and the steady-state line has been shown to be effective in predicting the undrained behaviour of sand. However, steady-state line for sand with fines is dependent on fines content. To overcome this problem, the concept of equivalent granular void ratio, e*, has been well investigated. However, the conversion from e to e* has been essentially a back-analysis process. A methodology for converting e to e* without the need of a back-analysis process was first presented. The concept of equivalent granular state parameter, ψ*, defined in terms of e*, and equivalent granular steady-state line was then developed. An extensive experimental study was conducted to investigate whether ψ* can capture the effects of fines content, and thus can be used to correlate undrained behaviour of sand–fines mixtures without the need of separately considering the effects of fines content. This study suggested that the effective stress path and deviatoric stress–strain responses in undrained shearing can be correlated with the ψ* value at the start of undrained shearing irrespective of fines content.     

Hydrocarbon prospects across Narmada-Tapti rift in Deccan trap, central India: Inferences from integrated interpretation of magnetotelluric and geochemical prospecting studies

As the Mesozoic sediments contribute most of the oil and gas reserves of the world, we present an integrated interpretation approach using magnetotellurics (MT) and surface geochemical prospecting studies to demarcate hydrocarbon prospective Gondwana (Mesozoic) formations underneath the Deccan flood basalts of Late Cretaceous age across Narmada-Tapti rift (between Bhusawal and Barwah) in Central India. The MT interpretation shows deep (∼5 km) basement structure between southern and central part of the MT profile however, it gradually becomes shallower to either ends of the profile with a predominant basement depth reduction in the northern end compared to the southern end. The geophysical results suggest thick (2-3.5 km) Mesozoic sediments in the area characterized by deep basement structure. The geochemical analysis of the near surface soil samples indicate higher concentrations of light gaseous hydrocarbons constituents over the area marked with thick sub-basalt Mesozoic formations. Analyses of the geochemical data imply that these hydrocarbons are genetically related, generated from a thermogenic source and these samples fall in the oil-producing zone. The temperature-depth estimations in the region supports favorable temperature conditions (80-120 °C) for oil generation at basement depths.     

Evaluation of an Ultrafiltration Method for Surfactant Recovery and Reuse During In Situ Washing of Contaminated Sites: Laboratory and Field Studies

Feasibility studies were conducted on the use of ultrafillration to recover surfactant from aqueous waste streams generated from the in situ surfactant washing of a site contaminated with poly-chlorinated biphenyls (PCBs) and oils. A Romicon Model HF-Lab-5 ultrafiltration unit and three types of ultrafillration membranes (PM500, XM50, and CM50) were evaluated for their permeability to a nonionic surfactant previously selected for the in situ washing. Results from laboratory studies using the XM50 membrane cartridge showed that 78 percent of the surfactant passed through the membrane surface (permeate) and was recovered.
Two field-pilot tests of the ultrafiltralion system were conducted using leachate containing a mixture of water, oils, PCBs, and surfactant that was collected from an in situ surfactant-washing demonstration test. Forty-six percent of the surfactant (mass) was recovered during the first field test using the XM50 membrane. The membrane retained 94 percent of the PCBs and 89 percent of the oils. The second field test showed that the PM500 membrane recovered 67 percent of the surfactant in the permeate and retained more than 90 percent and 83 percent of the PCBs and oils, respectively. This study indicates that a significant volume of a nonionic surfactant can be recovered from leachatc mixture containing PCBs and oils by ultrafillration. The recovered surfactant could be reused to improve the economic viability of in situ surfactant washing of contaminated sites.     

Migration of Petroleum Products Through Sandy Hydrogeologic Systems

Laboratory column experiments were carried out to study the migration of petroleum products through a sandy porous medium. It was found that the oil pressure needed to displace water from the pores of the sand medium increased with depth below the top of the column. While oil under negative pressure displaced water through the variably unsaturated zone, a significant vertical column of oil was needed to displace water from the pores at the water table. These results indicate that oil penetration to and below the water table will occur only if the porous medium is highly conductive and the rate of oil leak is high. For small to moderate leak rates and hydraulic conductivities, oil would preferentially spread laterally through the zones above the water table. This process of spreading could serve as a natural barrier to severe aquifer contamination by petroleum products.
A simplified procedure was developed to give an order-of-magnitude estimate of the preferred subsurface migration pathways of leaked petroleum products. This procedure utilizes the main drainage and wetting curves for oil and water and the interfacial pressure between these two fluids. This approach could be useful in guiding exploratory investigations, reducing both the risk for further spreading of the contaminants and the investigative cost.     

Prediction of climate change in Brunei Darussalam using statistical downscaling model

Theoretical and Applied Climatology - Climate is changing and evidence suggests that the impact of climate change would influence our everyday lives, including agriculture, built environment,...