Limitations of Monitoring Wells for the Detection and Quantification of Petroleum Products in Soils and Aquifers

Theoretical analysis and laboratory column experiments were carried out to investigate the conditions required for petroleum products (oil) to flow into a well installed through a sandy porous medium contaminated with the oil. The results indicated that oil would flow into a well only after a layer of "free oil" is formed in the adjacent porous medium. Because significant quantities of oil could be stored in the porous medium under the influence of capillary suction prior to the formation of the zone of free oil, the presence of oil in a well would indicate an advanced stage of oil contamination of the subsurface. While monitoring wells could be used to delineate the extent of the free-oil plume and the plume of dissolved petroleum constituents, they are not useful for delineating the extent of capillary held oil.
The experimental results also indicated that the ratio of the oil-layer thickness in the well to that in the porous medium is not a constant as is sometimes assumed in practice. Further, estimates of the oil thickness in the medium based on the oil thickness in wells and on capillary properties measured in the laboratory were sensitive to the values of the parameters used in these estimates. The measured thickness of the oil layer in a monitoring well alone may not yield reliable estimates of the amount of oil in the subsurface, and assuming that the oil-thickness ratio is a constant can lead to inadequate site assessments and inappropriate remedial plans.     

A quantitative study of the energy release in the aftershocks of the Bhuj earthquake, 2001, India, using Lg phase

The devastating earthquake on 26 January 2001 at Bhuj, India, resulted in large-scale death and destruction of properties of several million US dollars. The moment magnitude of the earthquake was 7.7 and its maximum focal intensity exceeded X in MM scale. The rate of aftershocks of this earthquake, recorded at Gauribidanur seismic array station (GBA), shows a monotonic decay with time superposed with oscillations. For the Indian continent the Lg phase is a prominent arrival at regional distances. The estimate of Lg amplitude is obtained by optimally fitting the Lg wave train to a exponential decay curve. The logarithm of these amplitudes and logarithm of root mean square (rms) value of actual amplitudes of the Lg are calibrated with USGS m_b to create a local m_bLg magnitude scale. The energy released from these aftershocks is calculated from the rms value of Lg phase. The plot of cumulative energy release with time follows the power law of the form t^p, superposed with oscillations. The exponent of the power law, p, is estimated both by a time-window scanning method and by an interpolation method. The value of p is 0.434 for time-window scanning method and 0.432 for the interpolation method. The predominant periods found in the oscillatory part of the cumulative energy, obtained by differencing the observed from the power law fit, are 10.6, 7.9, 5.4, 4.6 and 3.5 h for time-window scanning method. The corresponding periods for interpolation method are 13.4, 11.5, 7.4, 4.2, 3.5, 2.6 and 2.4 h.     

Copula based analysis of rainfall severity and duration: a case study

The main objective of this study is to investigate the joint distribution of rainfall severity and rainfall duration in the state of Victoria, Australia, based on monthly rainfall data from selected rain-gauge stations which are located in the north-eastern and south-western parts of the state, during the period from 1950 to 2010. Traditional approach for considering the joint distribution of rainfall characteristics using standard bivariate modeling presents some limitations that can be circumvented by using Copula models. Archimedean and extreme-value copulas will be used to obtain the bivariate distribution of rainfall severity and duration. The Standard Precipitation Index (SPI), which is employed extensively to quantify rainfall severity, will be discussed in detail. Several goodness of fit tests will be performed to find the best fitting copulas and the results will be summarized. The final fitted copulas will then be applied to obtain the joint and conditional return periods from a minimum of two years to one hundred years of rainfall events in Victoria.     

Trace gases and PM2.5-bound metal abundance over a tropical urban environment,South India

Pre and Post-Monsoon levels of ambient SO₂, NO₂, PM_2.5 and the trace metals Fe, Cu, etc. were measured at industrial and residential regions of the Kochi urban area in South India for a period of two years. The mean PM_2.5, SO₂ and NO₂ concentrations across all sites were 38.98?±?1.38 µg/m³, 2.78?±?0.85 µg/m³ and 11.90?±?4.68 µg/m³ respectively, which is lower than many other Indian cities. There was little difference in any on the measured species between the seasons. A few sites exceeded the NAAQS (define acronym and state standard) and most of the sites exceeded WHO (define acronym and state standard) standard for PM_2.5. The average trace metal concentrations (ng/m³) were found to be Fe (32.58)?>?Zn (31.93)?>?Ni (10.13)?>?Cr (5.48)?>?Pb (5.37)?>?Cu (3.24). The maximum concentration of trace metals except Pb were reported in industrial areas. The enrichment factor, of metals relative to crustal material, indicated anthropogenic dominance over natural sources for the trace metal concentration in Kochi’s atmosphere. This work demonstrates the importance of air quality monitoring in this area.

     

Relevance of Pentane- and Hexane-Utilizing Bacterial Indicators for Finding Hydrocarbon Microseepage: A Study from Jamnagar Sub-basin, Saurashtra, Gujarat, India

Mesozoic sediments are source rocks for nearly half the world’s hydrocarbon reserves. Hence, there is great interest in the oil industry to know the trap and sub-trappean sediment thickness and their extent in the trap covered regions of Jamnagar study area. The microbial prospecting method is applied in the Jamnagar sub-basin, Gujarat for evaluating the prospects for hydrocarbon exploration by investigating the anomalous abundance of n-pentane- and n-hexane-oxidizing bacteria of this area. A total of 150 near-surface soil samples were collected in Jamnagar sub-basin, Gujarat for the evaluation of hydrocarbon resource potential of the basin. In this study, bacterial counts for n-pentane-utilizing bacteria range between 1.09 × 10² and 9.89 × 10⁵ cfu/g and n-hexane-utilizing bacteria range between 1.09 × 10² and 9.29 × 10⁵ cfu/g. The adsorbed hydrocarbon gases consisting of ethane plus hydrocarbons (ΣC₂₊) of 1–977 ppb and n-pentane (nC₅) of 1–23 ppb. The integrated geomicrobial and adsorbed soil gas studies showed the anomalous hydrocarbon zones nearby Khandera, Haripur, and Laloi areas which could probably aid to assess the true potential of the basin. Integrated geophysical studies have shown that Jamnagar sub-basin of Saurashtra has significant sediment thickness below the Deccan Traps and can be considered for future hydrocarbon exploration.     

Integrated geoelectrical resistivity and hydrogeochemical methods for delineating and mapping heavy metal zone in aquifer system

A novel study on using geoelectrical resistivity, soil property, and hydrogeochemical analysis methods for delineating and mapping of heavy metal in aquifer system is presented in this paper. A total of 47 surveys of geoelectrical resistivity with Wenner configuration were conducted to determine the subsurface and the groundwater characteristics. The groundwater sample from 53 existing wells and 2 new wells has been analyzed to derive their water chemical content. The chemical analysis was done on the soil sample obtained from new two wells and from selected locations. The water and soil chemical analysis results from the new two wells were used as calibration in resistivity interpretation. The occurrence of heavy metal in aquifer system was expected to detect using the geoelectrical resistivity survey for the whole study area. The result of groundwater analysis shows that the groundwater sample contains a relatively low concentration of Fe (<?0.3 mg/L) elongating from the south up to the middle region. While in the middle and the northwestern, Fe concentration is relatively high (around 12 mg/L). Chemical analysis of soil sample shows that in the lower resistivity zone (<?18 Ωm), Al and Fe concentrations are comparatively high with an average of 68,000 and 40,000 mg/kg, respectively. Starting from the middle to the northwestern zone, the resistivity value appears to be low. It is definitely caused by higher Al and Fe concentration within the soil, and it is supported also by lower total anion content in the groundwater. While the resistivity value of more than 40 Ωm in aquifers is obtained in the zone which Fe concentration is relatively lower in the soil but not present in the groundwater. Correlation Fe concentration in the soil and Fe concentration in the groundwater sample shows the trend of positively linear; however, the Al concentration in soil has no correlation with Al content in groundwater. Finally, the probability of high heavy metal zone in the aquifer system is easily delineated by the distribution of geoelectrical resistivity presented in depth slice shapes which extend from the Boundary Range Composite Batholith in the north to the northwest.     

Korrelation der Sporenzonen der Oberen Trias und des Jura im Mittleren Orient und in Süddeutschland

Zusammenfassung Bei der sporenstratigraphischen Gliederung des mittleren Mesozoikums im Mittleren Orient konnten vom Nor bis zur Unteren Kreide 6 Sporenzonen unterschieden werden: Unterkreide:Ischyosporites variegatus — Rouseisporites laciniatus — Cicatricosisporites-Zone Malm:Ischyosporites variegatus — Rouseisporites laciniatus-Zone Dogger:Ischyosporites variegatus — Duplexisporites problematicus-Zone Lias:Concavisporites — Duplexisporites problematicus-Zone Rät:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus-Zone Nor:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer-ZoneVergleichende Untersuchungen ergaben, daß diese Sporenzonen auch auf Süddeutschland übertragbar sind und den faunistischen Grenzen entsprechen. Nur die sporenstratigraphische Festlegung der Nor/Rätsowie der Dogger/Malm- und der Malm/Unterkreide-Grenze bedürfen noch der Verifizierung.

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In the middle Mesozoic of the Middle East 6 spore-assoziations could be distinguished from the Norian to the Lower Cretaceous: Lower Cretaceous:Ischyosporites variegatus — Rouseisporites laciniatus — Cicatricosisporites zone Upper Jurassic:Ischyosporites variegatus — Rouseisporites laciniatus zone Middle Jurassic:Ischyosporites variegatus — Duplexisporites problematicus zone Lower Jurassic:Concavisporites — Duplexisporites problematicus zone Rhaetian:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus zone Norian:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer zone.The interregional validity and the correspondance of these spore zones with the faunistic boundaries could be substantiated in equivalent sequences in Southern Germany. However, the palynological definition of the Norian/Rhaetian, Middle/Upper Jurassic and Jurassic/Cretaceous boundaries have still to be confirmed in other regions since suitable sections have not been available in Southern Germany.

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Résumé Dans le Mésozoïque moyen du Moyen Orient, six zones de spores peuvent être distinguées du Norien au Crétacé inférieur: Crétacé inférieur: Zone àIschyosporites variegatus — Rouseisporites laciniatus — Cicatricosisporites Jurassique supérieur: Zone àIschyosporites variegatus — Rouseisporites laciniatus Jurassique moyen: Zone àIschyosporites variegatus — Duplexisporites problematicus Jurassique inférieur: Zone àConcavisporites — Duplexisporites problematicus Réthien: Zone àConcavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus Norien: Zone àConcavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer Une étude comparative montre que les mêmes zones de spores existent en Allemagne du sud et qu'elles correspondent aux limites faunistiques. Toutefois, les limites Norien/ Rhétien, Dogger/Malm et Malm/Crétacé inférieur demandent à être vérifiées.

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- : : Ischyosporites variegatus —Rouseisporites laciniatus — Cicatricosisporites : Ischyosporites variegatus — Rouseisporites laciniatus : Ischyosporites variegatus — Duplexisporites problematicus : Concavisporites — Duplexisporites problematicus : Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus : Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer. , , . , /, / / .

     

Pile Head Cyclic Lateral Loading of Single Pile

This paper presents an elastic continuum model using an extended nonlinear Davies and Budhu equations, which enables the nonlinear behavior of the soil around the long elastic pile to be modeled using a simple expression of pile-head stiffness method. The calculated results were validated with the measured full-scale dynamic field tests data conducted in Auckland residual clay. An idealized soil profile and soil stiffness under small strain (i.e. shear modulus, G _s and shear wave velocity, V _s of the soil) determined from in situ testing was used to model the single pile tests results. The predictions of these extended equations are also confirmed by using the three-dimensional finite-element OpenSeesPL (Lu et al. in OpenSeesPL 3D lateral pile-ground interaction: user manual, University of California, San Diego, 2010). A soil stiffness reduction factor, G _s /G _s,max of 0.36 was introduced to the proposed method and model. It was found to give a reasonable prediction for a single pile subjected to dynamic lateral loading. The reduction in soil stiffness found from the experiment arises from the cumulative effects of pile–soil separation as well as a change in the soil properties subjected to cyclic load. In summary, if the proposed method and model are accurately verified and properly used, then they are capable of producing realistic predictions. Both models provide good modelling tools to replicate the full-scale dynamic test results.     

A statistical approach to evaluate debris avalanche activity in central Virginia

On August 19–20, 1969, the heavy rainfall associated with hurricane Camille triggered numerous debris avalanches in the Blue Ridge Province of central Virginia. Most slope movements occurred in Nelson County in an area that is predominantly underlain by Precambrian granites, gneisses, and schists. This study was undertaken to determine which geotechnical properties of soil and rock were important in promoting debris avalanche activity in central Virginia.

Twenty-one first-order drainage basins in Nelson County were randomly selected and classified as unstable based on their values of horizontal curvature and average gradient as measured on topographic maps. Slope orientation, total soil thickness, and soil horizon thicknesses were measured in the field. Soils from the study basins were tested for geotechnical properties including natural water content, grain-size distribution, Atterberg limits,in situ dry density, and shear strength. These geomorphic and geotechnical properties were subsequently analyzed to ascertain what significant differences existed at the 99% confidence level between three failure classes of unstable basins. Where rock outcrops were present, information regarding discontinuity type, orientation, spacing, continuity, roughness, waviness, aperture, and water quantity was obtained. Values of hand sample hardness were also procured. The role of these bedrock characteristics in determining unstable basin failure class was statistically analyzed at the 95% confidence level.

In general, the results indicate that basins classified as geomorphically unstable are particularly susceptible to debris avalanche activity if they contain coarse-grained soils with low values of plasticity index and moisture content. Geotechnical properties are also found to be significantly different when analyzed with respect to the underlying bedrock unit, which helps explain why basins underlain by certain bedrock units failed more often than basins underlain by other bedrock units. Differences in topography, due to the nature of the underlying bedrock unit, also explain the frequency of debris avalanche occurrences in a given bedrock unit. Characteristics of bedrock discontinuities do not appear to have influenced drainage basin failure.     

Tectono-sedimentary processes along an active marine/lacustrine half-graben margin: Alkyonides Gulf, E. Gulf of Corinth, Greece

ABSTRACT The Alkyonides half‐graben is separated from the Gerania Range to the south by active faults whose offshore traces are mapped in detail. The East Alkyonides and Psatha Faults have well‐defined, Holocene‐active tip zones and cannot be extrapolated from the onshore Skinos Fault into a single continuous surface trace. During the late Quaternary, catchments draining the step‐faulted range front have supplied sediment to alluvial fans along a subsiding marine ramp margin in the hangingwall of the Skinos Fault, to shelf ledge fans on the uplifting footwall to the East Alkyonides Fault and to the Alepochori submarine fan in the hangingwall of the latter. During late Pleistocene lowstand times (c. 70–12 ka), sediment was deposited in Lake Corinth as fan deltas on the subsiding Skinos shelf ramp which acted as a sediment trap for the adjacent 360 m deep submarine basin plain. At the same time, the uplifting eastern shelf ledge was exposed, eroded and bypassed in favour of deposition on the Alepochori submarine fan. During Holocene times, the Skinos bajada was first the site of stability and soil formation, and then of substantial deposition before modern marine erosion cut a prominent cliffline. The uplifting eastern shelf ledge has developed substantial Holocene fan lobe depositional sequences as sediment‐laden underflows have traversed it via outlet channels. We estimate mean Holocene displacement rates towards the tip of the Psatha Fault in the range 0.7–0.8 mm year^?1. Raised Holocene coastal notches indicate that this may be further partitioned into about 0.2 mm year^?1 of footwall uplift and hence 0.5–0.6 mm year^?1 of hangingwall subsidence. Holocene displacement rates towards the tip of the active East Alkyonides Fault are in the range 0.2–0.3 mm year^?1. Any uplift of the West Alkyonides Fault footwall is not keeping pace with subsidence of the Skinos Fault hangingwall, as revealed by lowstand shelf fan deltas which show internal clinoforms indicative of aggradational deposition in response to relative base‐level rise due to active hangingwall subsidence along the Skinos Fault. Total subsidence here during the last 58 kyr lowstand interval of Lake Corinth was some 20 m, indicating a reduced net displacement rate compared to estimates of late Holocene (< 2000 bp ) activity from onshore palaeoseismology. This discrepancy may be due to the competition between uplift on the West Alkyonides Fault and subsidence on the onshore Skinos Fault, or may reflect unsteady rates of Skinos Fault displacement over tens of thousands of years.