The problem of inherited Ar* in dating impact glass by the Ar/Ar method: Evidence from the Tswaing impact crater (South Africa)

The Tswaing meteorite impact crater is a 1.13 km diameter structure located in the 2.05 Ga Nebo granite of the Bushveld Complex. The impact age had previously been determined by fission track dating to 220 ± 104 ka. ⁴⁰Ar/³⁹Ar step-heating and total fusion experiments performed on single- and multi-grain impact glass aliquots gave apparent ages ranging from 1.0 ± 0.3 Ma to 204 ± 6 Ma. These “ages” indicate that the radiogenic Ar derived from the target rocks has not been completely degassed as a result of the impact process, despite fusion of the target material. Results of step-heating experiments imply that the trapped within the glass is located in two distinct reservoirs thought to be the glass matrix and fluid/vapor inclusions (or un-melted residual clasts). Calculations assuming an age of 0.2 ± 0.1 Ma for Tswaing (fission track data) reveal that the amount of inherited ⁴⁰Ar*() relative to the pre-impact concentration varies from 0.015% to 4.15%. The spread defined by likely reflects the various quench rates experienced by the glass, most certainly due to the pre-impact position of the sample relative to the center of the crater. We compare the influence of on the apparent ⁴⁰Ar/³⁹Ar age determination of five impact structures. Our calculations show that the main characteristic controlling the age offset (for a given proportion of ) is the age difference between the impact and the target rocks (i.e., the ⁴⁰Ar* concentration in the target rock). The buffer effect for a given crater structure can be predicted knowing the age of the basement and having a rough estimation of the age of the crater structure itself. The occurrence of is likely influenced by (1) the degree of polymerization (i.e., silicate structure complexity) of the target rock and presumably related to the diffusivity of Ar in the melt and glass, (2) the Ar partial pressure at the grain boundary, (3) the quantity of energy involved in the impact, and (4) the porosity of the target rocks. For glass that inevitably suffers inherited and/or excess ⁴⁰Ar*, the use of the inverse isochron technique can be appropriate but should be applied with careful statistical treatment.     

Studies of temperature effects of dust storms

We studied the temperature variations of the lower air layer caused by dust content using a dust storm in Dushanbe in November 2007 as an example. Quantitative estimates of air cooling and a decrease in the diurnal temperature difference due to a diminishing horizontal visibility range are given. Observations of air temperature variations due to the dust content of the atmosphere in an arid zone are presented. The critical value of aerosol concentration for toggling between the greenhouse and antigreenhouse effects is determined. The long-term effect of dust aerosol on climate is analyzed.     

A study of volcanogenic exhalation mineralization

This paper considers volcanogenic exhalation mineralization using data from 35 years of observation of fumarole activity during an earlier phase of the posteruptive activity of the Second Cone, which is one of the New Tolbachik volcanoes that were formed during the eruption at the North Vent of the Great Tolbachik Fissure Eruption (Kamchatka, 1975–1976). We describe the main types of mineral associations, identify the key mineral species and the secondary and accessory minerals, as well as the sequence of mineral generation. We provide a summary of minerals and compounds that have been identified in ejecta of fumaroles on the Second Cone.     

Jinshanjiangite and bafertisite from the Gremyakha-Vyrmes Alkaline Complex,Kola Peninsula

Jinshanjiangite (acicular crystals up to 2 mm in length) and bafertisite (lamellar crystals up to 3 × 4 mm in size) have been found in alkali granite pegmatite of the Gremyakha-Vyrmes Complex, Kola Peninsula. Albite, microcline, quartz, arfvedsonite, zircon, and apatite are associated minerals. The dimensions of a monoclinic unit cell of jinshanjiangite and bafertisite are: a = 10.72(2), b=13.80(2), c = 20.94(6) Å, β = 97.0(5)° and a = 10.654(6), b = 13.724(6), c = 10.863(8) Å, β = 94.47(8)°, respectively. The typical compositions (electron microprobe data) of jinshanjiangite and bafertisite are: (Na_0.57Ca_0.44)_Σ1.01(Ba_0.57K_0.44)_Σ1.01 (Fe_3.53Mn_0.30Mg_0.04Zn_0.01)_Σ3.88(Ti_1.97Nb_0.06Zr_0.01)_Σ2.04(Si_3.97Al_0.03O₁₄)O_2.00(OH_2.25F_0.73O_0.02)_Σ3.00 and (Ba_1.98Na_0.04K_0.03)_Σ2.05(Fe_3.43Mn_0.37Mg_0.03)_Σ3.83(Ti_2.02Nb_0.03)_Σ2.05 (Si_3.92Al_0.08O₁₄)(O_1.84OH_0.16)_Σ2.00(OH_2.39F_1.61)_Σ3.00, respectively. The minerals studied are the Fe-richest members of the bafertisite structural family.     

A very large scale GIS-based groundwater flow model for the Nubian sandstone aquifer in Eastern Sahara (Egypt,northern Sudan and eastern Libya)

A three-dimensional GIS-based groundwater flow model for the Nubian Sandstone Aquifer in the eastern Sahara was developed and calibrated under steady-state and transient conditions. The model was used to simulate the response of the aquifer to climatic changes that occurred during the last 25,000 years. The simulation results indicated that the groundwater in this aquifer was formed by infiltration during the wet periods 20,000 and 5,000 years b.p. The recharge of groundwater due to regional groundwater flow from more humid areas in the south was excluded. It also indicates that the Nubian Aquifer System is a fossil aquifer, which had been in an unsteady state condition for the last 3,000 years.

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Resumen Fue desarrollado un modelo de flujo de agua subterránea en tres dimensiones, basado en un SIG, para el Acuífero Arenisca Nubian en el Sahara Oriental, el cual fue calibrado para condiciones de estado estacionario y transitorio. El modelo se usó para simular la respuesta del acuífero a los cambios climáticos que ocurrieron durante los últimos 25000 años. Los resultados de esta simulación indicaron que el agua subterránea en este acuífero, se formó por infiltración, durante los períodos húmedos que hubo hace 20000 y 5000 años, antes del presente. Fue excluida la recarga del acuífero debida a un flujo regional de agua subterránea proveniente de áreas con un clima más húmedo en el sur. El modelo también muestra, que el Sistema Acuífero Nubian es un acuífero fósil, el cual ha permanecido en una condición de estado no estacionario, durante los últimos tres mil años.

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Résumé Pour laquifère gréseux Nubien de Sahara -Est on a mis au points un modèle tridimensionnel, basé sur GIS. Le modèle a été calibré tant pour lécoulement stationnaire que pour lécoulement transitoire. On a simulé après la réponse de laquifère aux changements climatiques des derniers 25000 ans. Les résultats des simulations indiquent que la nappe a été rechargée par des infiltrations pendant une période humide qui sétend 5000 et 20000 ans, dès temps actuel. On na pas pris en compte la recharge de laquifère par la zone plus humide située dans sa partie sud. Le modèle indique aussi que leau de laquifère Nubien est une eau fossile qui a eu un écoulement transitoire pendant les derniers 3000 ans.

     

Steady state hodographs in a baroclinic boundary layer

If the steady-state geostrophic wind vector varies exponentially with height in the planetary boundary layer, calculated hodographs of the 24-hour mean wind resemble the classic Ekman spiral distorted by thermal effects. For such an assumed distribution, Lettau's (1967) conclusion that the effects of thermal influence on the steady-state boundary-layer winds can be linearly superimposed on the effects of internal friction is justified.The minimum value of the cross-isobar angle of the surface wind for a given magnitude of the thermal wind vector occurs when that vector points about 345° to the right of the surface geostrophic wind vector and the maximum value occurs when it points at an azimuth of about 120° relative to the surface geostrophic wind vector. The range of values of the cross-isobar angle is almost directly proportional to the magnitude of the thermal wind vector.Hodographs resulting from the assumed variation of the geostrophic wind have approximately the same shape as 24-hour mean hodographs at two locations over the Great Plains.This work is part of a thesis submitted to the University of Wisconsin in partial fulfillment of the requirements for the Ph.D. Degree, written under the supervision of Professor H. Lettau, Department of Meteorology.     

Age and source material of the Kingash ultramafic-mafic massif,East Sayan

The REE distribution patterns and Nd whole-rock and mineral isotope ratios of the Kingash ultramafic-mafic massif enabled us to propose a multistage history for its evolution at 1410 and 875 Ma. These stages reflect the magmatic evolution of the Siberian paleocontinent margin during the Late Precambrian. The age of metamorphism of the massif during collision and accretion in the Early Paleozoic (∼500 Ma) was obtained based on a Sm-Nd mineral isochron from rheomorphic veined albitite. The Nd and Sr isotopic compositions of rocks from the Kingash massif suggest mantle sources for picritic and basic magmas, which are thought to have originated by mixing of different proportions of depleted (PREMA or DM) and enriched (EM) melts. The initial isotope ratios of the parental melts transformed during interaction with Sr-rich material from the host metasedimentary complexes.     

Relationships between marginal thrusting and movement on major,internal shear zones in the Northern Highland Caledonides,Scotland

The development of the syn-metamorphic Sgurr Beag slide zone, a major ductile shear zone of initially low dip, caused at least 50 km north-western thrust displacement of part of the internal metamorphic complex of the Northern Highland Caledonides of Scotland. Initiation of the zone, and movements upon it, were earlier than formation of the marginal Moine Thrust zone. Movement on the zone followed but overlapped the peak Caledonian metamorphism and the mid to high amphibolite facies mineral assemblages, fabrics and structures produced during the development of the slide zone and those surviving from earlier events, were reworked under greenschist facies conditions during mylonitization associated with initiation of the Moine Thrust zone. Displacements on the slide zone and thrust movements were separated by emplacement of a regional suite of pegmatites and a considerable change of metamorphic grade. Thus, they may not constitute members of a progressive sequence of Caledonian thrusts formed over a short time interval. Rather, preliminary isotopic data may imply an interval of c. 25 Ma between movement on the slide zone and final, ductile translation along the Moine Thrust zone.