Distribution of forms of sulfur in peats from saline environments in the Florida Everglades

Although there is published information on the mechanism of sedimentary pyrite formation resulting from bacterial reduction of sulfate, little is known about the distribution of forms of sulfur, including organic, in peats. In order to increase understanding of the geochemistry of sulfur in coals, we have determined distributions of forms of sulfur in five cores of saline peat and one of brackish peat, all from areas near the Shark River and Whitewater Bay in the coastal swamps of south Florida. All concentrations vary widely with depth. Total sulfur concentrations range up to 6% of dry solids. Minor amounts of sulfur are present as H₂S, S⁰, SO₄²⁻, and acid-soluble sulfide, but the principal forms are usually pyritic and organic. The ratio, organic/pyritic, is highly variable, but at a majority of levels in a profile is considerably greater than unity. It is inferred that topochemical factors are important in determining the distribution of sulfur forms in any element of volume.     

Physical Libration of the Moon: An Extended Problem

Astronomy Reports - The work is devoted to the study of the physical libration of the Moon. Interest in the traditional topic related to the rotation of the Moon is stirred up by the activity of...     

Interaction of the Atmosphere and Lithosphere in the Minute Range of Periods

Doklady Earth Sciences - The interaction between the atmosphere and the lithosphere in the minute range of periods is considered. The technique of assessment of the influence of atmospheric...     

Baroclinic seiches in rotating basins of variable depth in the case of two-layer density stratification

We solve a plane problem of linear baroclinic seiches in closed rotating basins of variable depth with two-layer density stratification. In the long-wave approximation, we get a boundary-value problem for a system of ordinary differential equations and propose a numerical procedure for finding internal seiches. The analytic solutions of the problem are obtained for a basin of constant depth. The numerical analysis of seiches is performed for the distributions of depth corresponding to the zonal and meridional sections of the Black Sea and model basins including the cases of a shelf zone and an underwater ridge. It is shown that the baroclinic seiches become more intense in shallow-water regions and that the intense longshore currents caused by Earth’s rotation are formed in the shelf zones and over the underwater ridges.     

Convection Regime of the Development of an Impulse–Buoyant Transient Jet Submerged in a Homogeneous Fluid

An intergral model of a transient vertical impulse–buoyant jet is suggested. The model contains a universal equation describing the propagation of the upper boundary of the convection front depending on the strength of the point source of buoyancy and momentum. The convective regime of jet propagation is considered, which includes a class of self-similar solutions corresponding to the buoyancy sources, whose strength varies with time following power and exponential laws. The obtained numerical solutions are compared with available experimental data on the profiles of vertical velocity and buoyancy on the jet axis.