Epifanovite,NaCaCu5(PO4)4[AsO2(OH)2] · 7H2O: a New Mineral from the Kester Deposit,Sakha (Yakutia) Republic,Russia

Geology of Ore Deposits - Epifanovite, NaCaCu5(PO4)4[AsO2(OH)2] · 7H2O, a new natural copper, sodium and calcium arsenate–phosphate, has been found in a quartz–phosphate pocket...     

Phosphates of the Chalotskoe Pegmatite Deposit,Transbaikal Region

A number of rare phosphates have been found in specimens from the Chalotskoe pegmatite deposit, Transbaikal region, Russia: väyrynenite, MnBe[PO₄](OH,F); parascholzite, CaZn₂[PO₄]₂ · 2H₂O; messelite, Ca₂(Fe²⁺,Mn)[PO₄]₂ · 2H₂O; eosphorite, MnAl[PO₄](OH)₂ · H₂O; moraesite, Be₂[PO₄](OH)4H₂O; and fluorapatite. Väyrynenite forms pink grains 2–3 mm in size, less frequent prismatic crystals up to 0.8 × 3.0 cm, and spheres up to 3 mm in diameter. Parascholzite occurs as pockets up to 0.6 × 1.0 cm composed from snow-white small grains. Messelite forms pale yellow honeycomb grains and poorly shaped crystals up to 1 mm. Eosphorite has been seen in the Chalotskoe pegmatites before, but it has not been studied in detail. It occurs as red-brown prismatic crystals up to 8 cm in length, occasionally forming openbook- like aggregates and pink to pale pink grains up to 5 mm in size. Moraesite forms snow-white fibrous aggregates up to 5 × 6 mm, together with white spheres and short prismatic crystals of fluorapatite up to 1 mm. Microcline, albite, quartz, muscovite, beryl, schorl, almandine-spessartine, columbite-(Fe), and bertrandite are associated minerals. Väyrynenite and parascholzite are found for the first time in Russia.

     

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.     

Neotectonics of the Kharaulakh sector of the Laptev Shelf

Seismotectonic deformation and crustal stress pattern have been studied comprehensively in major seismogenic structures of the Kharaulakh sector of the Verkhoyansk fold system and adjacent parts of the Chersky seismotectonic zone. The study focuses on neotectonic structures, deep structure, and systems of active faults, as well as tectonic stress fields inferred by tectonophysical analysis of Late Cenozoic faults and folds. The results, along with geological and geophysical data, reveal main strain directions and structural patterns of crustal stress and strain in the Arctic segment of the Eurasia-North America plate boundary. The area is a junction of mid-ocean and continental structures evolving in a mixed setting of extension, compression, and their various combinations. The rotation pole of the two plates is presumably located near Buor-Khaya Bay. In this case, extension is expected to act currently upon the neotectonic structures north of the bay and compression to control those in the south and southeast. This inference is consistent with the identified zoning of stress and strain in the Kharaulakh sector.     

Development of medium-term prediction methods: A case study of the August 14, 2016 Onor (Mw = 5.8) earthquake on Sakhalin

The potential of the load-unload response ratio (LURR) method for medium-term earthquake prediction is studied for Sakhalin Island as an example. An approach to the generation of predicted conditions and assessment of their implementation in real time is considered. The results of a retrospective analysis of other large Sakhalin earthquakes are used for generalization. It is shown that deviations of prediction parameters from specified values are satisfactory for this method. It is recommended that this method be used to compile summaries of medium-term predictions for Sakhalin provided that catalogs are filled as soon as possible.     

Nodular monazite from placers in the Kular Ridge (Arctic Siberia,Russia): Composition and age

Nodular monazite occurs in metamorphic rocks worldwide and has zonal REE patterns. This paper focuses on the composition of nodular monazite hosted by Permian black shales of the Kular Ridge in the Kular-Nera terrane. This monazite variety (called kularite in the Russian literature) reaches commercial amounts in placers of the area. The contents of Ce, Nd, and La in the analyzed monazite nodules show correlations at Ce/Nd = 14.39La + 0.0919 (in apfu) and Ce/Nd = 0.2318La + 0.1135 (in wt.%) and vary regularly from core to rim. All monazite compositions fall on this trend, but specific grains may plot in its different parts. Thermodynamic calculations indicate that monazite forms via an intermediate precursor (LnPO₄·2H₂O). The Ce:La:Nd changes in different grains record Eh-pH variations during nucleation and a gradual temperature increase during subsequent growth. The Ce:La:Nd ratio changes partly in grain rims as a result of oxidative dissolution. Judging by the tectonic setting, REE came to the Kular-Nera rocks from the weathered Tomtor Nb-REE deposit, being transported by the Paleo-Khatanga River with monazite nanoparticles bound to the surface of clay minerals.     

Isotope stratigraphy and U-Pb dating of detrital zircons from the Vendian-Cambrian deposits of the North Muya block

U-Pb dating of detrital zircons from the sandstones of the Mamakan Formation has been made. Geochemical and isotope parameters of the carbonate deposits of the Yanguda Formation in the Vendian-Cambrian cover of the North Muya continental block have been estimated. It has been established that only the Neoproterozoic (630-915 Ma) rocks of the North Muya block were the provenances of terrigenous material. In the least altered carbonate rocks of the Yanguda Formation, the ⁸⁷Sr/⁸⁶Sr ratio is within 0.70814-0.70879 and δ¹³C varies from -0.4 to + 1.9‰. Comparison of the evaluated isotope parameters with those of carbonate rocks of typical Vendian-Cambrian sections shows that the carbonate deposits of the Yanguda Formation accumulated in the Early Cambrian, about 520 Ma. Sedimentation of the Mamakan and Yanguda Formations took place in the local sedimentary basin in the Vendian-Early Cambrian, in the absence of tectonic activity within the North Muya block. Detrital material that formed during the destruction of the rocks of the Siberian Platform basement and cover was not supplied into the basin.     

Phenanthrene biomarkers in the organic matter of Precambrian and Phanerozoic deposits and in the oils of the Siberian Platform

The composition and distribution of phenanthrenes (polyaromatic compounds) have been studied in chloroform extracts from dispersed organic matter (OM) of clayey, siliceous, carbonate, and terrigenous rocks of different ages and facies and from some oils of the Siberian Platform. Phenanthrenes have been analyzed by gas chromatography-mass spectrometry. High contents of 1,7,8-trimethylphenanthrene and 1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene are present in the OM of Vendian and Cambrian carbonate-shale deposits and in ancient oils of the Nepa-Botuobiya and Anabar anteclises. The OM of Permian continental deposits and oils of the Vilyui syneclise is dominated by 1-methyl-7-isopropylphenanthrene (retene). A triangular diagram for identification of the types of original OM of rocks and classification of genetically related oils has been constructed based on the assessment of phenanthrene biomarker distribution. Putative pathways of the formation of phenanthrene biomarkers are discussed.     

Geologic structure and correlation of the Berriasian-Lower Aptian productive beds of the Gydan Peninsula (Russian Arctic)

We discuss the geologic structure of the Berriasian-Lower Aptian deposits of the Gydan Peninsula. Eight seismic sequences have been distinguished; most of them are associated with Lower Cretaceous regional clinoforms of West Siberia, their characteristics are given. A correlation of productive beds was based on the stratotype sections of the Yamal and Gydan Peninsulas as well as seismic and well data. A sequence stratigraphic model of the Berriasian-Lower Aptian complex is proposed.     

A distributed parallel multiple-relaxation-time lattice Boltzmann method on general-purpose graphics processing units for the rapid and scalable computation of absolute permeability from high-resolution 3D micro-CT images

Digital rock physics (DRP) is a rapidly evolving technology targeting fast turnaround times for repeatable core analysis and multi-physics simulation of rock properties. We develop and validate a rapid and scalable distributed-parallel single-phase pore-scale flow simulator for permeability estimation on real 3D pore-scale micro-CT images using a novel variant of the lattice Boltzmann method (LBM). The LBM code implementation is designed to take maximum advantage of distributed computing on multiple general-purpose graphics processing units (GPGPUs). We describe and extensively test the distributed parallel implementation of an innovative LBM algorithm for simulating flow in pore-scale media based on the multiple-relaxation-time (MRT) model that utilizes a precise treatment of body force. While the individual components of the resulting simulator can be separately found in various references, our novel contributions are (1) the integration of all of the mathematical and high-performance computing components together with a highly optimized code implementation and (2) the delivery of quantitative results with the simulator in terms of robustness, accuracy, and computational efficiency for a variety of flow geometries including various types of real rock images. We report on extensive validations of the simulator in terms of accuracy and provide near-ideal distributed parallel scalability results on large pore-scale image volumes that were largely computationally inaccessible prior to our implementation. We validate the accuracy of the MRT-LBM simulator on model geometries with analytical solutions. Permeability estimation results are then provided on large 3D binary microstructures including a sphere pack and rocks from various sandstone and carbonate formations. We quantify the scalability behavior of the distributed parallel implementation of MRT-LBM as a function of model type/size and the number of utilized GPGPUs for a panoply of permeability estimation problems.