Lateral and consolidation behaviors of seabed-type breakwater for very soft ground

A seabed-type of breakwater applicable to very soft ground without the need for soil improvement is newly developed. This type of soft-ground breakwater is expected to ensure sufficient lateral resistance and prevent excessive consolidation settlement due to self-weight of the breakwater. In this paper, lateral and consolidation behaviors of soft-ground breakwater were investigated by performing model tests and finite element simulations. The results revealed that the bottom wall and buoyant box, which are the main features of soft-ground breakwater, contribute to the increase in lateral resistance and to the control of the consolidation settlements, respectively, and that Terzaghi's consolidation theory could be conservatively adopted in deriving the consolidation settlements of soft-ground breakwater proposed herein.     

Interannual SST variability in the Japan/East Sea and relationship with environmental variables

Interannual variability of the Japan/East Sea (JES) sea surface temperature (SST) is investigated from the reconstructed NOAA/AVHRR Oceans Pathfinder best SST data (1985–2002) using the complex empirical function (CEOF) analysis. The iterative empirical function analysis is used for the SST data reconstruction. The first two leading CEOFs account for 86.0% of total variance with 66.4% for the first mode and 19.6% for the second mode. The first CEOF mode represents a standing oscillation and a maximum belt in the central JES. There are two near-7-year events and one 2–3-year event during the period of 1985–2002. The first mode oscillates by adjacent atmospheric systems such as the Aleutian Low, the North Pacific High, the Siberian High, and the East Asian jet stream. Positive correlation in a zonal belt between the first mode JES SST anomaly and the background surface air temperature/SST anomaly reveals intensive ocean-atmosphere interaction near the Polar Front in the North Pacific. The second CEOF mode represents two features: standing oscillation and propagating signal. The standing oscillation occurs in the northern (north of 44°N) and southern (south of 39°N and west of 136°E) JES with around 180° phase difference. A weak southwestward propagating signal is detected between the two regions. The eastward propagating signal is detected from the East Korean Bay to near 135°E. The second mode contains 4–5-year periodicity before 1998 and 2–3-year periodicity thereafter. It is associated with the Arctic Oscillation, which leads it by 1–5-year. Furthermore, a strong correlation with the background surface air temperature/SST anomaly is detected in the tropical to subtropical western Pacific.     

Effects of climate change on the phenology of <Emphasis Type="Italic">Osmia cornifrons</Emphasis>: implications for population management

The phenology of many ecological processes including pollination service is modulated by surface air temperature, making them potentially sensitive to climatic change. The Japanese hornfaced bee, Osmia cornifrons (Hymenoptera: Megachilidae), was introduced into the USA in the 1970s and has been used as a key pollinator of spring blooming fruit crops such as apple and blueberry. This study examined the effects of future climate change on three key phenological events of O. cornifrons: date for adult emergence (female and male) in spring, date for completion of egg and larval development, and duration for the development in the Eastern USA. We used daily temperature data obtained from 21 models in Coupled Model Intercomparison Project Phase 5 for 2006–2100 under the two future climate scenarios of Representative Concentration Pathways (RCPs 4.5 and 8.5). We estimated the Julian dates (JDs) of spring emergence and development of O. cornifrons using the phenological parameters derived from temperature-dependent biophysical models. The JDs for the bee emergence and development are projected to be significantly advanced in the Eastern USA under the RCP 4.5 and 8.5 scenarios. The number of days for bee development is projected to be longer in the southern region (+?0.57 days/decade) and shorter in the central (??0.27 days/decade) and northern (??0.65 days/decade) regions of the Eastern USA (all the p values <?0.01). The significantly longer duration of bee development under future climate change could pose a risk to the bee due to the longer period of being exposed to its pests. Implications for management of O. cornifrons population were discussed in this article.     

Practical determination of mechanical design parameters of intact rock considering scale effect

As a rule, the change in mechanical properties of rock by specimen size is regarded as scale effect. A rock mass basically consists of two components: intact rock and discontinuities, each of which has different scale effects. In order to numerically analyze the behavior of discontinuous rock masses, sufficient mechanical properties must be determined not only for discontinuities but also for intact rock taking into consideration the different scale effects. This paper reviews the scale effect on strength and deformation characteristics of intact rock, and also discusses the possibility of using standard specimens to estimate strength and deformation characteristics of actual-scale rock. Finally, we propose an adequate method for the practical determination of mechanical design parameters based on the above discussions.     

Simultaneous inner- and outer-sphere arsenate adsorption on corundum and hematite

The ability to predict the fate and transport of arsenic in aquatic environments, its impact on water quality and human health, and the performance and cost-effectiveness of water treatment systems relies on understanding how it interacts with solid surfaces. In situ resonant surface X-ray scattering measurements of arsenate adsorption at pH 5 in 0.01 M NaCl on corundum and hematite (012) surfaces demonstrate that arsenate surface complexation is unexpectedly bimodal, adsorbing simultaneously as inner- and outer-sphere species. In addition, this bimodal behavior is found to be independent of the total arsenate solution concentration, and thus surface coverage, over the range of 10⁻⁶ to 10⁻³ M. Alternative mechanisms to produce the observed As distributions, such as arsenate dimerization or surface precipitation of an aluminum or ferric arsenate, are inconsistent with the experimentally-determined total and As-specific density profiles. Based on the location of the outer-sphere arsenate in relation to the surfaces studied, possible binding mechanisms include electrostatic attraction, hydrogen bonding to surface oxygen functional group, and configurational stabilization by interfacial water. Although the observation of outer-sphere arsenate surface complexes on a metal oxide surface is unprecedented, it is unclear if such species were absent in previous molecular-scale studies, as it is difficult for methods commonly used to investigate the mechanisms of arsenate adsorption to conclusively identify or rule out the presence of outer-sphere species when inner-sphere species are also present.     

Evaluation of the processes affecting vertical water chemistry in an alluvial aquifer of Mankyeong Watershed, Korea, using multivariate statistical analyses

Vertical variations of redox chemistry and groundwater quality were investigated in an alluvial aquifer beneath an agricultural area, in which deep groundwaters are free of NO₃, Fe, and Mn problems that are frequently encountered during the development of alluvial groundwaters. This study was performed to identify and evaluate vertical chemical processes attenuating these chemical species in the study area. For this study, the processes affecting groundwater chemistry were identified by factor analysis (FA) and the groundwater samples collected from six multilevel samplers were hierarchically classified into three different redox zones by cluster analysis (CA) based on the similarity of geochemical features. FA results indicated three major factors affecting the overall water chemistry: agricultural activities (factor 1), redox reactions (factor 2), and remnant seawater (factor 3). The groundwater quality in the study area was revealed to be controlled by a series of different redox reactions, resulting in different redox zones as a function of depth. It was also revealed that the low Fe and Mn levels in the groundwater of the deeper part are associated with sulfate reduction, which led to precipitation of Fe as iron sulfide and adsorption of Mn on it.