Interfacial water structure on the (0 1 2) surface of hematite: Ordering and reactivity in comparison with corundum

Many geochemical reactions that control the composition of natural waters, contaminant fate and transport, and biogeochemical element cycling take place at the interface between minerals and aqueous solutions. A fundamental understanding of these important processes requires knowledge of the structure of mineral-water interfaces. High-resolution specular X-ray reflectivity was used to determine the structure of the hematite (0 1 2)-water interface. Relaxation of the surface was observed to be minor, and water was found to order near the hematite surface. Two sites of adsorbed water are inferred to be ordered laterally, one bridging between triply coordinated functional groups and the other bridging between the singly coordinated functional groups on the surface, as steric constraints limit the possible arrangements of water molecules occurring at the observed heights above the hematite surface. Relaxations of the hematite and corundum (0 1 2) surfaces, which are isostructural, are similar and limited primarily to the top most layer of the structures. No significant changes to the interfacial stoichiometry (i.e., partial occupancy of surface species) are observed in either case. The structure of interfacial water is similar on the hematite and corundum (0 1 2) surfaces as well, although water appeared to be less well ordered on the hematite surface. This may be due to expected differences in the oxygen exchange rates from surface functional groups or the apparent better matching of the corundum oxygen lattice to the natural structural ordering in water, and suggests that the dielectric constant gradients of interfacial water may differ on the two surfaces. Similar charging behavior is expected for these surfaces as similar types of surface functional groups are exposed. Although generally similar, subtle differences in the reactivity of hematite and corundum (0 1 2) surfaces to arsenate adsorption, and possibly the adsorption of other species, may be related to the difference in ordering of interfacial water observed in this study.     

Effects of land use on the spatial distribution of trace metals and volatile organic compounds in urban groundwater, Seoul, Korea

To investigate the urban groundwater contamination by eight trace metals and 69 volatile organic compounds (VOCs) in relation to land use in Seoul, a total of 57 groundwater samples collected from wells were examined using a non-parametric statistical analysis. Land use was classified into five categories: less-developed, residential, agricultural, traffic, and industrial. A comparison of analyzed data with US EPA and Korean standards for drinking water showed that some metals and VOCs exceeded the standards in a few localities, such as Fe (N=5), Mn (N=6), Cu (N=1), TCE (N=6), PCE (N=8), 1,2-DCA (N=1), and 1,2-dichloropropane (N=1). Among the 69 investigated VOCs, 19 compounds such as some gasoline-related compounds (e.g., toluene) and chlorinated compounds (e.g., chloroform, PCE, TCE) were detected in groundwater. Non-parametric statistical analysis showed that the concentrations of most trace metals (Fe, Mn, As, Cr, Pb, Cd) and some VOCs (especially, TCE, PCE, chloroform; toluene, carbon tetrachloride, bromodichloromethane, CFC113) are significantly higher in the industrial, residential, and traffic areas (P<0.05), indicating that anthropogenic contamination of urban groundwater by those chemicals is growing. Those chemicals can be used as effective indicators of anthropogenic contamination of groundwater in urban areas and therefore a special attention is warranted for a safe water supply in those areas. The results of this study suggest that urban groundwater quality in urban areas is closely related with land use.     

Deformation history inferred from magnetic fabric in the southwestern Okcheon metamorphic belt, Korea

Magnetic fabric and rock-magnetic studies have been carried out for the non-fossiliferous, low- to medium-grade metasedimentary rocks in the southwestern part of the Okcheon metamorphic belt (OMB). Two major metamorphic events in the study area were previously recognized: regional metamorphism (M₁) in the late Carboniferous to early Permian and contact metamorphism (M₂) due to the intrusion of granite in the middle Jurassic. The metamorphic grade of the study area increases from the biotite zone in southeast through the garnet zone to the staurolite zone towards the northwest. Magnetic fabrics of the study area are generally well defined and can be characterized according to the metamorphic zones. Magnetic foliation is the dominant magnetic fabric in the biotite zone, while magnetic lineation prevails in both garnet and staurolite zones. We interpret the metamorphism-related deformation history of the study area based on magnetic fabrics, magnetic mineralogy and previously reported metamorphic evolution as follows. Penetrative NW-dipping cleavage, represented by magnetic foliation, was formed in the study area by prevailing NW–SE shortening event during the M₁ regional metamorphism in the late Carboniferous–early Permian. This shortening event is interpreted to be associated with the collisional event between the North and South China blocks. Cleavages dipping steeply to the southeast in the staurolite zone are attributed to the pressure exerted from the intrusion of Jurassic granite in the northwestern area.     

Application of APG and Calfax 16L-35 on surfactant-enhanced electrokinetic removal of phenanthrene from kaolinite

Removal characteristics of polycyclic aromatic hydrocarbons (PAHs) from low-permeable soil using a surfactant-enhanced electrokinetic (EK) process were investigated. Phenanthrene and kaolinite were selected as a representative PAH and a model soil. A nonionic surfactant, alkyl polyglucosides (APG), and an anionic surfactant, Calfax 16L-35, were used to enhance the solubility of phenanthrene. The two surfactants showed similar solubilization capacities for phenanthrene, while only APG was affected by sorption. When surfactants were applied to EK process, the electrical potential gradient was lower than that of water. The electroosmotic flow (EOF) decreased as the concentration of surfactant increased. In the case of APG, the removal efficiency of phenanthrene increased with the surfactant concentration. The APG micelles containing phenanthrene easily migrated to the cathode reservoir by EOF. On the other hand, Calfax 16L-35 did not enhance the removal efficiency even at the highest concentration, because most of Calfax 16L-35 remained in soil, and only small amount existed in effluent. It was thought that, during electrokinetic process, Calfax 16L-35 was adsorbed onto soil and the migration of the surfactant from cathode to anode was superior to EOF due to anionic charges of Calfax 16L-35. A nonionic surfactant, APG, seems to be suitable for surfactant-enhanced electrokinetic remediation.     

Evaluation of an upscaled model for DNAPL dissolution kinetics in heterogeneous aquifers

Estimates of contaminant fluxes from DNAPL sources as a function of time and DNAPL mass reduction are important to assess the long-term sustainability and costs of monitored natural attenuation and to determine the benefits of partial source removal. We investigate the accuracy of the upscaled mass transfer function (MTF) proposed by Parker and Park [Parker JC, Park E. Modeling field-scale dense nonaqueous phase liquid dissolution kinetics in heterogeneous aquifers. WRR 2004;40:W05109] to describe field-scale dissolved phase fluxes from DNAPL sources for a range of scenarios generated using high-resolution 3-D numerical simulations of DNAPL infiltration and long-term dissolved phase transport. The results indicate the upscaled MTF is capable of accurately describing field-scale DNAPL dissolution rates as a function of time. For finger-dominated source regions, an empirical mass depletion exponent in the MTF takes on values greater than one which results in predicted mass flux rates that decrease continuously with diminishing DNAPL mass over time. Lens-dominated regions exhibit depletion exponents less than one, which results in more step-function like mass flux versus time behavior. Mass fluxes from DNAPL sources exhibiting both lens- and finger-dominated subregions were less accurately described by the simple MTF, but were well described by a dual-continuum model of the same form for each subregion. The practicality of calibrating a dual-continuum model will likely depend on the feasibility of obtaining spatially resolved field measurements of contaminant fluxes or concentrations associated with the subregions using multilevel sampling or some other means.     

Regional innovation strategies in the knowledge-based economy

This paper aims to examine major regional innovation strategies for regional development in the knowledge-based economy in Korea. Innovation policy and Regional Innovation Systems (RIS) are becoming important issues in Korea in both national and regional perspectives. These issues have been evolving since the mid 1990s, especially since the financial crisis of 1997 in Korea. Five major policy issues for promoting innovation and regional competitiveness are examined in this paper. The major policy issues are: promoting region-specific clustering; building habitats for innovation and entrepreneurship; collective learning processes and innovation networks; building a stock of social capital; and promoting local and global networks. Several strategies are suggested for each of these policy issues. These major policy issues and related strategies for regional innovation and competitiveness can be regarded as common issues required for the successful development of RIS. Taking these basic policy issues into account, each region can develop their own region-specific RIS, with appropriate consideration of distinctive regional characteristics such as the level of development, industrial specialization, local labor market, local business climate, local financial system, etc.     

AGCM simulations of intraseasonal variability associated with the Asian summer monsoon

The intraseasonal variability associated with the Asian summer monsoon as simulated by a number of atmospheric general circulation models (AGCMs) are analyzed and assessed against observations. The model data comes from the Monsoon GCM Intercomparison project initiated by the CLIVAR/Asian–Australian Monsoon Panel. Ten GCM groups, i.e., the Center for Ocean–Land–Atmosphere Studies (COLA), Institute of Numerical Mathematics (DNM), Goddard Space Flight Center (GSFC), Geophysical Fluid Dynamics Laboratory (GFDL), Institute of Atmospheric Physics (IAP), Indian Institute of Tropical Meteorology (IITM), Meteorological Research Institute (MRI), National Center for Atmospheric Research (NCAR), Seoul National University (SNU), and the State University of New York (SUNY), participated in the intraseasonal component of the project. Each performed a set of 10 ensemble simulations for 1 September 1996–31 August 1998 using the same observed weekly SST values but with different initial conditions. The focus is on the spatial and seasonal variations associated with intraseasonal variability (ISV) of rainfall, the structure of each model's principal mode of spatial-temporal variation of rainfall [i.e. their depiction of the Intraseasonal Oscillation (ISO)], the teleconnection patterns associated with each model's ISO, and the implications of the models' ISV on seasonal monsoon predictability. The results show that several of the models exhibit ISV levels at or above that found in observations with spatial patterns of ISV that resemble the observed pattern. This includes a number of rather detailed features, including the relative distribution of variability between ocean and land regions. In terms of the area-averaged variance, it is found that the fidelity of a model to represent NH summer versus winter ISV appears to be strongly linked. In addition, most models' ISO patterns do exhibit some form of northeastward propagation. However, the model ISO patterns are typically less coherent, lack sufficient eastward propagation, and have smaller zonal and meridional spatial scales than the observed patterns, and are often limited to one side or the other of the maritime continent. The most pervasive and problematic feature of the models' depiction of ISV and/or their ISO patterns is the overall lack of variability in the equatorial Indian Ocean. In some cases, this characteristic appears to result from some models forming double convergence zones about the equator rather than one region of strong convergence on the equator. This shortcoming results in a poor representation of the local rainfall pattern and also significantly influences the models' representations of the global-scale teleconnection patterns associated with the ISO. Finally, analysis of the model ensemble shows a positive relationship between the strength of a model's ISV of rainfall and its intra-ensemble variability of seasonal monsoon rainfall. The implications of this latter relation are discussed in the context of seasonal monsoon predictability.     

Quaternary reactivation of Tertiary faults in the southeastern Korean Peninsula: Age constraint by optically stimulated luminescence dating

Abstract   Two groups of Quaternary faults occur in the southeastern Korean Peninsula. The first group is north-northeast-striking, high-angle dextral strike–slip faults. The second group is north-northeast-striking, low-angle reverse faults that represent the reactivation of the pre-existing normal faults. Optically stimulated luminescence dating of Quaternary sediments cut by one of the reverse faults constrains the faulting age to post-32 Ka. These faults seem to be capable of further slip under the current tectonic stress regime, as determined by recent earthquake events in northeast Asia. Therefore, the traditional concept that the southeastern Korean Peninsula is seismically stable should be reappraised.