Impact of rock-water interactions and recharge on water resources quality of the Agadir-Essaouira basin,southwestern Morocco

The Agadir-Essaouira area in the occidental High Atlas Mountains of Morocco is characterized by a semi-arid climate. The scarcity and quality of water resources, exacerbated by long drought periods, constitute a major problem for a sustainable development of this region. Groundwater resources of carbonate units within Jurassic and Cretaceous aquifers are requested for drinking and irrigation purposes. In this study, we collected 84 samples from wells, boreholes, springs, and rivers. Hydrochemical and isotopic data were used to examine the mineralization and origin of water, which control groundwater quality. The chemical composition of water seems to be controlled by water-rock interactions, such as dissolution of carbonates (calcite and dolomite), weathering of gypsum, as well as ion exchange processes, which explain the observed variability. Stable isotopes results show that groundwater from the mainly marly Cretaceous aquifer are submitted to an evaporation effect, while samples from the chiefly calcareous Jurassic aquifer indicate a meteoric origin, due to a rapid infiltration of recharge runoff through the karstic outcrops. The low values of δ¹⁸O and δ²H suggest a local recharge from areas with elevations ranging from 400 to 1200 m for the Cretaceous aquifer and from 800 to 1500 m for the Jurassic units.     

Nature of serpentinization and carbonation of ophiolitic peridotites (Eastern Desert,Egypt): constrains from stable isotopes and whole-rock geochemistry

Serpentinites are widespread in the Arabian-Nubian Shield (ANS) of the Eastern Desert of Egypt and usually enclose a tremendous carbonate alteration. Combined investigation of the stable isotope compositions of both O-H in serpentines and O-C in the whole-rock and the chemistry of the fluid-mobile elements (FMEs) in whole-rock serpentinites from Wadi (W.) Alam, Gabal (G.) El-Maiyit, and W. Atalla (Eastern Desert of Egypt) allowed to better understand the subsequent fluid sources of serpentinization and carbonation, as well as impact of these processes on the geochemistry of protolith ultramafic rocks. δ ¹⁸O values of W. Alam and W. Atalla serpentine minerals are close to the unaltered mantle and propose a lower temperature serpentinization if compared with those of G. El-Maiyit rocks. Moreover, δD values of W. Alam and W. Atalla serpentines (? 94 to ? 65‰) correspond to an igneous source that might be hydrothermal solutions mixed with the seawater in the mid-ocean ridge-arc transition setting. On the other hand, G. El-Maiyit serpentine is more depleted in ¹⁸O (with lower δ ¹⁸O values = 4.08–4.85‰), and its δD values (? 73 to 56 ‰) are most probably caused by an interaction with metamorphic fluids, acquired during on-land emplacement of oceanic peridotites or during burial in fore-arc setting. In addition, the oceanic oxygen isotope composition of most studied ophiolitic serpentinites points to the preservation of the pre-obduction δ ¹⁸O signatures and thus local-scale fluid flow at low water/rock ratios. Serpentinization fluids were CO₂-poor and the carbonation of the serpentinites resulted from infiltration of externally derived fluids. δ ¹⁸O_VSMOW values of carbonates in the studied serpentinites vary between heavier oxygen isotope composition in G. El-Maiyit samples (av. = 25.32‰) to lighter composition in W. Alam samples (av. = 19.43‰). However, δ ¹³C values of all serpentinites point mantle source of carbon. This source might have been evolved in mid-ocean ridge (W. Atalla) and subduction zone (W. Alam and G. El-Maiyit) settings. The studied serpentinites are usually enriched in FMEs, particularly Pb, Sr, Cs, and U. These enrichments were most probably the result of serpentinization and/or carbonation.     

Groundwater Recharge Rate and Zone Structure Estimation Using PSOLVER Algorithm

The quantification of groundwater recharge is an important but challenging task in groundwater flow modeling because recharge varies spatially and temporally. The goal of this study is to present an innovative methodology to estimate groundwater recharge rates and zone structures for regional groundwater flow models. Here, the unknown recharge field is partitioned into a number of zones using Voronoi Tessellation (VT). The identified zone structure with the recharge rates is associated through a simulation‐optimization model that couples MODFLOW‐2000 and the hybrid PSOLVER optimization algorithm. Applicability of this procedure is tested on a previously developed groundwater flow model of the Tahtal? Watershed. Successive zone structure solutions are obtained in an additive manner and penalty functions are used in the procedure to obtain realistic and plausible solutions. One of these functions constrains the optimization by forcing the sum of recharge rates for the grid cells that coincide with the Tahtal? Watershed area to be equal to the areal recharge rate determined in the previous modeling by a separate precipitation‐runoff model. As a result, a six‐zone structure is selected as the best zone structure that represents the areal recharge distribution. Comparison to results of a previous model for the same study area reveals that the proposed procedure significantly improves model performance with respect to calibration statistics. The proposed identification procedure can be thought of as an effective way to determine the recharge zone structure for groundwater flow models, in particular for situations where tangible information about groundwater recharge distribution does not exist.     

Main features of the deep structure by local earthquake tomography and active tectonics: case of Rif Mountain (morocco) and Betic Cordillera (Spain)

Within the Spain and Moroccan networks, a large volume of seismic data has been collected and used for investigating the lithosphere in the Betic–Rif Cordillera. The present study has two main goals: (1) Use the most actual seismological data from recent earthquakes in the Betic–Rif arc for investigating the lithosphere through the application of seismic local tomography techniques. (2) Define the possible structural blocks and explain the GPS velocities perturbation in this region. The resolution tests results indicate that the calculated images gave a close true structure for the studied regions from 5- to 60-km depth. The resulting tomographic image shows that the presence of two upper crust body (velocity 6.5 km/s) at 3- to 13-km depth between Iberian Betic and Moroccan Rif in the western and in the middle of Alboran Sea also shows the low velocity favoring the presence of melt in the base of these two bodies. The crustal bodies forms tectonic blocks in the Central Rif and in the Central Betic Cordillera.     

A three-scale cracking criterion for drying soils

Cracking is a most unwanted development in soil structures undergoing periodic drying and wetting. Desiccation cracks arise in an apparent absence of external forces. Hence, either an internal, self-equilibrated stress pattern resulting from kinematic incompatibilities, or a stress resulting from reaction forces at the constraints appear as a cracking cause, when reaching tensile strength. At a meso-scale, tubular drying pores are considered in the vicinity of a random imperfection, inducing a stress concentration in the presence of significant pore suction. This approach allows one to use the effective stress analysis, which otherwise, away from the stress concentration, usually yields compressive effective stress and hence a physically incompatible criterion for a tensile crack. Recent experiments on idealized configurations of clusters of grains provide geometrical data suggesting that an imperfection as a result of air entry deep into the granular medium penetrates over 4 to 8 internal radii of a typical pore could yield a tensile effective stress sufficient for crack propagation.     

The impact of health financing and CO<Subscript>2</Subscript> emission on health outcomes in Sub-Saharan Africa: A cross-country analysis

The current paper examines the relationship between health financing (public and out-of-pocket health financing), CO₂ emission and health outcomes in 35 Sub-Saharan African countries for the period of 1995–2012. The panel unit root and cointegration tests are conducted as pre-tests, followed by the estimation of the parameters using the FM-OLS and DOLS techniques. The findings of the study show the importance of public health financing as one of the major factors that lead to better health outcomes, whereas the out-of-pocket expenditure is found to be harmful to population health since it leads to increase under-5 mortality rate. Although the results show a negative relationship between CO₂ and health outcomes, still these results remain inclusive. In addition, the findings reveal the importance of socioeconomic factors such as income and education as key determinants of health outcomes.     

利用瞬变电磁和多频电磁方法监测地下水位及其对Hawara遗址的影响

利用瞬变电磁（TEM）和地面电磁（GEM）方法,本文研究了埃及Hawara遗址区的地下水对遗址的影响.这个遗址包括Hawara金字塔、北区墓地、以及被称作“迷宫”的南区墓葬场所.现今Hawara遗址已经完全荒废,被耕作区和Bahr Wahba运河包围.地表水和地下水会破坏Hawara金字塔和“迷宫”遗址的地基,现在金字塔入口已被淹没至地面下约6 m深处.本文在耕作区、金字塔以及“迷宫”等三个地区进行了TEM勘察;在“迷宫”地区进行了GEM勘察.综合分析以上两种勘察数据,我们发现,农业灌溉是浸入到地下的水的主要来源;本地区地下水位随着观测点及海拔的不同,在地面以下2~7 m之间变化.