Sedimentary provenance in the central Ribeira belt based on laser-ablation ICPMSPb/Pb zircon ages

²⁰⁷Pb/²⁰⁶Pb ages from 420 zircons from 9 upper amphibolite and granulite facies quartzites of the post-1.8 Ga metasedimentary cover from the Occidental and Oriental terranes from the Neoproterozoic central Ribeira belt, in eastern Brazil, are discussed. Ages from the Occidental terrane show that Proterozoic ages predominate with a modal class at 2.1–2.2 Ga and that Archean ages are less common and lie within the 2.5–3.6 Ga range. A wider dispersion on Proterozoic ages down to 1.1 Ga and youngest Neoproterozoic ages (550–700 Ma) were also observed and could be related to the Brasiliano/PanAfrican metamorphic events. The data show that detrital sediments of the Occidental terrane were derived predominantly from erosion of a 1.8–2.2 Ga Paleoproterozoic terrane with a small proportion of a 2.6–3.6 Ga Archean crust. Ages from the Oriental terrane are greatly dispersed, but show a significant proportion of ages between 1.7 and 2.1 Ga, although the great majority are between 0.5 and 1.6 Ga. Only 3 out of 144 grains yield Archean ages, between 2.5 and 2.9 Ga. Based on the greatest errors observed on the data from the Oriental Terrane (100–300 Ma), and a continuum of obtained ages between 2072 Ma (Paleoproterozoic) and 517 Ma (Cambrian), the more plausible interpretation is that the dispersion of ages results from partial resetting of the U–Pb system by Brasiliano metamorphism in Proterozoic–Archean zircons, although a Mesoproterozoic source could not be discarded.     

Oxygen and Ethene Biostimulation for a Persistent Dilute Vinyl Chloride Plume

Contamination of groundwater with chlorinated ethenes is common and represents a threat to drinking water sources. Standard anaerobic bioremediation methods for the highly chlorinated ethenes PCE and TCE are not always effective in promoting complete degradation. In these cases, the target contaminants are degraded to the daughter products DCE and/or vinyl chloride. This creates an additional health risk, as vinyl chloride is even more toxic and carcinogenic than its precursors. New treatment modalities are needed to deal with this widespread environmental problem. We describe successful bioremediation of a large, migrating, dilute vinyl chloride plume in Massachusetts with an aerobic biostimulation treatment approach utilizing both oxygen and ethene. Initial microcosm studies showed that adding ethene under aerobic conditions stimulated the rapid degradation of VC in site groundwater. Deployment of a full‐scale treatment system resulted in plume migration cutoff and nearly complete elimination of above‐standard VC concentrations.     

地磁数据分析的一些思考

通过若干实例,本文讨论了地磁数据分析中的一些方法.这些方法包括时间序列的多项式拟合,相关性分析,频谱分析和小波分析等.在Matlab和AutoSignal软件下实现了以上方法,并基于这些方法研究了地磁场形态和地磁现象的频谱特征.我们分析了Surlari观测台（余纬45.3°,经度26.3°）的地磁时间序列,并与Ottawa（余纬44.6°,〖JP2〗经度284.5°）,Canberra（余纬125.3°,经度149.3°）, Kakioka（余纬53.8°,经度140.2°）,Vernadsky〖JP〗（余纬155.3°,经度295.7°）等台站的结果进行了对比分析,讨论了Fourier变换时间窗和小波基函数选取的影响,有限长时间序列引起的边缘效应,以及小波尺度和Fourier频率的关系等问题.我们采用谱分析和小波分析处理了2007年两个台站的地磁数据,研究了地磁场形态和地磁现象的频谱特征,并讨论了Fourier变换和小波变换的优缺点.     

Quaternary interaction of cryospheric and oceanographic processes along the central‐east Greenland margin

The east Greenland margin has been influenced by oceanographic and cryospheric processes since the late Miocene, when the southwards flow of the East Greenland Current (EGC) initiated and ice sheets first advanced across the margin. However, the relative importance of these processes, and their influence on the sedimentation of the margin through time remains poorly understood. High‐resolution single‐channel seismic, chirp sub‐bottom profiles and swath bathymetry data were acquired along the middle/lower slope and proximal basinal area off Liverpool Land, central‐east Greenland margin. In this study, seismic‐stratigraphical and morphological analyses allowed us to distinguish between the major sedimentary processes that influenced this margin during the Quaternary. The stratigraphical architecture reveals mass transport deposits (MTDs) related to glacially influenced down‐slope sedimentation. These are intercalated with buried contourite systems associated with bottom‐current controlled along‐slope sedimentation. The distribution of the MTDs suggests the influence of two distinct ice‐stream systems. Initial phases of down‐slope deposition during the early‐middle Quaternary appears to be related to distal deposition fed by an ice stream from the Scoresby Sund area in the south. Shallow sedimentary processes, together with morphological analysis of the sea floor, show that the most recent activity of down‐slope processes during the latest Quaternary has occurred in the north, linked to an ice stream from the Kong Oscar Fjord area. These observations document a temporal shift in the relative dominance of the Scoresby Sund and Kong Oscar Fjord ice‐stream systems. The glacial influence on the margin has been interrupted by periods of stronger activity of along‐slope bottom‐current flow, demonstrating that the EGC periodically controlled sedimentation on the continental margin.     

On the migration of precursors of strong earthquakes

It is found that perturbations presumedly associated with swarms, the B patterns and the BG pattern precursors of strong earthquakes in New Zealand, California and Apennines, propagate in the crust of the Earth with a velocity of the order of cm¹. The hypothesis that a single travelling elastic perturbation causes a set of precursors of the same strong earthquake is discussed and it is concluded that each precursor is associated with a different perturbation.     

Temporal variation of ophiuroids associated with the macroalga Amphiroa fragilissima on a Southwest Atlantic coral reef

The species of Ophiuroidea that commonly occur on coral reefs can be found on different substrates and associated with other organisms including algae, sponges, and corals. This study evaluated the temporal variability of the ophiuroid fauna associated with the alga Amphiroa fragilissima on the Ponta Verde coral reef on the coast of Maceió in Alagoas, Northeastern Brazil. Replicate samples of algal substrate were collected at low tide during in the dry and rainy seasons, over a 10‐year period, from 1998–2007. Eight species of Ophiuroidea were identified, with a total of 8736 individuals associated with A. fragilissima. The most dominant and frequent species of Ophiuroidea were Amphipholis squamata and Ophiactis savignyi; all other species were rare. Cluster analysis and nMDS detected four groups, with two groups each occurring only in summer or winter periods, as well as other groups occurring in both periods.     

Interference Testing for Atmospheric HOx Measurements by Laser-induced Fluorescence

Accurate OH and HO₂ (collectively called HO_x) measurements by laser-induced fluorescence (LIF) may be contaminated by spurious signals from interfering atmospheric chemicals or from the instrument itself. Interference tests must be conducted to ensure that observed OH signal originates solely from ambient OH and is not due to instrument artifacts. Several tests were performed on the Penn State LIF HO_x instrument, both in the laboratory and in the field. Theseincluded measurements of the instrument's zero signal by using either zero air or perfluoropropylene to remove OH, examination of spectral interferences from naphthalene, sulfur dioxide, and formaldehyde, and tests of interferences by addition of suspected interfering atmospheric chemicals, including ozone, hydrogen peroxide, nitrous acid, formaldehyde, nitric acid, acetone, and organic peroxy radicals (RO₂). All tests lacked evidence ofsignificant interferences for measurements in the atmosphere, including highly polluted urban environments.     

Illuminating Subsurface Microbial Water Quality Patterns Using Adenosine Triphosphate and Dynamic Time Warping Approaches

Aquifer microbial water quality evaluations are often performed by collecting groundwater samples from monitoring wells. While samples collected from continuously pumped sources are seldom disputed as representative of the aquifer, natural biofilm present in the vicinity of well screens may introduce unwanted microbial artefacts in monitoring wells that are only periodically sampled. The need for well water purging to obtain samples void of these artefacts has been widely recognized. However, purging methods are not standardized; many approaches presume that physico-chemical water quality stability achieved through the removal of 3 to 5 well volumes is indicative of the stability of target analytes. Using a data set collected from a shallow unconfined aquifer in Southern Ontario, Canada, the need for using dedicated approaches that account for the time-dependent nature of microbial water quality changes was demonstrated. Specifically, the utility of adenosine triphosphate (ATP) as a rapid, field-ready biochemical indicator of microbial water quality stability was investigated. This work shows that ATP concentrations reflect time-limited (bio)colloid transport processes that are consistent with other microbial water quality parameters monitored, but different from commonly measured physical and chemical water quality indicators of well purging adequacy. ATP concentrations occasionally fluctuated even after 3 or 4 h of purging, indicating that microbial artefacts attributable to biofilms in the vicinity of the well screen can still persist. The recurrence of characteristic ATP patterns in each well was systematically examined through the novel application of dynamic time warping (DTW), a nonparametric time series analysis approach. These patterns are believed to be linked with seasonal hydrogeological conditions, which warrant consideration in the design and interpretation of subsurface microbial water quality investigations.     

Crystal chemistry, surface morphology and X-ray photoelectron spectroscopy of Fe-rich osumilite from Mt. Arci, Sardinia (Italy)

Microprobe analysis, single crystal X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy, and X-ray absorption spectroscopy were applied on Fe-rich osumilite from the volcanic massif of Mt. Arci, Sardinia, Italy. Osumilite belongs to the space group P6/mcc with unit cell parameters a = 10.1550(6), c = 14.306(1) Å and chemical formula (K_0.729)_C (Na_0.029)_B (Si_10.498 Al_1.502)_T1 (Al_2.706 Fe _0.294 ²⁺ )_T2 (Mg_0.735 Mn_0.091 Fe _1.184 ²⁺ )_AO₃₀. Structure refinement converged at R = 0.0201. Unit cell parameter a is related to octahedral edge length as well as to Fe²⁺ content, unlike the c parameter which does not seem to be affected by chemical composition. The determination of the amount of each element on the mineral surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s and Fe_2p core levels, suggests that Fe presents Fe²⁺ oxidation state and octahedral coordination. Two peaks at 103.1 and 100.6 eV can be related to Si⁴⁺ and Si¹⁺ components, respectively, both in tetrahedral coordination. The binding energy of Al_2p, at 74.5 eV, indicates that Al is mostly present in the distorted T2 site, whereas the Mg peak at 1,305.2 eV suggests that this cation is located at the octahedral site. X-ray absorption at the Fe L_2,3-edges confirms that iron is present in the mineral structure, prevalently in the divalent state and at the A octahedral site.     

A Comparison Between Machine Learning and Functional Geostatistics Approaches for Data-Driven Analyses of Sediment Transport in a Pre-Alpine Stream

Mathematical Geosciences - The problem of providing data-driven models for sediment transport in a pre-Alpine stream in Italy is addressed. This study is based on a large set of measurements...