A numerical technique for simulation of the effect of soil nitrogen transport and transformations on groundwater contamination

Two numerical models, one for the vadose zone and the other for the aquifer system, are utilized to predict nitrate pollution potential in groundwater. Transport by dispersion and convection of mobile species of nitrogen, ammonium ion exchange, first order nitrogen transformations, and nitrogen plant uptake are included in the formulation for the vadose zone. Transport of nitrate in the aquifer is assumed to be affected only by dispersion-convection phenomena. Justifications for one-dimensional conceptualization of flow in the vadose zone and two-dimensional representation for the aquifer, under various field conditions, are presented. To illustrate the concept, a simple hypothetical problem is solved. The approach presented here provides an efficient means of long-term simulation of large-scale field problems.     

Syn-depositional continental rifting of the Southeastern Neo-Tethys margin during the Albian–Cenomanian: evidence from stratigraphic correlation

ABSTRACT

Albian–Cenomanian successions (Kazhdumi and Sarvak formations) represent remarkable variations in thickness, facies, fauna, and environments throughout the Zagros area. In the Coastal Fars (Charmu section), sedimentological and paleontological data evidence an intrashelf, with depths of 10s–100s m, surrounded by a shallow carbonate platform. Due to its depth, deposition of sequences in this setting has been controlled by eustatic sea-level changes rather than eurybathic changes, and several condensation episodes occurred related to marine transgressions. These observations are different from those in the adjacent sections in the Coastal Fars which recorded subaerial exposures instead. Combined with previous studies, this study denotes several intrashelf basins enclosed by a shallow carbonate platform on the southeastern margin of the Neo-Tethys during the Albian–Cenomanian. Development of intrashelf basins corresponds to basement faults in the Fars Salient. Likely, an extensional tectonic regime associated with a rifting event created horst–graben architecture by exerting extension along the basement faults and reactivating salt structures. Deposition on these troughs and highs led to the facies and thickness variations of the concomitant sequences. Development of several intrashelf basins on the southeastern margin of the Neo-Tethys indicates that syn-depositional continental rifting event could occur during the Albian–Cenomanian, prior to the tectonic inversion around the earliest Turonian.     

Backcasting long-term climate data: evaluation of hypothesis

Most often than not, incomplete datasets or short-term recorded data in vast regions impedes reliable climate and water studies. Various methods, such as simple correlation with stations having long-term time series, are practiced to infill or extend the period of observation at stations with missing or short-term data. In the current paper and for the first time, the hypothesis on the feasibility of extending the downscaling concept to backcast local observation records using large-scale atmospheric predictors is examined. Backcasting is coined here to contrast forecasting/projection; the former is implied to reconstruct in the past, while the latter represents projection in the future. To assess our hypotheses, daily and monthly statistical downscaling models were employed to reconstruct past precipitation data and lengthen the data period. Urmia and Tabriz synoptic stations, located in northwestern Iran, constituted two case study stations. SDSM and data-mining downscaling model (DMDM) daily as well as the group method of data handling (GMDH) and model tree (Mp5) monthly downscaling models were trained with National Center for Environmental Prediction (NCEP) data. After training, reconstructed precipitation data of the past was validated against observed data. Then, the data was fully extended to the 1948 to 2009 period corresponding to available NCEP data period. The results showed that DMDM performed superior in generation of monthly average precipitation compared with the SDSM, Mp5, and GMDH models, although none of the models could preserve the monthly variance. This overall confirms practical value of the proposed approach in extension of the past historic data, particularly for long-term climatological and water budget studies.     

Soil organic carbon stock as affected by land use/cover changes in the humid region of northern Iran

This study was conducted to determine the changes in the soil carbon stocks as influenced by land use in a humid zone of Deylaman district(10,876 ha), a mountainous region of northern Iran. For this, land use maps were produced from TM and ETM+ images for 1985, 2000 and 2010 years; and this was supplemented by field measurement of soil carbon in 2010. The results showed that the mean soil organic carbon(SOC) density was 6.7±1.8 kg C m-2, 5.2±3.4 kg C m-2 and 3.2±1.8 kg C m-2 for 0-20 cm soil layer and 4.8±1.9 kg C m-2, 3.1±2 kg C m-2 and 2.7±1.8 kg C m-2 for 20-40 cm soil layer in forest, rangeland and cultivated land, respectively. During the past 25 years, 14.4% of the forest area had been converted to rangeland; and 28.4% of rangelands had been converted to cultivated land. According to the historical land use changes in the study area, the highest loss of SOC stocks resulted from the conversion of the forest to rangeland(0.45×104 Mg C in 0-40 cm depth layer); and the conversion of rangeland to cultivated land(0.37×104 Mg C in 0-40 cm), which typically led to the loss of soil carbon in the area studied. The knowledge on the historical land use changes and its influence on overall SOC stocks could be helpful for making management decision for farmers and policy managers in the future, for enhancing the potential of C sequestration in northern Iran.     

Advances in techniques to formulate the watertight concept for cadastre

The world’s rising urban density expansion has resulted in a proliferation of attempts to efficiently use space and a higher level of spatial complexity in metropolitan areas. 3D geospatial data models are increasingly being embraced to facilitate communicating the spatial dimensions of complex built environments in different applications. For example, the use of 3D models in land administration systems has been recognized as a good approach for communicating the spatial complexity of legal spaces within multi‐storey buildings. The spatial extent of legal space—to which rights, restrictions and responsibilities relate in a 3D digital cadastre—needs to be accurately defined and geometrically closed; watertight. Therefore, this study aims to address the challenges regarding checking the closure of diverse 3D legal spaces and engage several techniques to formulate the watertight concept for cadastre. The research’s methodology is built on a 3D polyhedral surface using a half‐edge data structure. A primitive check is employed to assess the spatial consistency of lower‐dimensional primitives of 3D objects. Subsequently, advanced closure checks ensure the closure of volumetric legal spaces represented by 2‐manifold and non‐2‐manifold data models. The article concludes that, by adopting the proposed approaches, the internal spatial consistency of legal spaces in urban land administration will be certified.     

First microbialites associated to organic-rich facies of the Oceanic Anoxic Event 2 (Northern Tunisia,Cenomanian–Turonian transition)

From northern Tunisia, small-scale well-preserved microbialites, contemporaneous to the global oceanic anoxic event 2 (OAE 2) are first reported on the southern Tethyan Margin. These microbialites are encased within the pelagic organic-rich black shales of the Bahloul Formation (Cenomanian–Turonian transition). Biostratigraphic, petrographic, and geochemical investigations carried out to constrain their biogenicity and genesis character led to consider them as thrombolites and stromatolites occurring in lenticular bioherms/biostromes and columnar bodies co-relatable to the global ‘filament event’ of the authors, close to the base of the Watinoceras ammonite zone. Abundant clotted micrite, cyanobacterial filaments, and algal tissues point to the key process of microbial carbonate precipitation and to a major role played by microbes in the stabilisation and subsequent lithification, which in turn favoured the preservation of the original structure of the microbialites. These microbially induced carbonate formations are considered as favoured by chemosynthetic fauna of bivalve molluscs and lithistid sponges which were able to host symbiotic microbial communities. The latter contributed to the precipitation of authigenic calcite and non-carbonate minerals (e.g. pyrite) fuelled by microbial activity under sulphate-reducing conditions. The carbonate body onset is considered to be initiated by seafloor instability due to syndepositional fault acting that induced the appraisal of uplifted tilted blocks within oxygenated waters but near the anoxic water masses. Generated depressions allowed the development of chemosynthetic-based communities. Deep faults related to Triassic salt domes acted as conducts for hydrocarbon and salt brine expulsion to the seafloor and the microbialite growth was enhanced by an abrupt uprising sea level under warmer conditions.     

Late Ediacaran crustal thickening in Iran: Geochemical and isotopic constraints from the ~550 Ma Mishu granitoids (northwest Iran)

The aim of this article is to examine the geochemistry and geochronology of the Cadomian Mishu granites from northwest Iran, in order to elucidate petrogenesis and their role in the evolution of the Cadomian crust of Iran. The Mishu granites mainly consist of two-mica granites associated with scarce outcrops of tonalite, amphibole granodiorite, and diorite. Leucogranitic dikes locally crosscut the Mishu granites. Two-mica granites show S-type characteristics whereas amphibole granodiorite, tonalities, and diorites have I-type signatures. The I-type granites show enrichment in large-ion lithophile elements (e.g. Rb, Ba and K) and depletion in high field strength elements (e.g. Nb, Ti and Ta). These characteristics show that these granites have been formed along an ancient, fossilized subduction zone. The S-type granites have high K, Rb, Cs (and other large ion lithophile elements) contents, resembling collision-related granites. U–Pb zircon dating of the Mishu rocks yielded ²³⁸U/²⁰⁶Pb crystallization ages of ca. 550 Ma. Moreover, Rb–Sr errorchron shows an early Ediacaran age (547 ± 84 Ma) for the Mishu igneous rocks. The two-mica granites (S-type granites) show high ⁸⁷Sr/⁸⁶Sr_(i) ratios, ranging from 0.7068 to 0.7095. Their ?Nd values change between ?4.2 and ?4.6. Amphibole granitoids and diorites (I-type granites) are characterized by relatively low ⁸⁷Sr/⁸⁶Sr_(i) ratios (0.7048–0.7079) and higher values of ?Nd (?0.8 to ?4.2). Leucogranitic dikes have quite juvenile signature, with ?Nd values ranging from +1.1 to +1.4 and Nd model ages (T_DM) from 1.1 to 1.2 Ga. The isotopic data suggests interaction of juvenile, mantle-derived melts with old continental crust to be the main factor for the generation of the Mishu granites. Interaction with older continental crust is also confirmed by the presence of abundant inherited zircon cores. The liquid-line of descend in the Harker diagrams suggests fractional crystallization was also a predominant mechanism during evolution of the Mishu I-type granites. The zircon U–Pb ages, whole rock trace elements, and Sr–Nd isotope data strongly indicate the similarities between the Mishu Cadomian granites with other late Neoproterozoic–early Cambrian (600–520 Ma) granites across Iran and the surrounding areas such as Turkey and Iberia. The generation of the Mishu I-type granites could be related to the subduction of the Proto-Tethyan Ocean during Cadomian orogeny, through interaction between juvenile melts and old (Mesoproterozoic or Archaean) continental crust. The S-type granites are related to the pooling of the basaltic melts within the middle–upper parts of the thick continental crust and then partial melting of that crust.     

Evolution of Pleistocene travertine depositional system from terraced slope to fissure-ridge in a mixed travertine-alluvial succession (Jebel El Mida,Gafsa, southern Tunisia)

The Quaternary stratigraphic record of Jebel El Mida, composed of continental deposits, is a useful example of concomitant travertines and alluvial deposition in an extensional setting. Travertine deposition occurred in a faulted Pleistocene alluvial fan giving rise to seven (recognised) facies interfingering with five other alluvial ones. The travertine depositional events indicate a tectonically driven evolution from terraced slope (facies group FC1–FC6) to a travertine fissure ridge-type depositing phase (facies group of FC1–FC7). Interfingering between travertine and alluvial facies indicates the co-existence of adjacent and time-equivalent depositional environments. The travertine deposition resulted from deep origin hydrothermal fluids channelled along damaged rocks volumes associated to a regional fault system, named as the Gafsa Fault (GF). The travertine–terrigenous succession in Jebel El Mida highlights the major role played by the GF in controlling: (i) the hydrothermal fluid flow, still active as also indicated by the numerous thermal springs aligned along the fault zone; (ii) paleoflow directions, discharge locations, volume, rate and fluctuations of the water supply. The paleoclimatic correlation with adjacent localities reveals that, at that time, humid episodes could have contributed to the recharge of the hydrothermal system and to the deposition of alluvial sediments.     

Evaluating distribution pattern of petrophysical properties and their monitoring under a hybrid intelligent based method in southwest oil field of Iran

This study deals with reservoir characterization based on well log data using an unsupervised self-organizing map (SOM) and supervised neural network algorithms with the aim of clustering log responses into reservoir facies of an oil field located in southwest of Iran. In order to promote and justify the quality control and quantify spatial relationships for petrophysical properties, some of neural network-based approaches were introduced such as the SOMs as the intelligent clustering method compared with other hybrid methods, principal component analysis networks (PCANs) and multilayer perceptron (MLP) and statistical clustering (CA) methods. The results obtained from all the abovementioned methods are compared to each other, and the best option is selected based on accuracy and capabilities of clustering and estimation of the petrophysical data, concluding that for predicting any characteristic of the reservoirs, the appropriate network should be chosen and a unique network cannot be convenient for all of them. Accordingly, the SOM clustering technique was employed to classify the reservoir rocks. Based on the SOM visualization, the reservoir rocks were classified into six facies associated with specific petrophysical properties; among them, F6 expressed the best reservoir quality which is characterized by the low amount of density, highest DT, high amount of neutron porosity (NPHI), and lowest GR response. Ultimately, the performance of all the methods was compared to estimate the porosity and permeability within each facies. The results revealed the preference and reliability of PCAN in predicting porosity and confirmed the capability of MLP in permeability prediction. This study also indicates that neuro-prediction of formation properties using well log data is a feasible methodology for optimization of exploration programs and reduction of expenditure by delineating potentially oil-bearing strata with higher accuracy and lower expenses. The resulting neural net-based model can be used as a powerful and distributive system to reduce the high impact of risk in similar fields.     

The impact of the geologic setting on the Quaternary aquifer,El-Tur area,Southwest Sinai,Egypt

The groundwater extracted from the unconfined Quaternary aquifer is the main source of water supply in El-Tur area. The area is bounded from the east by the elevated basement complex of Southern Sinai and from the west by El-Qabaliyat Ridge. The wadis dissecting these highlands form effective watersheds of the Quaternary aquifer. These wadis form areas of focused recharge. Recharge also occurs directly via the Quaternary sediments covering El-Qaa Plain. Subsurface lateral groundwater flow from the fractured basement contributes significant recharge to the aquifer as well. The aquifer sediment facies affect the type and quality of groundwater. In the eastern part where the aquifer is composed mainly of gravel and coarse sand with fragments of weathered basement, the Na-Cl-SO₄ water dominates. In the west where the facies change is rapid and complex, many water types arise. The base exchange index (BEX) is positive in this part reflecting the role of clay minerals in changing the water types via cation exchange. In the east where clays are insignificant in the aquifer, the BEX is negative. In the western part next to El-Qabaliyat Ridge, the wells discharging from the calcareous sand zone have low groundwater salinities compared to the wells discharging from the alluvium. In general, the groundwater salinity increases in the direction of groundwater flow from the northeast to the southwest which reflects the dissolution of aquifer sediments. The concentration relationships between the major ions on one hand and chloride on the other reflect the dissolution of calcium carbonates, precipitation of K- and Mg-bearing minerals, and cation exchange of Ca for Na on clay minerals. The hydrochemical models support these reactions. In addition, they show that the effect of evaporation on the recharge water in the western catchment is about four times its effect on the eastern recharge water which reflects the rapid recharge through the wadis draining the fractured basement. Moreover, the contribution from the eastern catchment in sample No. 23 is more than four-folds the contribution from the western recharge area. The stable isotopes (²H and ¹⁸O) show that the Quaternary aquifer is recharging from recent rainfall. However, upward leakage of Paleogene groundwater (depleted in ¹⁸O) also occurs. The groundwater level map shows strong overpumping impact especially in the areas close to El-Tur city.