Geochemical characteristics and hydrocarbon generation modeling of the Jurassic source rocks in the Shoushan Basin, north Western Desert, Egypt

The Shoushan Basin is an important hydrocarbon province in the Western Desert, Egypt, but the origin of the hydrocarbons is not fully understood. In this study, organic matter content, type and maturity of the Jurassic source rocks exposed in the Shoushan Basin have been evaluated and integrated with the results of basin modeling to improve our understanding of burial history and timing of hydrocarbon generation. The Jurassic source rock succession comprises the Ras Qattara and Khatatba Formations, which are composed mainly of shales and sandstones with coal seams. The TOC contents are high and reached a maximum up to 50%. The TOC values of the Ras Qattara Formation range from 2 to 54 wt.%, while Khatatba Formation has TOC values in the range 1-47 wt.%. The Ras Qattara and Khatatba Formations have HI values ranging from 90 to 261 mgHC/gTOC, suggesting Types II-III and III kerogen. Vitrinite reflectance values range between 0.79 and 1.12 VRr %. Rock−Eval T_max values in the range 438-458 °C indicate a thermal maturity level sufficient for hydrocarbon generation. Thermal and burial history models indicate that the Jurassic source rocks entered the mature to late mature stage for hydrocarbon generation in the Late Cretaceous to Tertiary. Hydrocarbon generation began in the Late Cretaceous and maximum rates of oil with significant gas have been generated during the early Tertiary (Paleogene). The peak gas generation occurred during the late Tertiary (Neogene).     

Temporal Variations in the Dissolved Nutrient Stocks in the Surface Water of the Western North Atlantic Ocean

Changes in patterns of undetectability and molar ratios of dissolved nutrients in the euphotic zone of the oligotrophic western North Atlantic Ocean were investigated utilizing the Bermuda Atlantic Time-series Study (BATS) data set of the US Joint Global Ocean Flux Study (JGOFS). Our aim was to examine the temporal dynamics of nutrient stocks over a decade (1989∼1998) and to gain insight into the interactions between the different biotic and abiotic factors underlying BATS. Patterns of nutrient undetectability clearly revealed the depleted nature of the nutrients in surface water at the BATS location, particularly phosphorous. The N:P ratio was consistently far above the nominal Redfield ratio (mean, 38.5) but was significantly lower during the 1993∼1994 period (22.1). Over the same period the proportion of samples depleted in N only increased while the proportion of samples depleted in P only decreased. This indicates an overall reduction of N relative to P in the surface water at BATS during the 1993∼1994 period, the reasons for this anomaly, though, are not clear. The correlation analysis between the biotic and abiotic variables at BATS has indicated some interesting relationships that can help understand some of the parameters affecting nutrient stocks in the euphotic zone and their consequent impacts on marine biota. Although nutrient stocks in the oligotrophic environment are limited, they might be subject to interannual variation that may become anomalous in some cases. These variations might underlay significant feedback mechanisms by affecting marine productivity, the prime factor controlling the sequestration of atmospheric CO₂ by the oceans. This revised version was published online in July 2006 with corrections to the Cover Date.     

Embayment characteristic time and biology via tidal prism model

Transport time scales are often offered by scientists, and accepted by ecologists, as qualitative indicators of the susceptibility of ecological components within an embayment. However, rigorous quantitative methods were never presented to confirm this intuition. Transport time scales in water bodies are classically based on their physical and chemical aspects rather than their ecological and biological character. The direct connection between a physical time scale and an ecological effect has to be investigated in order to quantitatively relate a transport time scale to ecology. This concept is presented here with some general guidelines and clarifying examples. To be able to relate physical time scales to biological processes, a simple tidal prism model is developed that calculates temporal changes in concentration and the related exposure. This approach provides a quick method to calculate the characteristic time for transport in a large number of embayments, which can also help in classification endeavors.     

Geochemical variation of the groundwater characters along Wadi Qudaid,northeast Jeddah,westcentral Arabian Shield,Saudi Arabia

Wadi Qudaid is present about 120 km northeast of Jeddah, Saudi Arabia. The area includes Precambrian Arabian Shield, Tertiary sedimentary rocks, Tertiary basic volcanics (harrat), and finally Quaternary wadi deposits which represent the main aquifer of Wadi Qudaid area. The present study indicates the presence of pronounced geochemical variations in the groundwater characters along the main channel of Wadi Qudaid from the southwestern part (downstream) to the northeastern (upstream) part. The groundwater-bearing horizon is thicker in the downstream part than the upstream part. The study also revealed that the groundwater is of good quality in the upstream (NE) part than the downstream (SW) part. This is related to the addition and depletion of many elements during the groundwater trip from NE to SW and the addition and depletion of some elements. The downstream part is of high hardness and TDS when compared with the upstream part. Also, the downstream part is of high bisnous element (As, Co, Ni) than the upstream part. The groundwater of the southwestern part of Wadi Qudaid are free from the following elements: i.e., Al, Mn, Fe, Ni, Cu, Zn, and Pb.     

Real surface conductivity component as indicator for the hydraulic conductivity

Estimation of hydraulic conductivity from surface resistivity measurements is one of the most difficult and challenging hydrogeophysical targets. The promising side of this relation is the analogy between electric current flow and water flow, whereas the grand ambiguity is the non-dimensionality between both two quantities. Imaginary surface conductivity component is used recently to deduce the hydraulic conductivity via complex resistivity measurements. Since there are similar properties between imaginary (out-of-phase) and real (in-phase) surface conductivity components, the latter is used in this paper to predict the hydraulic conductivity. Two mathematical parameters were determined to express the electrical equivalent of hydraulic conductivity in sand and clay systems based on the mode of electrical double-layer formation in both systems. The reliability of the proposed method is tested through applying on two datasets representing sand and clay systems. The first dataset is a clean sand and gravel aquifer in the Keritis basin in Chania, Crete, Greece. The second is mostly clayey sand aquifer in Wadi El-Assuity, Egypt. Application of the present approach in these two cases resulted in promising nearly identical values with the measured hydraulic conductivity via pumping test or geometric hydraulic conductivity via grain size analysis.     

Duration Magnitude Scale and Site Residuals for Northern Morocco

— The first empirical duration magnitude (M_D) formula is developed and tested for the Northern Morocco Seismic Network (NMSNET). This relationship is obtained by relating the IGN (Instituto Geografico National, Madrid) body-waves mbLg^IGN to the duration (), and the epicentral distance (), at 25 analogue stations of the NMSNET for 479 earthquakes with 2.5 mb 5.4, from March 1992 to February 2001. M_D estimates are significantly more precise while introducing a correction term for each of these stations, cSta_j. The magnitude for the i^th event (M_D)_i is the mean value of individual M_Dij=–0.14+1.63log₁₀(_ij)+0.031(_ij)+cSta_j. The cSta_j corrections reduce considerably the local site effects which influence the recorded durations and cause stations to either overestimate, or underestimate M_D up to 0.5 magnitude units. Average station M_D residuals (–cSta_j) are found to be independent of the distance from the epicenter to at least 10 degrees. It seems evident that regional geological features in the immediate behavior of stations have a systematic effect on the corresponding obtained residuals: older well-consolidated Precambrian crystalline rocks produce high negative residuals (shorter durations), younger unconsolidated sediments produce high positive residuals (longer durations), whereas, intermediate M_D site residuals appear to be the result of the effect of various factors, principally age and state of consolidation of the bedrock, combined with the local tectonic.     

Toward mapping land-use patterns from volunteered geographic information

A large number of applications have been launched to gather geo-located information from the public. This article introduces an approach toward generating land-use patterns from volunteered geographic information (VGI) without applying remote-sensing techniques and/or engaging official data. Hence, collaboratively collected OpenStreetMap (OSM) data sets are employed to map land-use patterns in Vienna, Austria. Initially the spatial pattern of the landscape was delineated and thereafter the most relevant land type was assigned to each land parcel through a hierarchical GIS-based decision tree approach. To evaluate the proposed approach, the results are compared with the Global Monitoring for Environment and Security Urban Atlas (GMESUA) data. The results are compared in two ways: first, the texture of the resulting land-use patterns is analyzed using texture-variability analysis. Second, the attributes assigned to each land segment are evaluated. The achieved land-use map shows kappa indices of 91, 79, and 76% agreement for location in comparison with the GMESUA data set at three levels of classification. Furthermore, the attributes of the two data sets match at 81, 67, and 65%. The results demonstrate that this approach opens a promising avenue to integrate freely available VGI to map land-use patterns for environmental planning purposes.