Characteristics of Porphyry Cu Mineralization at Waisoi (Namosi District), Viti Levu, Fiji

The porphyry Cu deposits at Waisoi in Namosi district, Viti Levu are separated into two deposits: the Waisoi East deposit and the Waisoi West deposit. In the Waisoi East deposit, quartz porphyry is exposed and in the Waisoi West deposit, diorite porphyry is sporadically exposed in addition to a small body of quartz porphyry. The mineralization in the Waisoi East deposit is characterized by the bornite–chalcopyrite–pyrite assemblage associated with traces of molybdenite and native gold. Polyphase fluid inclusions in stockwork quartz veinlets show homogenization temperatures ranging from 210 to >500°C. The high‐grade Cu mineralization in the Waisoi West deposit is characterized by the bornite–chalcopyrite–pyrite assemblage accompanied with sheeted and stockwork quartz veinlets. Polyphase fluid inclusions occasionally containing hematite flakes in quartz veinlets in the center of the Waisoi West deposit homogenize at temperatures ranging from 450°C to >500°C. However, fluid inclusions in stockwork quartz veinlets in the periphery, homogenize at lower temperatures around 210°C. Both in the Waisoi East and Waisoi West deposits, primary bornite–chalcopyrite–pyrite assemblage in the high Cu‐grade zone was deposited at the upper stability limit of chalcopyrite with respect to sulfur fugacity. Thus, the principal Cu mineralization at the Waisoi deposits occurred at a relatively high sulfur fugacity, that is, in a high‐sulfidation environment.     

Deposition rates of polysilicic acid with up to 10 M calcium ions

Cementitious materials used for radioactive waste repository construction complicate the performance assessment of radioactive waste systems because the use of cement may greatly alter the pH (8–13) of groundwater and release constituents such as calcium ions. Under such conditions, it is important to clarify also the dynamic behavior of silica (silicic acid), in order to evaluate the alteration in the chemical and physical properties of the fractured layer or the host rock surrounding the repository. Since silica undergoes polymerization, precipitation or dissolution depending on the pH and/or temperature, the behavior of silica would be greatly complicated in the presence of other ions. This study is focused on the deposition rates of polysilicic acid and soluble silicic acid with up to 10⁻³ M Ca ions. In the experiment, Na₂SiO₃ solution (250 mL, pH > 10, 298 K) was poured into a polyethylene vessel containing amorphous silica powder (0.5 g), and a buffer solution, HNO₃, and CaNO₃ as Ca ions were sequentially added into the vessel. The pH of the solution was set to 8. The silica, initially in a soluble form at pH > 10 (1.4 × 10⁻² M), became supersaturated and either deposited on the solid surface or changed into the polymeric form. Then the concentrations of both poly- and soluble silicic acid were monitored over a 40-day period. The decrease of polysilicic acid became slow with an increase in the concentration of Ca ions in the range of up to 10⁻³ M. In general, the addition of electrolytes to a supersaturated solution accelerates the aggregation and precipitation of polymeric species. However, the experimental result showed that polysilicic acid in the presence of Ca ions is apparently stable in solution, compared with that under a Ca-free condition. On the other hand, the concentration of soluble silicic acid in the presence of Ca ions immediately became metastable, that is, slightly higher than the solubility of soluble silicic acid. Its dynamic behavior was similar to that in the Ca-free condition.     

Fluid infiltration associated with seismic faulting: Examining chemical and mineralogical compositions of fault rocks from the active Chelungpu fault

In order to understand the fault zone architecture and mechanisms that caused the Chi-Chi earthquake, the Chelungpu drilling project was conducted during April 2000 through a collaborative project between Japan and Taiwan. In this study, chemical and mineralogical variations within the overall Chelungpu fault zone, including variations between less damaged host rocks, damaged zones, and fault cores caused by the Chi-Chi earthquake were examined. Slopes of TiO₂ immobile isocons were consistently > 1 for analyses comparing host rocks with rocks from damaged zones or with gouges from fault cores, indicating that volume loss occurred in damaged zones and the fault cores. These results strongly imply that pervasive fluid infiltration occurred within the fault zone. Volume loss within the damaged zone and fault core is interpreted to result from a two-stage process involving: (i) coseismic mechanical wearing and/or dissolution in the fault core, and (ii) fluid infiltration within the fault zone during postseismic and interseismic periods along cracks caused by seismic failure. Semi-quantitative XRD analysis indicates that the kaolinite content consistently increases from the less damaged host rocks to the damaged zone and gouges in each fault core. Mineralogic changes indicate that pervasive acidic fluid infiltration occurred within the fault zones and reacted with the feldspars or muscovite to form kaolinite. Enrichment of kaolinite and illite found in the fault zones of southern drilling site could play some role on the slipping behavior of the southern part of the Chelungpu fault. Greater volume loss in the fault core may have resulted from moderate permeability, combined with the very fine grain nature of pulverized material in the fault core, which enhanced chemical reactions including transformation of feldspars and muscovite to clay minerals. The study results indicate that pervasive fluid infiltration occurred and changed the mineralogical and chemical architecture of fault zones caused by the cyclic earthquakes.     

In situ hydraulic tests in the active fault survey tunnel, Kamioka Mine, excavated through the active Mozumi-Sukenobu Fault zone and their hydrogeological significance

Abstract   The spatial hydrogeological and structural character of the active Mozumi-Sukenobu Fault (MSF) was investigated along a survey tunnel excavated through the MSF in the Kamioka Mine, central Japan. Major groundwater conduits on both sides of the MSF are recognized. One is considered to be a subvertical conduit between the tunnel and the surface, and the other is estimated to be a major reservoir of old meteoric water alongside the MSF. Our studies indicate that part of the MSF is a sub-vertical continuous barrier that obstructs younger meteoric water observed in the south-eastern part of the Active Fault Survey Tunnel (AFST) and water recharge to the rock mass intersected by the north-western part of the AFST. The MSF might be a continuous barrier resulting in the storage of a large quantity of older groundwater to the northwest. The observations and results of in situ hydraulic tests indicate that the major reservoir is not the fault breccia associated with the northeast–southwest trending faults of the MSF, but the zone in which blocks of fractured rocks occur beside high angle faults corresponding to X shears whose tectonic stress field coincides with the present regional stress field and antithetic Riedel shears of the MSF. The results from borehole investigations in the AFST indicate that secondary porosity is developed in the major reservoir due to the destruction of filling minerals and fracture development beside these shears. The increase in hydraulic conductivity is not directly related to increased density of fractures around the MSF. Development of secondary porosity could cause the increase in hydraulic conductivity around the MSF. Our results suggest that minor conduits of the fracture network are sporadically distributed in the sedimentary rocks around the MSF in the AFST.     

Fracture-zone conditions on a recently active fault: insights from mineralogical and geochemical analyses of the Hirabayashi NIED drill core on the Nojima fault, southwest Japan, which ruptured in the 1995 Kobe earthquake

An 1800-m-deep borehole into the Nojima fault zone was drilled at Nojima-Hirabayashi, Japan, after the 1995 Hyogo-ken Nanbu (Kobe) earthquake. Three possible fracture zones were detected at depths of about 1140, 1300, and 1800 m. To assess these fracture zones in this recently active fault, we analyzed the distributions of fault rocks, minerals, and chemical elements in these zones. The central fault plane in the shallowest fracture zone was identified by foliated blue-gray gouge at a depth of 1140 m. The degree of fracturing was evidently greater in the hanging wall than in the footwall. Minerals detected in this zone were quartz, orthoclase, plagioclase, and biotite, as in the parent rock (granodiorite), and also kaolinite, smectite, laumontite, stilbite, calcite, ankerite, and siderite, which are related to hydrothermal alteration. Biotite was absent in both the hanging wall and footwall across the central fault plane, but it was absent over a greater distance from the central fault plane in the hanging wall than in the footwall. Major element compositions across this zone suggested that hydrothermal alteration minerals such as kaolinite and smectite occurred across the central fault plane for a greater distance in the hanging wall than in the footwall. Similarly, H₂O+ and CO₂ had higher concentrations in the hanging wall than in the footwall. This asymmetrical distribution pattern is probably due to the greater degree of wall–rock fracturing and associated alteration in the hanging wall. We attributed the characteristics of this zone to fault activity and fluid–rock interactions. We analyzed the other fracture zones along this fault in the same way. In the fracture zone at about 1300 m depth, we detected the same kinds of hydrothermal alteration minerals as in the shallower zone, but they were in fewer samples. We detected relatively little H₂O+ and CO₂, and little evidence for movement of the major chemical elements, indicating little past fluid–rock interaction. In the fracture zone at about 1800 m depth, H₂O+ and CO₂ were very enriched throughout the interval, as in the fracture zone at about 1140 m depth. However, smectite was absent and chlorite was present, indicating the occurrence of chloritization, which requires a temperature of more than 200 °C. Only smectite can form under the present conditions in these fracture zones. The chloritization probably occurred in the past when the fracture zone was deeper than it is now. These observations suggest that among the three fracture zones, that at about 1140 m depth was the most activated at the time of the 1995 Hyogo-ken Nanbu (Kobe) earthquake.     

The effect of artificial viscosity on a hydrodynamic model of Cepheids

The effect of artificial viscosity on a hydrodynamic simulation of stellar radial pulsation is examined for the purpose of studying the dependence of the modal coupling on the sharpness of the shock front. The model used in our study is a 2.5-d first-overtone pulsator in the Cepheid instability strip. By increasing the parameters in the von Neumann–Richtmyer formula of artificial viscosity, we obtained a low growth rate together with a small pulsation amplitude. The time-scale related to pulsation mode-switching is also increased.     

Fine S wave velocity structure beneath Iwate volcano, northeastern Japan, as derived from receiver functions and travel times

A genetic algorithm inversion of receiver functions derived from a dense seismic network around Iwate volcano, northeastern Japan, provides the fine S wave velocity structure of the crust and uppermost mantle. Since receiver functions are insensitive to an absolute velocity, travel times of P and S waves propagating vertically from earthquakes in the subducting slab beneath the volcano are involved in the inversion. The distribution of velocity perturbations in relation to the hypocenters of the low-frequency (LF) earthquakes helps our understanding of deep magmatism beneath Iwate volcano. A high-velocity region (dV_S/V_S=10%) exists around the volcano at depths of 2–15 km, with the bottom depth decreasing to 11 km beneath the volcano’s summit. Just beneath the thinning high-velocity region, a low-velocity region (dV_S/V_S=−10%) exists at depths of 11–20 km. Intermediate-depth LF (ILF) events are distributed vertically in the high-velocity region down to the top of the low-velocity region. This distribution suggests that a magma reservoir situated in the low-velocity region supplies magma to a narrow conduit that is detectable by the hypocenters of LF earthquakes. Another broad low-velocity region (dV_S/V_S=−5 to −10%) occurs at depths of 17–35 km. Additional clusters of deep LF (DLF) events exist at depths of 32–37 km in the broad low-velocity zone. The DLF and ILF events are the manifestations of magma movement near the Moho discontinuity and in the conduit just beneath the volcano, respectively.     

Measurements of electric charge distribution in volcanic plumes at Sakurajima Volcano,Japan

Measurements of perturbations in the atmospheric potential gradient around volcanic plumes at multiple (from two to five) sites, and measurements of the charge-mass ratio of ash particles falling from volcanic plumes, were carried out at Sakurajima Volcano, Japan. Results from 28 and 29 October 1995, show that the nature of the perturbations depends on the intensity of plume activity. Although plume activity was vigorous on 28 October, negative perturbations were predominant. As plume activity peaked, the magnitude of negative perturbations decreased just below the plume and increased at an off-axis site. During the peak period, positively charged ash particles fell out from the plume. This suggests that the active plume dominantly contained negatively charged materials, and that positively and negatively charged materials were added to the lower and upper parts of the plume, respectively, during the peak period. On the other hand, as plume activity became less vigorous on 29 October, the perturbations were characterized by a positive anomaly followed by a negative anomaly. Because wind velocity increased with altitude that day, we infer that positive and negative charges were distributed in the upper and lower parts of the plume, respectively. The differences in perturbations observed on 28 and 29 October suggest that volcanic plumes are generally composed of three parts: an upper part with positively charged gas and aerosol, a middle part with negatively charged fine ash particles, and a lower part with positively charged coarse ash particles. The compilation of present and previous results from Sakurajima and other volcanoes indicates that the effect of the negative charge in the middle part was predominant in most cases, although positive perturbations caused by the upper part were observed around some weak plumes. The effect of positively charged particles in the lower part was observable only when plume activity was sufficiently strong because positively charged coarse particles tended to fall out near the vent.