测定锰矿石中低含量钒的试验

化学分析工作要求测试快速、准确,低含量钒的测定因流程长,操作复杂,不易掌握,影响了推广使用。该试验采用分光光度法针对锰矿石中钒的测定进行了改进,取得了良好的效果。该法采用过氧化钠-碳酸钠熔融、水浸取,吸取清液依次加入硝酸、磷酸、钨酸钠溶液生成可溶性的黄色磷钨钒酸络合物,测量其吸光度,大大提高了分析效率。     

端头扩大型土锚的新发展 ——船锚式注浆张开型土锚

作为提高锚固性能的一种有效手段，端头扩大型土锚被广泛应用于实际工程。介绍了端头扩大型锚杆的各种扩孔方法，重点阐述一种新型的船锚式注浆张开型土锚。带有锚抓的新型土锚，不需要专门的扩孔机械，在注浆作用下能连续完成端头扩张与灌浆，具有施工方便、锚固面大、效果好等优点。通过对土锚进行张开试验，证明了在上海等软土地区通过灌浆压力使锚抓张开并形成扩大头是能够实现的。     

非线性支持向量机在油气预测中的应用

油气预测的传统方法通常是基于经验风险最小化准则,但在有限样本情况下,预测效果并不理想.研究引入基于结构化风险最小化准则的非线性支持向量机方法,通过对推广误差界的最小化达到最大的泛化能力和全局最优,时于小样本数据,该方法具有可靠的预测能力.在对四川观音场构造面新统上部碳酸盐岩储层数据处理中.通过实例试算,结果表明该方法有效可靠,预测精度高,与已知结果吻合较好.     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

西藏冈底斯带阿索构造混杂岩南侧亚布努马花岗斑岩地球化学特征及锆石U-Pb年龄

西藏中冈底斯北部尼玛县阿索乡亚布努马地区东侧出露一处花岗斑岩岩脉,LA-ICP-MS锆石U-Pb测年结果显示,该花岗斑岩的形成时代为晚侏罗世(161.2±5.9Ma)。全岩地球化学数据显示其高硅、富碱、富铝的特征,属于碱性准铝质花岗斑岩;富集轻稀土元素,轻、重稀土元素分异明显,具有明显的负Eu异常,富集Rb、Pb等大离子亲石元素,亏损Ba、Sr元素及Nb、Ta、Ti、U等高场强元素,形成于岛弧环境。其源区可能为来自俯冲带增厚下地壳的深熔作用,结合区域上同时代的岩浆事件,亚布努马花岗斑岩应该形成于以班公湖-怒江洋南向俯冲为动力背景的陆缘弧环境。     

中国省区循环经济预评估及区域差异研究

以省(区)为基本空间单元,构建了区域循环经济预评估指标体系,建立循环经济预评估的数学模型,并对中国大陆31个省(区)进行循环经济的事前评估,为不同省(区)开展循环经济的动态评估奠定了基础,同时对不同省(区)探索差异化的循环经济发展策略起到了基础性的探索作用。评估结果显示不同省(区)发展循环经济前的状况和特点存在明显的地区差异,因此,不同的省份在推行循环经济的发展过程中应实行差别化的策略。     

Fault Systems and their Control of Deep Gas Accumulations in Xujiaweizi Area

A study of faults and their control of deep gas accumulations has been made on the basis of dividing fault systems in the Xujiaweizi area. The study indicates two sets of fault systems are developed vertically in the Xujiaweizi area, including a lower fault system and an upper fault system. Formed in the period of the Huoshiling Formation to Yingcheng Formation, the lower fault system consists of five fault systems including Xuxi strike-slip extensional fault system, NE-trending extensional fault system, near-EW-trending regulating fault system, Xuzhong strike-slip fault system and Xudong strike-slip fault system. Formed in the period of Qingshankou Formation to Yaojia Formation, the upper fault system was affected mainly by the boundary conditions of the lower fault system, and thus plenty of multi-directionally distributed dense fault zones were formed in the T2 reflection horizon. The Xuxi fault controlled the formation and distribution of Shahezi coal-measure source rocks, and Xuzhong and Xudong faults controlled the formation and distribution of volcanic reservoirs of Y1 Member and Y3 Member, respectively. In the forming period of the upper fault system, the Xuzhong fault was of successive strong activities and directly connected gas source rock reservoirs and volcanic reservoirs, so it is a strongly-charged direct gas source fault. The volcanic reservoir development zones of good physical properties that may be found near the Xuzhong fault are the favorable target zones for the next exploration of deep gas accumulations in Xujiaweizi area.     

湘西北页岩层地震反射波组特征研究

湘西北地区发育寒武系下统牛蹄塘组、志留系下统龙马溪组两套富有机质黑色页岩。通过合成地震记录和已知地质特征推断反射层位的方法,对两套含烃黑色页岩层的地震地质特征、波组层位识别、波组特征进行了分析对比,总结出湘西北地区页岩层地震反射波所具有的典型特征:龙马溪组存在3~4个强相位,主频集中在30Hz左右;牛蹄塘组存在3个强反射界面,因深度加大,其主频集中在20Hz左右。由于龙马溪组和牛蹄塘组二组地层间距达2 500~3 000m,因此在湘西北地区将二组地层的反射波视作一个波系,其二维地震剖面存在3个波组4个反射层位或3个波组3个反射层位,三个波组分别为龙马溪组,中寒武底界及牛蹄塘组。另外因龙马溪组砂质泥岩段具有低速、低密度、低电阻率、高放射性等特征,其界面波阻抗差异较大,可作为本区的地震波标志层位。