Geochronology,stratigraphy and geochemistry of Cambro-Ordovician,Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean–island magmatism

International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were...     

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.     

Extreme waves induced by cyclone Nargis at Myanmar coast: numerical modeling versus satellite observations

Natural Hazards - The deltaic coast of Myanmar was severely hit by tropical cyclone Nargis in May 2008. In the present study, a top-down numerical simulation approach using the Weather Research and...     

Age and origin of groundwater resources in the Ararat Valley,Armenia: a baseline study applying hydrogeochemistry and environmental tracers

Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ²H, δ¹⁸O) and radioactive (³⁵S, ³H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (³⁵S), the detected ³H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.

     

Equilibrium erosion of soft rock shores with a shallow or absent beach under increased sea level rise

A process-based numerical model was used to explore the response of soft rock shores with low volume beaches to variable rates of sea level rise. Equilibrium recession rates were simulated for ranges of wave height and period, tidal amplitude, rock strength, beach volume and rate of sea level rise. Equilibrium shore profiles were found to be steeper with higher rates of sea level rise. Beaches were represented as protective surfaces yet were found to cause no significant reduction in equilibrium recession rate when their volumes were below a critical threshold. Reduced equilibrium recession rates were found with beaches that extended sufficiently far below low tide level. The model results imply that, given several constraints, a very simple relationship exists between increased rates of sea level rise and the response of eroding composite soft rock/low volume beach shores.     

Sediment resuspension events induced by the wake wash of deep-draft vessels

Hydrodynamics and sediment resuspension events, induced at the shoreline by a deep-draft vessel passing nearby, are described. Measurements (pressure, currents and turbidity) were obtained at 4 Hz, on a lower beach ~50 m from a channel where large car ferries operate in Wootton Creek, Isle of Wight. The study focuses on a representative 8-min 32-s-long record, during which two large vessels passed the channel section. At the shore, the passage of each vessel induced a long-period water-level drawdown, followed by a water-level oscillation (seiche) of similar period, and the short-period waves of the wake. Both drawdowns were the main constituents of the prevailing wave pattern. The second drawdown was the largest in amplitude, in response to a higher speed of the ferry, and the influence of the seiche which had been activated during the preceding event. Two successive peaks of turbidity were observed shortly after this drawdown. Analyses of current velocity and direction indicate that the sediments resuspended originated from the shallower upper beach. Anthropogenically induced erosion of the foreshore is predicted at Wootton Creek.     

The curse of physiology—challenges and opportunities in the interpretation of geochemical data from mollusk shells

Physiology corrupts geochemical records of mollusk shells in many ways, e.g., by actively controlling the incorporation of trace elements in the skeleton. However, the effects of variable biomineralization rates and growth cessation have largely remained unconsidered. Mediated by endogenous timekeeping mechanisms, mollusks stop growing skeletal material on a regular basis ranging from ultradian to annual timescales. During growth cessation, the shells do not record environmental conditions. Shell growth also stops when environmental conditions are beyond the physiological tolerance of the organism, e.g., above and below genetically determined, species-specific thermal extremes where shell growth slows and eventually ceases. Such growth disruptions can occur at non-periodic time intervals. Due to growth retardations and halts, proxy records of mollusk shells are thus incomplete, and reconstructed environmental amplitudes prone to truncation. Furthermore, environmental records are biased toward the physiological optimum of the animal. Favorable environmental conditions increase shell growth, whereas adverse environmental conditions result in reduced shell production and lowered overall metabolism. Not least, the duration of the growing season and overall growth rate decrease as the mollusk grows older. Mathematical modeling approaches can significantly improve proxy records obtained from mollusk shells. For example, if the duration of growth cessation is known, it may be possible to model the missing environmental record. It is also fairly easy to account for age-related growth trends, or variable time-averaging in different portions of the shell. However, a major premise for a reliable interpretation of proxy records from a mollusk shell or other organisms secreting biogenic hard parts is a proper understanding of the physiology, and of course, a high-resolution record of the many different environmental factors that may influence physiology and shell growth. The present paper reviews examples from the literature, and unpublished data on how physiology influences geochemical proxy records from mollusk shells, and presents methods how to eliminate such adverse effects.     

Time to talk knowledge

As part of the secondary school qualification repackaging, the Ministry of Education has requested the geography education community define what constitutes their “critical body of knowledge.” In this article, I discuss three knowledge‐oriented themes focused on: (a) recent assessment trends in geography; (b) the predictive value of NCEA Level 3 geography with 100‐level success and (c) the nature of knowledge as expressed by the New Zealand Curriculum and assessment. Taken together, these themes suggest a need for a serious conversation about knowledge in school geography, as a pre‐cursor to the re‐design of the geography standards matrix.