Occurrence of naphthalenesulfonates and their condensates with formaldehyde in a landfill leachate and their transport behavior in groundwater of the Upper Rhine Valley, Germany

. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l^–1, which decreased to 9.5 µg l^–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.     

Cluster gets to grips with the magnetosphere

On 9 November 2001 RAS hosted the first UK meeting to discuss results from Cluster, itself the first mission to explore the Earth's magnetosphere with four identically instrumented spacecraft – and thus fully resolve the complex spatial and temporal variations of the plasmas that fill space around the Earth. Mike Hapgood reports.     

Synclinal-horst basins: examples from the southern Rio Grande rift and southern transition zone of southwestern New Mexico, USA

In areas of broadly distributed extensional strain, the back‐tilted edges of a wider than normal horst block may create a synclinal‐horst basin. Three Neogene synclinal‐horst basins are described from the southern Rio Grande rift and southern Transition Zone of southwestern New Mexico, USA. The late Miocene–Quaternary Uvas Valley basin developed between two fault blocks that dip 6–8° toward one another. Containing a maximum of 200 m of sediment, the Uvas Valley basin has a nearly symmetrical distribution of sediment thickness and appears to have been hydrologically closed throughout its history. The Miocene Gila Wilderness synclinal‐horst basin is bordered on three sides by gently tilted (10°, 15°, 20°) fault blocks. Despite evidence of an axial drainage that may have exited the northern edge of the basin, 200–300 m of sediment accumulated in the basin, probably as a result of high sediment yields from the large, high‐relief catchments. The Jornada del Muerto synclinal‐horst basin is positioned between the east‐tilted Caballo and west‐tilted San Andres fault blocks. Despite uplift and probable tilting of the adjacent fault blocks in the latest Oligocene and Miocene time, sediment was transported off the horst and deposited in an adjacent basin to the south. Sediment only began to accumulate in the Jornada del Muerto basin in Pliocene and Quaternary time, when an east‐dipping normal fault along the axis of the syncline created a small half graben. Overall, synclinal‐horst basins are rare, because horsts wide enough to develop broad synclines are uncommon in extensional terrains. Synclinal‐horst basins may be most common along the margins of extensional terrains, where thicker, colder crust results in wider fault spacing.     

Weather as a Chronic Hazard for Road Transportation in Canadian Cities

Inclement weather creates a chronic hazard for Canadian travellers. Past studies indicate that road collision rates increase during precipitation, although the magnitude of theincrease varies from study to study, partly as a result of variations in weather and driving conditions,but also because of differences in methods. The goal of the current study is to improve ourunderstanding of the links between weather and travel risk in mid-sized Canadian cities by using astandardized method for analyzing data from six cities with different climates: Halifax-Dartmouth,Ottawa, Québec, Hamilton, Waterloo Region, and Regina. The study has four interrelated objectives: (1) Toconduct a sensitivity analysis to determine the extent to which risk estimates vary depending onthe criteria used to define precipitation events and `normal' conditions; (2) To compare therelative risk of collision and injury during precipitation relative to `normal' conditions; (3) Todetermine the extent to which weather-related risks vary fordifferent Canadian cities; and (4) To explore any differences in collision characteristics between events and controls, especially as theyvary from city to city. Results are based on a matched-pair analysis, using six-hour time blocks over afour-year period, 1995 to 1998. Results indicate only modest sensitivity to the criteria used to define precipitation events and `normal' conditions. On average, precipitation is associated with a 75 percentincrease in traffic collisions and a 45 percent increase in related injuries, as compared to `normal'seasonal conditions, but risk levels vary depending on the characteristics of the weather event.Both sensitivity to specific weather conditions and weather-related accident profiles vary from city tocity in ways that are not easily explained.     

Fluxes of Sr into the headwaters of the Ganges

Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, ⁸⁷Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated ⁸⁷Sr/⁸⁶Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the ⁸⁷Sr flux in excess of the seawater ⁸⁷Sr/⁸⁶Sr ratio of 0.709.     

Intercomparison of Stratospheric Chemistry Models under Polar Vortex Conditions

Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.     

Meso-gamma scale forecasts using the nonhydrostatic model LM

Summary ?The nonhydrostatic model LM was developed for small scale operational predictions. Advances in computer development will give the possibility of operational models of a rather fine scale, which will cover the meso-gamma scale. The LM is currently applied at a scale of 7 km and an increase of the operational resolution to 2.5 km is planned for the next few years. Predictions of such high resolution require to abandon the hydrostatic assumption, which is used with most current operational weather prediction models. The LM was designed to cover all resolutions from 50 m to 50 km with an efficiency making it suitable for operational use. It is a fully elastic model, using second order centred finite differences. The time integration is done using the Klemp–Wilhelmson method, treating the slow modes by a larger time step than the fast modes. The vertical propagation of the fast waves is done implicitly. After describing the design of the LM, this paper gives examples of model predictions at the meso-γ scale. Some results of the current operational application at the resolution 7 km are presented. Deficiencies in the localisation of model generated precipitation are investigated using an idealised bell shaped mountain and applying different resolutions. In this way the convergence to the correct solution can be investigated. From these results it is concluded, that orographic filtering is necessary and the effect of such filtering on precipitation forecasts is investigated. Finally, the prediction of a squall line over northern Germany is shown in order to demonstrate the potential of the model in forecasting the meso-γ scale. Received May 15, 2001; revised September 21, 2001