Displaced-Beam Small Aperture Scintillometer Test. Part I: The Wintex Data-Set

The friction velocity (u_*) and the sensible heat flux density (H) determined with a displaced-beam small aperture scintillometer (DBSAS) and a hot-film eddy correlation system are compared. Random errors in the DBSAS are relatively small, compared to scatter found with two eddy-correlation systems. Assuming that the hot-film system yields the true fluxes, theDBSAS appears to overestimate u_* when u_* is less than 0.2 m s^-1 and to underestimate u_* at high wind speeds. This implies that the DBSAS measurements of theinner scale length of turbulence, l₀, a direct measure for the dissipation rate of kinetic turbulent energy, are biased. Possible causes for these results are discussedin detail. A correction procedure is presented to account for effects of random noise and of so-called inactive turbulence or sensor vibrations. The errors in u_* cause errors in the DBSAS measurements of the structure parameter of temperature C_T ². The derived H appears to be less sensitive to errors in l₀ and C_T ², because errors in these quantities tend to cancel out.     

Comparison of UV and IR Laser Ablation ICP-MS on Silicate Reference Materials and Implementation of Normalisation Factors for Quantitative Measurements

Direct analysis of geological reference materials was performed by LA-ICP-MS using two Nd:YAG laser systems operating at 266 nm and 1064 nm. The aim of this work was to compare UV and IR laser ablation and to assess the potential of the technique for the quantitative bulk analysis of rocks, sediments and soils. The laser sampling process was investigated and the analytical performance of both systems was compared. The influence of the laser operating conditions and the nature of the matrix on ICP-MS response factors calculated for major, minor and trace elements was evaluated. Under consistent laser settings, the response factors appeared to be matrix dependent. For a given matrix, the response factors were also significantly different for the two lasers. Normalisation with a single matrix element was effective only for matrices with similar mineralogy. When operating at 266 nm instead of 1064 nm, matrix effects could be reduced but not overcome. However, variations of the response factors between the different matrices appeared to be similar within distinct groups of elements, reflecting geochemical associations. When using multiple internal standards, matrix effects but also effects of the laser wavelength, could be fully compensated.     

Biological record of added manganese in seawater: a new efficient tool to mark in vivo growth lines in the oyster species Crassostrea gigas

The biological response of increased manganese in seawater was tested experimentally with the oyster species Crassostrea gigas by adding, once per day, a fixed quantity of MnCl₂ to the container where the oysters were living. Uptake of Mn²⁺ in the shell was traced with cathodoluminescence and quantified with a high spatial resolution proton microprobe. The daily addition of MnCl₂ resulted in the visualization of distinct growth increments seen simultaneously in both the calcitic shell and the aragonitic ligament. A relation was observed between the addition of Mn²⁺ to the seawater and incorporation of Mn in the mineral part of the shell. Thus, addition of MnCl₂ to seawater is an efficient tool to mark in vivo growth increments in bio-mineralised carbonates.     

The challenges of monitoring national climate policy: learning lessons from the EU

One of the most central and novel features of the new climate governance architecture emerging from the 2015 Paris Agreement is the transparency framework committing countries to provide, inter alia, regular progress reports on national pledges to address climate change. Many countries will rely on public policies to turn their pledges into action. This article focuses on the EU’s experience with monitoring national climate policies in order to understand the challenges that are likely to arise as the Paris Agreement is implemented around the world. To do so, the research employs – for the first time – comparative empirical data submitted by states to the EU’s monitoring system. Our findings reveal how the EU’s predominantly technical interpretation of four international reporting quality criteria – an approach borrowed from reporting on GHG fluxes – has constrained knowledge production and stymied debate on the performance of individual climate policies. Key obstacles to more in-depth reporting include not only political concerns over reporting burdens and costs, but also struggles over who determines the nature of climate policy monitoring, the perceived usefulness of reporting information, and the political control that policy knowledge inevitably generates. Given the post-Paris drive to achieve greater transparency, the EU’s experience offers a sobering reminder of the political and technical challenges associated with climate policy monitoring, challenges that are likely to bedevil the Paris Agreement for decades to come.

Policy relevance

The 2009 Copenhagen summit ushered in a more bottom-up system of international climate governance. Such systems typically depend on strong monitoring approaches to assess past performance and estimate future national contributions over time. This article shows why decision makers at multiple governance levels should pay serious attention to empirical data on the experiences and challenges that have emerged around monitoring in the EU, a self-proclaimed climate leader. The analysis highlights key political and administrative challenges that policy makers will likely encounter in implementing climate policy monitoring and ensuring transparency in the spirit of the Paris Agreement.     

Combining airborne laser scanning and Landsat data for statistical modeling of soil carbon and tree biomass in Tanzanian Miombo woodlands

Background

Soil carbon and biomass depletion can be used to identify and quantify degraded soils, and by using remote sensing, there is potential to map soil conditions over large areas. Landsat 8 Operational Land Imager satellite data and airborne laser scanning data were evaluated separately and in combination for modeling soil organic carbon, above ground tree biomass and below ground tree biomass. The test site is situated in the Liwale district in southeastern Tanzania and is dominated by Miombo woodlands. Tree data from 15 m radius field-surveyed plots and samples of soil carbon down to a depth of 30 cm were used as reference data for tree biomass and soil carbon estimations.

Results

Cross-validated plot level error (RMSE) for predicting soil organic carbon was 28% using only Landsat 8, 26% using laser only, and 23% for the combination of the two. The plot level error for above ground tree biomass was 66% when using only Landsat 8, 50% for laser and 49% for the combination of Landsat 8 and laser data. Results for below ground tree biomass were similar to above ground biomass. Additionally it was found that an early dry season satellite image was preferable for modelling biomass while images from later in the dry season were better for modelling soil carbon.

Conclusion

The results show that laser data is superior to Landsat 8 when predicting both soil carbon and biomass above and below ground in landscapes dominated by Miombo woodlands. Furthermore, the combination of laser data and Landsat data were marginally better than using laser data only.

     

Application of a mass-balance model to predict PCDD/F turnover in a Baltic coastal estuary

A dynamical, process-based mass-balance model was applied to quantify the transports of polychlorinated-p-dibenzodioxins and dibenzofurans (PCDD/Fs) to, within and from the Kallrigafjärden Bay, a coastal estuary in the Baltic Sea, and to predict the PCDD/F levels in the water and sediments of the bay. Before the modelling, a one-year sampling programme was implemented in 2007–2008 to measure the flows of PCDD/Fs in tributaries entering the system, the fluxes from the adjacent sea and the levels in water, sediment and fish within the estuary. The collected data set was used as input data to the model and for validation purposes.     

内蒙古大庙中新世哺乳动物群序列与环境变化

中新世是现代地理、生态、气候格局等形成的关键时期,是研究陆生哺乳动物演化与环境变化关系的理想时段.通过对内蒙古四子王旗大庙发现的中新世哺乳动物化石的研究,试图揭示同一区域哺乳动物群落演变过程、生态类型的变化及其与环境变化的关系.结果表明大庙共产出了3个时段的动物群,分别为早中新世谢家期、中中新世通古尔期以及晚中新世灞河...     

Development of oil formation theories and their importance for peak oil

This paper reviews the historical development of both biogenic and non-biogenic petroleum formation. It also examines the recent claim that the so-called “abiotic” oil formation theory undermines the concept of “peak oil,” i.e. the notion that world oil production is destined to reach a maximum that will be followed by an irreversible decline. We show that peak oil is first and foremost a matter of production flows. Consequently, the mechanism of oil formation does not strongly affect depletion. We would need to revise the theory beyond peak oil only for the extreme — and unlikely — hypothesis of abiotic petroleum formation.     

Impact of recycling and lateral sediment input on grain size fining trends—Implications for reconstructing tectonic and climate forcings in ancient sedimentary systems

Grain size trends in basin stratigraphy are thought to preserve a rich record of the climatic and tectonic controls on landscape evolution. Stratigraphic models assume that over geological timescales, the downstream profile of sediment deposition is in dynamic equilibrium with the spatial distribution of tectonic subsidence in the basin, sea level and the flux and calibre of sediment supplied from mountain catchments. Here, we demonstrate that this approach in modelling stratigraphic responses to environmental change is missing a key ingredient: the dynamic geomorphology of the sediment routing system. For three large alluvial fans in the Iglesia basin, Argentine Andes we measured the grain size of modern river sediment from fan apex to toe and characterise the spatial distribution of differential subsidence for each fan by constructing a 3D model of basin stratigraphy from seismic data. We find, using a self‐similar grain size fining model, that the profile of grain size fining on all three fans cannot be reproduced given the subsidence profile measured and for any sediment supply scenario. However, by adapting the self‐similar model, we demonstrate that the grain size trends on each fan can be effectively reproduced when sediment is not only sourced from a single catchment at the apex of the system, but also laterally, from tributary catchments and through fan surface recycling. Without constraint on the dynamic geomorphology of these large alluvial systems, signals of tectonic and climate forcing in grain size data are masked and would be indecipherable in the geological record. This has significant implications for our ability to make sensitive, quantitative reconstructions of external boundary conditions from the sedimentary record.