Extending the Application of a Shale Volume Estimation Formula Derived from Factor Analysis of Wireline Logging Data

A multivariate statistical procedure is developed for the estimation of shale volume in clastic sedimentary formations. The method offers an alternative for extracting the shale content from borehole geophysical measurements. Factor analysis of various well-logging data types generates a new well log that correlates with the shale content of shaly-sandy rocks. The mathematical relationship between shale volume and factor scores is represented by a nonlinear equation, which seems to be applicable for data sets originating from different sedimentary basins. A comparative study is made between three different data sets originating from Hungary and the United States of America in order to check the validity of the proposed empirical formula. Shale volumes predicted from factor analysis are confirmed by estimates from independent deterministic and inverse modeling. Petrophysical information derived by factor analysis of logs recorded in deep wells can be used for a more accurate and reliable estimation of effective porosity and absolute permeability of reservoir rocks, for decreasing the estimation error of inversion estimates and for reducing the ambiguity in the solution of the well-logging inverse problem.     

Cathodoluminescence microscopy and spectroscopy of forsterite from Kaba meteorite: An application to the study of hydrothermal alteration of parent body

Highly forsteritic olivine (Fo: 99.2–99.7) in the Kaba meteorite emits bright cathodoluminescence (CL). CL spectra of red luminescent forsterite grains have two broad emission bands at approximately 630 nm (impurity center of divalent Mn ions) in the red region and above 700 nm (trivalent Cr ions) in the red–IR region. The cores of the grains show CL blue luminescence giving a characteristic broad band emission at 400 nm, also associated with minor red emissions related to Mn and Cr ions. CL color variation of Kaba forsterite is attributed to structural defects. Electron probe microanalyzer (EPMA) analysis shows concentrations of Ca, Al, and Ti in the center of the forsterite grain. The migration of diffusible ions of Mn, Cr, and Fe to the rim of the Kaba meteoritic forsterite was controlled by the hydrothermal alteration at relatively low temperature (estimated at about 250 °C), while Ca and Al ions might still lie in the core. A very unusual phase of FeO (wüstite) was also observed, which may be a terrestrial alteration product of FeNi‐metal.     

Responses of diatoms to the Younger Dryas climatic reversal in a South Carpathian mountain lake (Romania)

A high-resolution paleolimnological study from Lake Brazi, a small mountain lake in the Southern Carpathian Mountains, Romania, shows distinct diatom responses to late glacial and early Holocene climate change between ca. 15,750 and 10,000?cal?year BP. Loss-on-ignition, titanium, sulphur, phosphorus, biogenic silica content, and diatom assemblage composition were used as proxies for past environmental changes. Total epilimnetic phosphorus (TP) concentrations and lakewater pH were reconstructed quantitatively using diatom-TP and pH transfer functions. The most remarkable changes in the aquatic ecosystem were found at ca. 12,870 and 10,400?cal?year BP. Whereas the onset of the Younger Dryas (YD) climatic reversal was conspicuous in our record, the beginning of the Holocene was not well marked. Two diatom assemblage zones characterize the YD in Lake Brazi, suggesting a bipartite division of this climatic oscillation. The diatom responses to the YD cooling were (1) a shift from Staurosira venter to Stauroforma exiguiformis dominance; (2) a decrease in overall diatom diversity; (3) a decrease in lake productivity, inferred from DI-TP, organic matter, and biogenic silica content; and (4) a lowering of the DI-pH. Compositional change of the diatom assemblages suggested a sudden shift towards more acidic lake conditions at 12,870?cal?year BP, which is interpreted as a response to prolonged ice cover and thus shorter growing seasons and/or enhanced outwash of humic acids from the catchment. Taking into account the chironomid-based inference of only moderate July mean temperature decrease (<1?°C), together with the pollen-inferred regional opening of the forest cover and expansion of steppe-tundra, our data suggest that ecosystem changes in the Southern Carpathians during the YD were likely determined by strong seasonal changes.     

Indoor radon mapping and its relation to geology in Hungary

Indoor radon mapping may show stronger dependence on geological formations if the measured homes are one-storied houses with no basement. In Hungary, 17,244 homes were investigated on the yearly average of indoor radon concentrations; among these homes, there were 6,154, one-storied, no-basement houses. In Hungary, 21 geological units were created relevant for indoor radon index characterized by lithology, the position of the ground water table, and the gas permeability. Maps were drawn of different topography (counties, grid, geological units) and different values (maximum, mean, indoor radon indexes). A kind of standardization of houses was that only the one-storied, no-basement ones were chosen, but from geological point of view some more information was gained when the wall materials (bricks or adobe) were also taken into account. (“Adobe” is made of clay and straw in Hungary, and not burned as brick, just dried on sunshine). Enhanced indoor radon values can be observed on the bedrock of Cenozoic volcanic rocks and their eroded materials deposited on the local alluvial valleys. Another group with relatively increased indoor radon values can be connected to granite bodies. The grid method is useful for covering large state or even continental areas. For practical public use and detailed radon risk mapping geological or administrative unit-systems could yield more reasonable and useful results.     

Estimation of the dispersion of an accidental release of radionuclides and toxic materials based on weather type classification

We investigate the influence of the regional-scale weather types on the atmospheric dispersion processes of the air pollutants originated from point sources. Hypothetical accidents were simulated with two different dispersion models. During a year’s test period, the 6-h emission of a radionuclide from the Paks Nuclear Power Plant (Paks NPP, Hungary) was assumed every day and the transport and deposition of the radionuclide was simulated by the Eulerian TREX dispersion model over the Central European region. In addition, the ALOHA Gaussian air dispersion model was also used for the local environment of the Paks NPP to simulate hypothetical hourly releases of ammonia during a 10-year period. During both types of model simulations, the dispersion of the plume for each time was analysed and tested with consideration of 13 circulation types corresponding to daily weather patterns over the Carpathian Basin. There are significant correlations between circulation types and plume directions and structures both in local and regional scales. The daily circulation pattern can be easily obtained from weather analyses; the expected size and direction of polluted area after an accidental release can be quickly estimated even before an accident occurs. However, this fast method cannot replace or neglect dispersion model simulations. It gives a ‘first guess’ and a fast estimation on the direction of the plume and can provide sufficient information for decision-making strategies.     

The effect of surface topography on the lunar photoelectron sheath and electrostatic dust transport

The dayside near-surface lunar plasma environment is electrostatically complex, due to the interaction between solar UV-induced photoemission, the collection of ambient ions and electrons, and the presence of micron and sub-micron sized dust grains. Further complicating this environment, although less well understood in effect, is the presence of surface relief, typically in the form of craters and/or boulders. It has been suggested that such non-trivial surface topography can lead to complex electrostatic potentials and fields, including “mini-wakes” behind small obstacles to the solar wind flow and “supercharging” near sunlit-shadowed boundaries (Criswell, D.R., De, B.R. [1977]. J. Geophys. Res. 82 (7); De, B.R., Criswell, D.R. [1977]. J. Geophys. Res. 82 (7); Farrell, W.M., Stubbs, T.J., Vondrak, R.R., Delory, G.T., Halekas, J.S. [2007]. Geophys. Res. Lett. 34; Wang, X., Horányi, M., Sternovsky, Z., Robertson, S., Morfill, G.E. [2007]. Geophys. Res. Lett. 34, L16104). In this paper, we present results from a three-dimensional, self-consistent, electrostatic particle-in-cell code used to model the dayside near-surface lunar plasma environment over a variety of local times with the presence of a crater. Additionally, we use the particle-in-cell model output to study the effect of surface topography on the dynamics of electrostatic dust transport, with the goal of understanding previous observations of dust dynamics on the Moon and dust ponding on various asteroids.     

Fingerprinting the Late Pleistocene tephras of Ciomadul volcano,eastern–central Europe

Late Pleistocene tephras derived by large explosive volcanic eruptions are widespread in the Mediterranean and surrounding areas. They are important isochronous markers in stratigraphic sections and therefore it is important to constrain their sources. We report here tephrochronology results using multiple criteria to characterize the volcanic products of the Late Pleistocene Ciomadul volcano in eastern–central Europe. This dacitic volcano had an explosive eruption stage between 57 and 30 ka. The specific petrological character (ash texture, occurrence of plagioclase and amphibole phenocrysts and their compositions), the high-K calc-alkaline major element composition and particularly the distinct trace element characteristics provide a strong fingerprint of the Ciomadul volcano. This can be used for correlating tephra and cryptotephra occurrences within this timeframe. Remarkably, during this period several volcanic eruptions produced tephras with similar glass major element composition. However, they differ from Ciomadul tephras by glass trace element abundances, ratios of strongly incompatible trace elements and their mineral cargo that serve as discrimination tools. We used (U-Th)/He zircon dates combined with U-Th in situ rim dates along with luminescence and radiocarbon dating to constrain the age of the explosive eruptions of Ciomadul that yielded distal tephra layers but lack of identified proximal deposits.     

Series Expansion-Based Genetic Inversion of Wireline Logging Data

An evolutionary approach is applied to solve the nonlinear well logging inverse problem. In the framework of the proposed interval inversion method, nuclear, sonic, and laterolog resistivity data measured at an arbitrary depth interval are jointly inverted, where the depth variation of porosity, water saturation, and shale volume is expanded into series using Legendre polynomials as basis functions. In the interval inversion procedure, the series expansion coefficients are estimated by using an adaptive float-encoded genetic algorithm. Since the solution of the inverse problem using traditional linear optimization tools highly depends on the selection of the initial model, a heuristic search is necessary to reduce the initial model dependence of the interval inversion procedure. The genetic inversion strategy used in interval inversion seeks the global extreme of the objective function and provides an estimate of the vertical distribution of petrophysical parameters, even starting the inversion procedure from extremely high distances from the optimum. For a faster computational process, after a couple of thousand generations, the genetic algorithm is replaced by some linear optimization steps. The added advantage of using the Marquardt algorithm is the possibility to characterize the accuracy of the series expansion coefficients and derived petrophysical properties. A Hungarian oil field example demonstrates the feasibility and stability of the improved interval inversion method. As a significance, the genetic inversion method does not require prior knowledge or strong restrictions on the values of petrophysical properties and gives highly reliable estimation results practically independent of the initial model and core information.