Research progress of TiO2 photocathodic protection to metals in marine environment

Corrosion protection has become an important issue as the amount of infrastructure construction in marine environment increased.Photocathodic protection is a promising method to reduce the corrosion of metals,and titanium dioxide(TiO_2) is the most widely used photoanode.This review summarizes the progress in TiO_2 photo gene rated protection in recent years.Different types of semiconductors,including sulfides,metals,metal oxide s,polymers,and other materials,are used to design and modify TiO_2.The strategy to dramatically improve the efficiency of photoactivity is proposed,and the mechanism is investigated in detail.Characterization methods are also introduced,including morphology testing,light absorption,photoelectrochemistry,and protected metal observation.This review aims to provide a comprehensive overview of Ti02 development and guide photocathodic protection.     

Provenance and Tectonic Implications of Paleozoic Strata in the South Yellow Sea Basin,China–Revealed from the Borehole CSDP-2

Well CSDP-2 is a fully coring deep drilling hole, penetrating the thick Paleozoic marine strata in the South Yellow Sea Basin(SYSB) in the lower Yangtze Block(LYB). Based on the petrological and geochemical analysis of 40 sandstone samples from the core CSDP-2, the provenance and tectonic features of Paleozoic detrital rocks from SYSB are analyzed and systematically delineated in this article. The results show that the Silurian – Carboniferous sandstones are mature sublitharenite, while the Permian sandstones are unstable feldspathic litharenite. The average CIA(chemical index of alteration) is 74.61, which reflects these sediments were derived from source rocks with moderate chemical weathering. The REE(rare earth element) patterns are characterized by LREE enrichment, flat HREE and obviously negative Eu anomaly, which are similar to that of the upper continental crust. Dickinson QFL discrimination results indicate the recycled orogeny provenance. Various diagrams for the discrimination of sedimentary provenance based on major and trace element data show all the sediments were derived predominantly from quartz sedimentary rocks, of which the Permian strata contain more felsic sedimentary rocks. Geochemical data for these detrital rocks suggest they occur at the passive continental margin and island arc settings, and the Permian sandstone presents active continental margin setting.     

基于统计动力反演的东亚亚热带季风变化驱动机制研究

利用观测数据,运用非线性统计-动力学方法,反演系统各因子之间的相互关系,建立了东亚亚热带季风变化的动力方程,为研究东亚亚热带季风的驱动机制提供了量化参考。研究发现：过去2 000 a东亚亚热带季风是多因子通过反馈机制相互作用影响且具有耦合效应的复杂非线性动力系统,其驱动力主要来源于普若岗日冰芯δ¹⁸О代表的青藏高原热力作用强迫、太阳黑子活动、ENSO、温室气体单因子CO₂和CH₄浓度、北极温度和CH₄及北极温度与7月太阳辐射的耦合作用机制;反馈调节作用主要源于7月太阳辐射与太阳黑子活动、CH₄浓度、中国陆地地表温、CH₄与7月太阳辐射以及CO₂和CH₄的耦合调节作用。并通过动力反演机制推论热带西太平洋对亚热带季风有一定驱动作用,但并不是主要驱动力,即驱动亚热带季风变化的主源地并不在热带西太平洋海区,石笋δ¹⁸О指代的也主要是夏季风信息。     

城市土地集约利用与生态利用灰色关联分析

采用灰色关联分析的方法分析我国内陆31个省会城市的土地集约利用与土地生态利用之间的关系,为城市土地集约与生态协同利用提供依据和支撑。结果表明:综合容积率,单位土地面积职工数,路网密度,人均城市建设用地,地均二、三产值,地均固定资产投入等,均与土地生态利用综合水平之间存在着密切关系,但密切程度不同;与31个省会城市相比,东中西部3个区域的城市土地集约与生态利用关联程度呈现出不同的特点。     

温室气体强迫与东亚亚热带季风演变耦合效应及动力机制研究

基于主要温室气体（CO₂、CH₄和N₂O）强迫因子和石笋δ¹⁸О观测资料（1~2002 年）,分别利用关联性耦合模型和非线性统计-动力学方法,分析温室气体强迫与东亚亚热带季风演变耦合度的时序规律和定量反演模拟温室气体强迫对近2 000 a东亚亚热带季风演变影响的非线性趋势和相对贡献。研究发现：① 温室气体与季风演变耦合度的高低对应季风的强弱变化,即两者耦合作用越强,东亚亚热带季风越强;反之,两者耦合强度越小,东亚亚热带季风越弱;耦合度峰谷值对应季风极强降水和极端干旱时段。② 时序演变规律为：N₂O和CO₂相互作用与季风演变间耦合效应最强,成为东亚亚热带季风演变的主要驱动力。其次,N₂O一次项和CO₂非线性项对季风演变起主要的负反馈调节机制。③ 时序演变阶段上有所不同：1~180年,CH₄因子对季风演变主要起负反馈调节机制;180~1760年和1760~2002年,对季风演变起主要的驱动和调节机制分别为CO₂因子和N₂O因子;但1900年后N₂O和CO₂相互作用与季风演变的耦合驱动效应近百年来明显增强,耦合度在中等-较强（或极强）之间来回波动转换,耦合作用明显增强,在耦合度由较强（或极强）转弱至中等时,东亚亚热带季风也随之减弱。     

海洋产业影响省域经济增长估计及其分异动因判识

采用静态和动态计量方法分析2006~2015年海洋经济对沿海省（市、区）经济发展的影响程度并通过空间计量方法识别差异动因。研究发现：① 海洋经济对中国省域经济发展具有显著地影响,其中天津、上海、福建、山东、广东、海南海洋经济总量贡献率高于全国平均水平;② 省域海洋产业对区域经济影响度分异呈现省际绝对差异不断扩大、相对差异不断缩小,且具有显著的空间相关性;③ 引起省域经济增长差异的海洋经济相关因素中,海洋第二产业、海洋进出口贸易额等起到正向促进作用（即拉大差异）,且海洋第二产业结构具有显著的溢出效应。相关发现有助于中国沿海省（市、区）经济的协调发展和科学决策。     

鲁西北连续两次强降水过程对比分析

利用各种观测资料和NCEP/NCAR 1×1°再分析资料,对2012年7月30日夜间和31日夜间鲁西北连续两天强降雨天气进行诊断和对比分析。结果表明:强降水产生在西风槽前和副热带高压边缘的偏南暖湿气流中,西风槽稳定少动,台风在东南沿海北上,副高加强北抬,为鲁西北连续两天的强降水提供了天气尺度背景。925hPa及以下的低层,来自于渤海的偏东气流和来自于华东沿海的东南气流同时向鲁西北强降水区输送水汽,低层比湿大,CAPE和K指数较高。第1次强降水产生在偏南气流的暖区中,降水强度大,维持时间短。第2次强降水期间,低层有冷空气锲入,把暖湿气流抬升,前期为对流性降水,中后期转为稳定性降水,降水强度小,维持时间较长。850hPa及以下倒槽式切变线和中尺度低涡环流是造成强降水的中尺度影响系统,近地面层来自于渤海的东北气流与来自于东南沿海的东南暖湿气流形成中尺度涡旋,产生气旋式辐合上升,触发对流不稳定能量释放。对流云团在鲁西北形成长形的中尺度对流系统(MCS),稳定少动,有明显的列车效应和后向传播特征。强降水具有较强的日变化,夜间发展增强,白天减弱。     

Evaluation of the 2.5-km Cloud-Resolving Storm Simulator in Predicting Local Afternoon Convection during the Summer in Taiwan

The forecast of summertime afternoon convection by numerical weather prediction models is highly challenging because of its weak dynamical forcing, small scale, and low predictability. To assess such an ability for future improvement, we evaluated the performance of the 2.5-km Cloud-Resolving Storm Simulator (CReSS) in predicting afternoon convection in Taiwan under weak synoptic conditions during the summers (May–October) of 2011 and 2012. For a total of 89 target days, daily CReSS forecasts in three ranges, starting at 0000 UTC (0800 LST) on the same day (D0), the day before (D-1), and 2 days before (D-2), were examined. With regard to the occurrence of afternoon convection anywhere in Taiwan, the predictive skill of the model was considerably high, as evidenced by the threat score (TS) and post-agreement (PA) of D0 (D-1) forecasts reaching 0.75 and 0.90 (0.50 and 0.79), respectively. While the score values decrease when Taiwan is divided into four regions (i.e., the forecast must be in the correct region to be considered a hit), the TS and PA for D0 (D-2) forecasts remain respectable at 0.44 and 0.73 (0.29 and 0.59). Among the four regions, the TS (0.48–0.65) and PA (0.77–0.83) for Central Taiwan are the highest with the best predictive skill. Overall, while the prediction of afternoon convection in the correct region is challenging, the 2.5-km CReSS model has considerable skill (TS ~ 0.30) even 2 days in advance, and can provide useful guidance for afternoon convection in Taiwan.     

负压对四肢瘢痕切除创面成纤维细胞的生长环境影响

目的 探究持续封闭负压引流技术（VSD）对瘢痕切除创面成纤维细胞生长环境的影响。方法 回顾性分析2014年1月~2015年11月于笔者医院行植皮手术的四肢瘢痕切除术后患者60例,根据植皮手术前是否接受VSD治疗分为负压组（n=30）和包扎组（n=30）,负压组均于一期植皮前接受VSD治疗,包扎组未接受VSD治疗。回顾性分析对比两组患者并发症发生率、首次植皮存活率、创面感染率、住院时间之间的差异。并用TUNEL染色、CD34染色法对比瘢痕标本中成纤维细胞凋亡指数及血管生成情况。结果 负压组菌培养阳性率明显低于包扎组（P<0.05）,植皮存活率明显高于包扎组（P<0.05）。两组并发症发生率、住院时间、疼痛评分、随访VSS评分间比较,负压组均明显较低（P<0.05）。负压组成纤维细胞凋亡指数明显较低,微血管计数明显较高（P<0.05）。结论 负压封闭引流可以减轻瘢痕切除创面感染率,有效减轻炎性水肿,且可以通过改变局部血液循环微环境以及机械应力作用促进成纤维细胞增殖分裂,提高创面恢复效果。