Application of multivariate statistical methods to indicate the origin and geochemical behavior of potentially hazardous elements in sediment around the Sarcheshmeh copper mine,SE Iran

Multivariate statistical techniques, i.e., correlation coefficient analysis, principal components analysis (PCA), and hierarchical cluster analysis (CA), were applied to the total and water-soluble concentrations of potentially hazardous metals in sediments associated with the Sarcheshmeh mine, one of the largest Oligo-Miocene porphyry copper deposits in the world. The samples were analyzed for hazardous metal concentration levels by inductively coupled plasma mass spectrometry method. Results indicate that the contaminant metals As, Cd, Cu, Mo, S, Sb, Sn, Se, Pb, and Zn were positively correlated with the total concentrations. These hazardous metals also have strong association in the PCA and CA results. Different anthropic versus natural sources of contaminant metals were distinguished by using CA method. Water-soluble fraction of hazardous metals showed that the hydro-geochemical behavior of these metals in sediments is different considerably. Elements such as Cd, Co, Cr, Cu, Fe, Mn, Ni, S, and Zn are readily water soluble from contaminated samples, especially from evaporative mineral phases, while the release of As, Mo, Sb, and Pb into the water is limited by adsorption processes. Results obtained from the application of multivariate techniques on the water-soluble fraction data set show that the hazardous metals are categorized into three groups including (1) Ni, S, Co, Cu, Cr, and Fe; (2) Se, Mn, Cd, and Zn; and (3) Sb, As, Mo, and Sn. This classification describes the hydro-geochemical behavior of hazardous metals in water–sediment environments of the Sarcheshmeh porphyry copper mine and can be used as a basis in remedial and treatment strategies.     

Damage Estimation in Masonry Buildings Based on Excavation-Induced Ground Movements

Excavation-induced ground movements and the resulting damages to adjacent structures and facilities is a source of concern for excavation projects in urban areas. The concern will be even higher if the adjacent structure is old or has low strength parameters like masonry building. Frame distortion and crack generation are predictors of building damage resulted from excavation-induced ground movements, which pose challenges to projects involving excavations. This study is aimed to investigate the relation between excavation-induced ground movements and damage probability of buildings in excavation affected distance. The main focus of this paper is on masonry buildings and excavations stabilized using soil nail wall method. To achieve this purpose, 21 masonry buildings adjacent to 12 excavation projects were studied. Parametric studies were performed by developing 3D FE models of brick walls and excavations stabilized using soil nail wall. Finally, probability evaluations were conducted to analyze the outputs obtained from case studies. Based on the obtained results, simple charts were established to estimate the damage of masonry structures in excavation affected distance with two key parameters including “Displacement Ratio” and “Normalized Distance”. The results also highlight the effects of building distance from excavation wall on its damage probability.

     

Time-frequency decomposition of seismic signals via quantum swarm evolutionary matching pursuit

Matching pursuit belongs to the category of spectral decomposition approaches that use a pre-defined discrete wavelet dictionary in order to decompose a signal adaptively. Although disengaged from windowing issues, matching point demands high computational costs as extraction of all local structure of signal requires a large size dictionary. Thus in order to find the best match wavelet, it is required to search the whole space. To reduce the computational cost of greedy matching pursuit, two artificial intelligence methods, (1) quantum inspired evolutionary algorithm and (2) particle swarm optimization, are introduced for two successive steps: (a) initial estimation and (b) optimization of wavelet parameters. We call this algorithm quantum swarm evolutionary matching pursuit. Quantum swarm evolutionary matching pursuit starts with a small colony of population at which each individual, is potentially a transformed form of a time-frequency atom. To attain maximum pursuit of the potential candidate wavelets with the residual, the colony members are adjusted in an evolutionary way. In addition, the quantum computing concepts such as quantum bit, quantum gate, and superposition of states are introduced into the method. The algorithm parameters such as social and cognitive learning factors, population size and global migration period are optimized using seismic signals. In applying matching pursuit to geophysical data, typically complex trace attributes are used for initial estimation of wavelet parameters, however, in this study it was shown that using complex trace attributes are sensitive to noisy data and would have lower rate of convergence. The algorithm performance over noisy signals, using non-orthogonal dictionaries are investigated and compared with other methods such as orthogonal matching pursuit. The results illustrate that quantum swarm evolutionary matching pursuit has the least sensitivity to noise and higher rate of convergence. Finally, the algorithm is applied to both modelled seismograms and real data for detection of low frequency anomalies to validate the findings.     

Chemical identification,antioxidant, cholinesterase inhibitory,and cytotoxic properties of fucoidan extracted from Persian Gulf Sargassum angustifolium

Marine macroalgal sulfated fucose-containing polysaccharides, like fucoidan, have drawn significant attention due to their biotechnological potentials, such as anti-cancer, antioxidant, and anti-cholinesterase activities. The fucoidan derived from brown macroalgae Sargassum angustifolium species (FSA) was investigated for its cytotoxic effects and alterations in cell proliferation, and cell cycle-related gene expression in the present study occurred on NB4 cell line. The results showed that FSA would induce p53, p21, pro-apoptotic genes and increase expression of the p15 gene as a cell arrest marker. Also, FSA inhibited the anti-apoptotic effect of the Bcl-2 gene and decreased dnmt-1 gene expression. FSA significantly exhibited potent 2, 2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activity (p<0.05) with an IC₅₀ value of 0.157 mg/mL and showed moderate anti-acetylcholinesterase activity with an IC₅₀ value of 1.20 μg/mL. These results indicated the potential of FSA for the development of therapeutic or preventive agents of cancer and Alzheimer’s disease mainly through cytotoxic effect and AChE (acetylcholinesterase) inhibition as well as additional antioxidant capacities.     

Salinisation de l’aquifère libre de la Chaouia côtière (Azemmour-Tnine Chtouka), Maroc

L’aquifère libre de la Chaouia côtière constitue un exemple des aquifères les plus exploités au Maroc. Ce travail est consacré à l’étude des processus de la salinisation des eaux souterraines par l’analyse physico-chimique de 39 puits répartis dans la zone. Deux types de faciès ont été révélés, l’un est chloruré-sodique dans la frange côtière ; l’autre faciès est de type chloruré bicarbonaté-calcique caractérisant les eaux exploitées dans les calcaires marneux du Crétacé. L’influence marine (aérosols et intrusion marine), la dissolution/précipitation de la roche aquifère et l’infiltration des eaux d’irrigation, sont parmi les causes de l’augmentation de la salinité des eaux souterraines, en plus de l’exploitation excessive de l’eau souterraine.     

Least-squares modification of extended Stokes’ formula and its second-order radial derivative for validation of satellite gravity gradiometry data

The gravity anomalies at sea level can be used to validate the satellite gravity gradiometry data. Validation of such a data is important prior to downward continuation because of amplification of the data errors through this process. In this paper the second-order radial derivative of the extended Stokes’ formula is employed and the emphasis is on least-squares modification of this formula to generate the second-order radial gradient at satellite level. Two methods in this respect are proposed: (a) modifying the second-order radial derivative of extended Stokes’ formula directly, and (b) modifying extended Stokes’ formula prior to taking the second-order radial derivative. Numerical studies show that the former method works well but the latter is very sensitive to the proper choice of the cap size of integration and degree of modification.     

Estimation from incomplete data files based on magnitude-frequency relation for earthquakes

The problem of incorporating the available seismological information provided by the major events of the historical catalog with those for the short period of instrumental data is investigated. Assuming that the frequency-magnitude law of Gutenberg and Richter is valid for both periods, an estimation procedure for the main parameter of this law and the rate of earthquake occurrence for historical period is presented. Application of the proposed method is demonstrated, using both real and simulated data. An extension to allow for variable quality of complete data with different magnitude values is also included.     

3D Elastic Solutions for Laterally Loaded Discs: Generalised Brazilian and Point Load Tests

This paper investigates the application of a double Fourier series technique to the construction of an elastic stress field in a cylindrical bar subject to lateral boundary loads. The lateral loads, including the constant load boundary conditions, are represented by two Fourier series: one on the perimeter of the circular section (r ₀, θ) and the other on the longitudinal curved surface parallel to the bar axis (z). The technique invokes acceptable potential functions of the Papkovich–Neuber displacement field, satisfying the governing partial differential equations, to assign appropriate odd and even trigonometric Fourier terms in cylindrical coordinates (r, θ, z). The generic solution decomposes the problem of interest to a state of stress caused by two independent boundary conditions along the z axis and θ-polar angle, both superimposed on a solution for which these potentials are the product of the trigonometric terms of the independent variables (θ, z). Constants appearing in the resultant second-order partial differential equations are determined from the generally mixed (tractions and/or displacements) boundary conditions. While the solutions are satisfied exactly at the ends of an infinite bar, they are satisfied weakly on average, in the light of Saint Venant’s approximation at the two ends of a finite bar. The application of the proposed analysis is verified against available elastic solutions for axisymmetric and non-axisymmetric engineering problems such as the indirect Brazilian Tensile Strength and Point Load Strength tests.     

Near-field probabilistic seismic hazard analysis with characteristic earthquake effects

In conventional seismic hazard analysis, uniform distribution over area and magnitude range is assumed for the evaluation of source seismicity which is not able to capture peculiar characteristic of near-fault ground motion well. For near-field hazard analysis, two important factors need to be considered: (1) rupture directivity effects and (2) occurrence of scenario characteristic ruptures in the nearby sources. This study proposed a simple framework to consider these two effects by modifying the predictions from the conventional ground motion model based on pulse occurrence probability and adjustment of the magnitude frequency distribution to account for the rupture characteristic of the fault. The results of proposed approach are compared with those of deterministic and probabilistic seismic hazard analyses. The results indicate that characteristic earthquake and directivity consideration both have significant effects on seismic hazard analysis estimates. The implemented approach leads to results close to deterministic seismic hazard analysis in the short period ranges (T < 1.0 s) and follows probabilistic seismic hazard analysis results in the long period ranges (T > 1.0 s). Finally, seismic hazard maps based on the proposed method could be developed and compared with other methods.     

Use of a trench adjacent to a shallow foundation as a mitigation measure for hazards associated with reverse faulting

Acta Geotechnica - Evidence from recent earthquakes reminds us that fault-induced permanent ground displacement has a devastating effect on structures in addition to damage caused by wave...