Northwest Africa 5790: A previously unsampled portion of the upper part of the nakhlite pile

We present a geochemical study of recently discovered Martian meteorite Northwest Africa (NWA) 5790 and use our results to constrain its origin and relationship with the other nakhlites. This nakhlite is a clinopyroxene cumulate composed of phenocrysts of augite, olivine, and rare oxides surrounded by a mesostasis composed of vitrophyric glass, feldspars, oxides, phosphates, and fine‐grained olivines and augite. Petrography, and major and trace element compositions of the phases present are consistent with derivation of NWA 5790 from a parental magma common to all the nakhlites. Olivine cores grew from a distinct, incompatible‐element enriched magma and are surrounded by rims containing augite inclusions that grew from the nakhlite parental liquid, supporting previous arguments for xenocrystic olivine cores in nakhlites. Rare earth element microdistributions suggest derivation of NWA 5790 augites from an evolved, relatively oxidized magma, produced by augite fractionation from the common nakhlite parental liquid. Augite grain shapes and CSD patterns are consistent with rapid cooling and derivation near the top of the nakhlite cumulate pile, but patterns are distinct from other nakhlites thought to have formed near the stratigraphic top. The high mesostasis abundance (~44 vol%) indicates solidification near the top of the nakhlite pile close to locations suggested for nakhlites NWA 817 and Miller Range (MIL) 03346. However, the geochemical and petrographic characteristics of these three samples do not permit their placement in a simple stratigraphic order as would occur in a single lava flow. This lack of simple ordering suggests that the nakhlite lava flow split into multiple sections as would occur during breakouts from a single lava flow. Finally we note that NWA 5790 is unique among currently available nakhlites in having phenocryst abundances low enough to allow it to flow.     

Swell-compressibility characteristics of lime-blended and cement-blended expansive clays – A comparative study

Chemical stabilisation of expansive soils has been quite efficacious in reducing swelling characteristics, namely, swell potential (S%) and swelling pressure (p_s). When chemicals such as lime and cement are added to an expansive clay, flocculation and cementation take place. Flocculation, which is an immediate reaction, is instrumental in reducing plasticity and swell potential significantly. It also reduces the time required for equilibrium heave. This paper presents experimental data on lime-blended and cement-blended expansive clay specimens. Free swell index (FSI), heave, rate of heave and swelling pressure were studied. FSI, heave and rate of heave decreased with increasing lime content and cement content in the blends. But, during a 3-day inundation (a period, generally allowed for the sample to attain to equilibrium heave), cementitious products developed and resisted the applied compressive loads stiffly, resulting in high swelling pressures in the case of lime-blended specimens. Swelling pressure could not be determined in the case of cement-blended specimens. Hence, short inundation tests (inundating the specimens only for 15 minutes) were performed. But, even from these tests, swelling pressure could not be determined for cement-blended specimens. This indicated the development of strong cementitious products in them. It was interesting to find that, in both long and short duration, the lime- and cement-blended specimens attained to equilibrium heave in the same time period. FSI decreased from 185% to 63.63% when lime content was increased from 0% to 4%, and from 185% to 110% when cement content was increased from 0% to 20%. Swell potential reduced by 42.5% at 4% lime and by 46.4% at 20% cement. Swelling pressure increased from 210 kPa to 320 kPa when lime content was increased from 0% to 4%. Linear shrinkage of the specimens also decreased with increasing additive content.     

Geochemistry and chronology of the Bunburra Rockhole ungrouped achondrite

Bunburra Rockhole is a unique basaltic achondrite that has many mineralogical and petrographic characteristics in common with the noncumulate eucrites, but differs in its oxygen isotope composition. Here, we report a study of the mineralogy, petrology, geochemistry, and chronology of Bunburra Rockhole to better understand the petrogenesis of this meteorite and compare it to the eucrites. The geochemistry of bulk samples and of pyroxene, plagioclase, and Ca‐phosphate in Bunburra Rockhole is similar to that of typical noncumulate eucrites. Chronological data for Bunburra Rockhole indicate early formation, followed by slow cooling and perhaps multiple subsequent heating events, which is also similar to some noncumulate eucrites. The ²⁶Al‐²⁶Mg extinct radionuclide chronometer was reset in Bunburra Rockhole after the complete decay of ²⁶Al, but a slight excess in the radiogenic ²⁶Mg in a bulk sample allows the determination of a model ²⁶Al‐²⁶Mg age that suggests formation of the parent melt for this meteorite from its source magma within the first ~3 Ma of the beginning of the solar system. The ²⁰⁷Pb‐²⁰⁶Pb absolute chronometer is also disturbed in Bunburra Rockhole minerals, but a whole‐rock isochron provides a re‐equilibration age of ~4.1 Ga, most likely caused by impact heating. The mineralogy, geochemistry, and chronology of Bunburra Rockhole demonstrate the similarities of this achondrite to the eucrites, and suggest that it formed from a parent melt with a composition similar to that for noncumulate eucrites and subsequently experienced a thermal history and evolution comparable to that of eucritic basalts. This implies the formation of multiple differentiated parent bodies in the early solar system that had nearly identical bulk elemental compositions and petrogenetic histories, but different oxygen isotope compositions inherited from the solar nebula.     

Magnesium isotopic fractionation in chondrules from the Murchison and Murray CM2 carbonaceous chondrites

We present high‐precision measurements of the Mg isotopic compositions of a suite of types I and II chondrules separated from the Murchison and Murray CM2 carbonaceous chondrites. These chondrules are olivine‐ and pyroxene‐rich and have low ²⁷Al/²⁴Mg ratios (0.012–0.316). The Mg isotopic compositions of Murray chondrules are on average lighter (δ²⁶Mg ranging from ?0.95‰ to ?0.15‰ relative to the DSM‐3 standard) than those of Murchison (δ²⁶Mg ranging from ?1.27‰ to +0.77‰). Taken together, the CM2 chondrules exhibit a narrower range of Mg isotopic compositions than those from CV and CB chondrites studied previously. The least‐altered CM2 chondrules are on average lighter (average δ²⁶Mg = ?0.39 ± 0.30‰, 2SE) than the moderately to heavily altered CM2 chondrules (average δ²⁶Mg = ?0.11 ± 0.21‰, 2SE). The compositions of CM2 chondrules are consistent with isotopic fractionation toward heavy Mg being associated with the formation of secondary silicate phases on the CM2 parent body, but were also probably affected by volatilization and recondensation processes involved in their original formation. The low‐Al CM2 chondrules analyzed here do not exhibit any mass‐independent variations in ²⁶Mg from the decay of ²⁶Al, with the exception of two chondrules that show only small variations just outside of the analytical error. In the case of the chondrule with the highest Al/Mg ratio (a type IAB chondrule from Murchison), the lack of resolvable ²⁶Mg excess suggests that it either formed >1 Ma after calcium‐aluminum‐rich inclusions, or that its Al‐Mg isotope systematics were reset by secondary alteration processes on the CM2 chondrite parent body after the decay of ²⁶Al.     

A Method to Represent a Well in a Three-Dimensional Discrete Fracture Network Model

In discrete fracture network (DFN) modeling, fractures are randomly generated and placed in the model domain. The rock matrix is considered impermeable. Small fractures and isolated fractures are often ignored to reduce computational expense. As a result, the rock matrix between fractures could be large and intersections may not be found between a well introduced in the model and the hydraulically connected fracture networks (fracture backbones). To overcome this issue, this study developed a method to conceptualize a well in a three-dimensional (3D) DFN using two orthogonal rectangular fractures oriented along the well's axis. Six parameters were introduced to parameterize the well screen and skin zone, and to control the connectivity between the well and the fracture backbones. The two orthogonal fractures were discretized using a high-resolution mesh to improve the quality of flow and transport simulations around and along the well. The method was successfully implemented within dfnWorks 2.0 (Hyman et al. 2015) to incorporate a well in a 3D DFN and to track particles leaving an injection well and migrating to a pumping well. Verification of the method against MODFLOW/MODPATH found a perfect match in simulated hydraulic head and particle tracking. Using three examples, the study showed that the method ensured the connectivity between wells and fracture backbones, and honored the physical processes of flow and transport along and around wells in DFNs. Recommendations are given for estimating the values of the six introduced well parameters in a real-world case study.     

Robertson-Walker cosmological models with perfect fluid in general relativity

Einstein's field equations with variable gravitational and cosmological constants are considered in the presence of perfect fluid for a Robertson-Walker universe by assuming the cosmological term to be proportional to R-m(R is a scale factor and m is a constant).A variety of solutions is presented.The physical significance of the cosmological models has also been discussed.     

Weak MHD discontinuities in a radiation-induced flow field

The growth of weak MHD discontinuities have been studied in a radiation induced flow field at very high temperature. Growth and decay properties of weak MHD discontinuities have been discussed under the influences of time-dependent gasdynamic field, the radiation field and the magnetic field with finite electrical conductivity. The effects of thermal radiation and conduction of the global behaviour of weak MHD discontinuities have been studied under a quasi-equilibrium and quasi-isotropic hypothesis of the differential approximation to the radiative heat transfer equation. It is shown that the existence of the time-dependent radiation field gives rise to a radiation induced wave which has a negligibly small effect on the non-relativistic flow properties of the gasdynamic field. It is also shown that the radiation stresses resist the steepening tendency of a compressive weak wave and help in stabilizing it whereas the thermal conduction effects counteracts to destabilize it. It is found that under radiation effects the shock formation is either disallowed or delayed. The two cases of diverging waves and converging waves have been studied separately to answer a particular question as to when a shock discontinuity or a coustic will be formed or disallowed under curvature effects.     

Probabilistic model for wave forces acting on a cylinder in random waves

Generally, the sea-state (random waves) is best described by a wave spectrum. A number of statistical models for wave spectra has been well established and a sea-state can be specified. Once the specified sea-state is established, the corresponding model for wave forces acting on a single cylinder or a group of cylinders can be formulated. Since peak force is of more practical value, a multivariate or joint probability density function for wave forces has been developed for the peak force distribution of wave forces. This theoretical force model derives the tri-variate probability density function P(F, F′, F″), where F is the peak force defined by Morison equation. This model is of wide-band in nature and is tested by wave flume experiments.     

Drinking water quality in villages of southwestern Haryana,India: assessing human health risks associated with hydrochemistry

The chemical quality of groundwater of western Haryana, India was assessed for its suitability for drinking purposes. A total of 275 water samples were collected from deep aquifer based hand-pumps situated in 37 different villages/towns of Bhiwani region. The water samples were analyzed for different physico-chemical properties, e.g., pH, total dissolved solids (TDS), total harness (TH), total alkalinity (TA), calcium, magnesium, carbonate, bicarbonate, sulphate, chloride and fluoride concentrations. In this study, the average TDS content was greater ranging 1,692 (Bhiwani block) to 2,560 mg l⁻¹ (Siwani block), and other important parameters of water, e.g., TA (442–1,232 mg l⁻¹), TH (437–864 mg l⁻¹) and bicarbonate (554–672 mg l⁻¹), were also higher than maximum permissible limit by WHO or BIS. The fluoride appeared as a major problem of safe drinking water in this region. We recorded greater fluoride concentration, i.e., 86.0 mg l⁻¹ from Motipura village that is highest fluoride level ever recorded for Haryana state. The average fluoride concentration ranged between 7.1 and 0.8 mg l⁻¹ in different blocks of western Haryana. On the basis of fluoride concentration, Siwani block showed the maximum number of water samples (84% of total collected samples) unsuitable for drinking purposes (containing fluoride >1.5 mg l⁻¹) followed by Charki Dadri block (58%), Bhiwani block (52%), Bawani Khera block (33%) and Loharu block (14%). This study clearly suggest that some health deteriorating chemicals in drinking water were at dangerous level and; therefore, water quality could be a major health threat for local residents of western Haryana. The high fluoride level in drinking water has posed some serious dental health risks in local residents.