The sagging deep-seated gravitational movements on the eastern side of Mt. Amiata (Tuscany,Italy)

The eastern side of the Mt. Amiata volcano is affected by a series of deep-seated gravitational slope deformations (DsGSDs). The San Piero and the Podere Mezzavia DsGSDs affect the lower part of the slope. The main escarpments are located on the outer edges of the lava flows, but the landslides mostly affect the pre-volcanic Ligurian Terrains. A deeper movement, possibly exceeding 100 m in thickness, is evidenced by a long trench at the base of the main escarpment that indicates a sagging type movement. This deeper movement is responsible for the activation of a series of superficial rock and mud flows that show evidence of ongoing activity. The most likely location of the sliding surface is the tectonized contact between the Santa Fiora and Argille a Palombini Fms within the Ligurian units, although the superficial landslides prevent our determining with certainty if a clear-cut sliding surface already developed connecting the upper and the lower parts of the slope. These DsGSDs were activated along the flanks of a larger movement that affects the lava flow units cropping out in the middle slope of the volcano. A long main escarpment, secondary escarpments, trenches and borehole data suggest that the thickness could locally exceed 200 m and generate another sagging type movement. Up-slope and up-movement-facing counterscarps indicate the existence of a listric elongated spoon-shaped compound embryonic sliding surface. This sagging, which hosts the towns of Abbadia San Salvatore and Piancastagnaio, appears to be in a quiescent stage, according to preliminary monitoring with a global positioning system (GPS) network. The downcutting of the river network along the softer Pliocene terrains of the Radicofani basin is enhanced by the general uplift of the Apennines and seems to be the major factor in the activation of these DsGSDs.     

Technological study of “ghiara” mortars from the historical city centre of Catania (Eastern Sicily, Italy) and petro-chemical characterisation of raw materials

This paper presents new petro-chemical data on some typical mortars found in many buildings in the historic city centre of Catania (Eastern Sicily). Extensively used in the architecture of the city from the second half of the nineteenth century until the mid-twentieth century, these mortars are characterised by a particular aggregate locally known as “agghiara” or “ghiara”. This is the product of thermal transformation induced by the heating undergone by palaeo-soils, originally rich in organic matter, covered by lava flows, which change their colour to reddish nuances. The volcanic origin of ghiara is a peculiar feature of the Etnean area. Mixed with lime, it gives to mortars an intense reddish colour, as well as hydraulic properties, which are comparable with those of the historically used pozzolana. This work aimed at complete characterisation of these ghiara mortars, for providing information on several important technological aspects. In order to get information on used raw materials, sampling of some ancient underground quarries, located both in the historic city centre and at the periphery, was also performed. Results led to the complete characterisation of the selected ghiara mortars and yielded information on some technological features and the composition of both newly formed and secondary phases, these latter due to alteration processes. The hydraulic properties of mortars have been related to the occurrence of amorphous phases within the ghiara aggregate, which were identified by means of SEM morphological observations. These phases, formed during the “firing” process of palaeo-soils, react with lime producing hydraulic compounds (C–S–H and C–A–H), which are responsible for the mortars durability.     

The use of iron chemical analysis of podzols to date the Late Pleistocene–Holocene deglaciation history of the Central Italian Alps

Podzols that have developed on glacial and periglacial features provide the opportunity to reconstruct glacial evolution after the Last Glacial Maximum (LGM) using different soil indices. Analysing 17 soils classified as podzol, we used the crystallinity ratio of free iron oxides (CRF) on both the A and Bs horizons, and absolute ages for the same landforms containing the soil profile, to create dating curves. Two equations were generated: age = 4566.9 × ln (CRF) + 1760 (1), and age = 3907 × ln (CRF) + 3508.2 (2). The reliability of the curves was evaluated with the Fe_o/Fe_d ratio, and with the difference of ages calculated using both equations. Equation (2) is considered more reliable because the A horizon may be influenced by new pedogenesis on the pre-existing podzol, leading to the development of a new type of soil. By dating the soils, we reconstructed the glacial history of the three main upper branches of the LGM Adda Glacier in the Central Italian Alps, specifically the Stelvio Pass area (ST), Gavia Pass area (GV), and the Val Viola valley (VV). Seven glacial advances were identified at 16.7–14.7 ka (phase I), 12.3 ka (phase II), 11 ka (phase III), 10–9.7 ka (phase IV), 9 ka (phase V), 7.5 ka (phase VI) and 5.3 ka (phase VII). The first five phases are chronologically similar to the main Late Pleistocene–Early Holocene phases recorded in the Central European Alps. The last two Holocene phases, which are both longer in duration than the Little Ice Age, are recorded in ST and GV. Interestingly, these phases generally are not recorded in the rest of the Central European Alps, where the late Holocene glaciers were smaller than their present size.     

The high-pressure stability of chlorite and other hydrates in subduction mélanges: experiments in the system Cr<Subscript>2</Subscript>O<Subscript>3</Subscript>–MgO–Al<Subscript>2</Subscript>O<Subscript>3</Subscript>–SiO<Subscript>2</Subscript>–H<Subscript>2</Subscript>O

The solubility of chromium in chlorite as a function of pressure, temperature, and bulk composition was investigated in the system Cr₂O₃–MgO–Al₂O₃–SiO₂–H₂O, and its effect on phase relations evaluated. Three different compositions with X _Cr = Cr/(Cr + Al) = 0.075, 0.25, and 0.5 respectively, were investigated at 1.5–6.5 GPa, 650–900 °C. Cr-chlorite only occurs in the bulk composition with X _Cr = 0.075; otherwise, spinel and garnet are the major aluminous phases. In the experiments, Cr-chlorite coexists with enstatite up to 3.5 GPa, 800–850 °C, and with forsterite, pyrope, and spinel at higher pressure. At P > 5 GPa other hydrates occur: a Cr-bearing phase-HAPY (Mg_2.2Al_1.5Cr_0.1Si_1.1O₆(OH)₂) is stable in assemblage with pyrope, forsterite, and spinel; Mg-sursassite coexists at 6.0 GPa, 650 °C with forsterite and spinel and a new Cr-bearing phase, named 11.5 Å phase (Mg:Al:Si = 6.3:1.2:2.4) after the first diffraction peak observed in high-resolution X-ray diffraction pattern. Cr affects the stability of chlorite by shifting its breakdown reactions toward higher temperature, but Cr solubility at high pressure is reduced compared with the solubility observed in low-pressure occurrences in hydrothermal environments. Chromium partitions generally according to \(X_{\text{Cr}}^{\text{spinel}}\) ? \(X_{\text{Cr}}^{\text{opx}}\) > \(X_{\text{Cr}}^{\text{chlorite}}\) ≥ \(X_{\text{Cr}}^{\text{HAPY}}\) > \(X_{\text{Cr}}^{\text{garnet}}\). At 5 GPa, 750 °C (bulk with X _Cr = 0.075) equilibrium values are \(X_{\text{Cr}}^{\text{spinel}}\) = 0.27, \(X_{\text{Cr}}^{\text{chlorite}}\) = 0.08, \(X_{\text{Cr}}^{\text{garnet}}\) = 0.05; at 5.4 GPa, 720 °C \(X_{\text{Cr}}^{\text{spinel}}\) = 0.33, \(X_{\text{Cr}}^{\text{HAPY}}\) = 0.06, and \(X_{\text{Cr}}^{\text{garnet}}\) = 0.04; and at 3.5 GPa, 850 °C \(X_{\text{Cr}}^{\text{opx}}\) = 0.12 and \(X_{\text{Cr}}^{\text{chlorite}}\) = 0.07. Results on Cr–Al partitioning between spinel and garnet suggest that at low temperature the spinel- to garnet-peridotite transition has a negative slope of 0.5 GPa/100 °C. The formation of phase-HAPY, in assemblage with garnet and spinel, at pressures above chlorite breakdown, provides a viable mechanism to promote H₂O transport in metasomatized ultramafic mélanges of subduction channels.     

The Balance Between Capturing Phosphorus from Manure and Wastewater and the Demand for Crop Fertilizer in Italy

Phosphorus (P) is an essential nutrient required for plant growth and at the same time a costly pollutant, which can cause eutrophication of water bodies. Modern agriculture relies heavily on mineral fertilisers, which contain phosphorus derived from phosphate rock, because, without regular applications, crop yields would be limited. Since phosphate rock is a non-renewable resource, there are growing concerns regarding future phosphorus scarcity and the sustainability of modern agriculture. For many farmers, animal manure was once a means of maintaining soil fertility, but now it presents a major operational problem. This study evaluated the possibility of recycling phosphorus on a national and regional scale in Italy, using major sources of manure and wastewater. These results were successively compared with an estimate of the agricultural demand for phosphorus. Considering the quantity of phosphorus fertilizer that was applied to the soil–plant system, for the years 2001–2010, the annual phosphorus requirement of Italian crops was about 101,000 t of P. Therefore, the phosphorus source comprising animal manure and civil/industrial waste (117,500 t of P and 40,000 t of P, respectively) could potentially satisfy the average annual agronomic phosphorus demand. Regarding the geographical distribution of phosphorus supply and demand on a regional scale, areas with a large deficit of phosphorus included Calabria, Puglia and Marche. However, when only livestock waste was considered, Sicily, Umbria and Friuli could also be considered to be regions experiencing a phosphorus deficit.

     

3D coupled fluid and heat transport simulations of the Northeast German Basin and their sensitivity to the spatial discretization: different sensitivities for different mechanisms of heat transport

Based on a numerical model of the Northeast German Basin (NEGB), we investigate the sensitivity of the calculated thermal field as resulting from heat conduction, forced and free convection in response to consecutive horizontal and vertical mesh refinements. Our results suggest that computational findings are more sensitive to consecutive horizontal mesh refinements than to changes in the vertical resolution. In addition, the degree of mesh sensitivity depends strongly on the type of the process being investigated, whether heat conduction, forced convection or free thermal convection represents the active heat driver. In this regard, heat conduction exhibits to be relative robust to imposed changes in the spatial discretization. A systematic mesh sensitivity is observed in areas where forced convection promotes an effective role in shorten the background conductive thermal field. In contrast, free thermal convection is to be regarded as the most sensitive heat transport process as demonstrated by non-systematic changes in the temperature field with respect to imposed changes in the model resolution.