Late Pleistocene fluvial dynamics in the Hochrhein Valley and in the Upper Rhine Graben: chronological frame

During the Pleistocene, the Rhine glacier system acted as a major south–north erosion and transport medium from the Swiss Alps into the Upper Rhine Graben, which has been the main sediment sink forming low angle debris fans. Only some aggradation resulted in the formation of terraces. Optically stimulated luminescence (OSL) and radiocarbon dating have been applied to set up a more reliable chronological frame of Late Pleistocene and Holocene fluvial activity in the western Hochrhein Valley and in the southern part of the Upper Rhine Graben. The stratigraphically oldest deposits exposed, a braided-river facies, yielded OSL age estimates ranging from 59.6 ± 6.2 to 33.1 ± 3.0 ka. The data set does not enable to distinguish between a linear age increase triggered by a continuous autocyclical aggradation or two (or more) age clusters, for example around 35 ka and around 55 ka, triggered by climate change, including stadial and interstadial periods (sensu Dansgaard–Oeschger cycles). The braided river facies is discontinuously (hiatus) covered by coarse-grained gravel-rich sediments deposited most likely during a single event or short-time period of major melt water discharge postdating the Last Glacial Maximum. OSL age estimates of fluvial and aeolian sediments from the above coarse-grained sediment layer are between 16.4 ± 0.8 and 10.6 ± 0.5 ka, and make a correlation with the Late Glacial period very likely. The youngest fluvial aggradation period correlates to the beginning of the Little Ice Age, as confirmed by OSL and radiocarbon ages.     

The Nuclear Stellar Cluster in NGC 1068

We present new near-infrared integral field spectroscopy and adaptive optics imaging of the nucleus of NGC 1068. Using the stellar CO absorption features in the H and K bands, we have identified a moderately extincted stellar core centered on the nuclear position and of intrinsic size ~50 pc. We show that this nuclear stellar core is probably 5-16 × 108 years in age and contributes at least 7% of the total nuclear luminosity of ~1 × 1011 L⊙. This revised version was published online in July 2006 with corrections to the Cover Date.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

3D shear-wave velocity structure of the Eifel plume, Germany

The Quaternary Eifel volcanic fields, situated on the Rhenish Massif in Germany, are the focus of a major interdisciplinary project. The aim is a detailed study of the crustal and mantle structure of the intraplate volcanic fields and their deep origin. Recent results from a teleseismic P-wave tomography study reveal a deep low-velocity structure which we infer to be a plume in the upper mantle underneath the volcanic area [J.R.R. Ritter et al., Earth Planet. Sci. Lett. 186 (2001) 7-14]. Here we present a travel-time investigation of 5038 teleseismic shear-wave arrivals in the same region. First, the transverse (T) and radial (R) component travel-time residuals are treated separately to identify possible effects of seismic anisotropy. A comparison of 2044 T- and 2994 R-component residuals demonstrates that anisotropy does not cause any first-order travel-time effects. The data sets reveal a deep-seated low-velocity anomaly beneath the volcanic region, causing a delay for teleseismic shear waves of about 3 s. Using 3773 combined R- and T-component residuals, an isotropic non-linear inversion is calculated. The tomographic images reveal a prominent S-wave velocity reduction in the upper mantle underneath the Eifel region. The anomaly extends down to at least 400 km depth. The velocity contrast to the surrounding mantle is depth-dependent (from −5% at 31-100 km depth to at least −1% at 400 km depth). At about 170-240 km depth the anomaly is nearly absent. The resolution of the data is sufficient to recover the described features, however the anomaly in the lower asthenosphere is underestimated due to smearing and damping. The main anomaly is similar to the P-wave model except the latter lacks the ‘hole’ near 200 km depth, and both are consistent with an upper mantle plume structure. For plausible anhydrous plume material in the uppermost 100 km of the mantle, an excess temperature as great as 200-300 K is estimated from the seismic anomaly. However, 1% partial melt reduces the required temperature anomaly to about 100 K. The temperature anomaly associated with the deeper part of the plume (250 to about 450 km depth) is at least 70 K. However, this estimate is quite uncertain, because the amplitude of the shear-wave anomaly may be larger than the modelled one. Another possibility is water in the upwelling material. The gap at 170-240 km depth could arise from an increase of the shear modulus caused by dehydration processes which would not affect P-wave velocities as much. An interaction of temperature and compositional variations, including melt and possibly water, makes it difficult to differentiate quantitatively between the causes of the deep-seated low-velocity anomaly.     

Extraktion und Verteilung der Aminosäuren in einigen kretazischen Kernproben

Zusammenfassung In 45 Sedimentproben wurde die Verteilung von 16 Aminosäuren quantitativ bestimmt. Durch aufeinanderfolgende Hydrolysen des gleichen Gesteins mit verschiedenen Säuren ließen sich zwei Arten von Aminosäurenverbindungen ermitteln. Aus den Verhältniswerten dieser löslichen, bereits mit 6-N-Salzsäure freisetzbaren Aminosäuren und der kerogengebundenen mit 12 N HCl zugänglichen Komponente lassen sich über die thermische Beanspruchung und den Reifungszustand eines Sedimentes Schlüsse ziehen. Diese stimmen mit den Ergebnissen der durchgeführten Thermalversuche überein und erklären sich durch eine Änderung der Bindungsform der Aminosäuren am Kerogen. Durch zunehmende thermische Beanspruchung erhöht sich der kerogengebundene Aminosäurenanteil, während das Verhältnis zwischen neutralen und nicht neutralen Aminosäuren abnimmt.

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The distribution of 16 aminoacids in 45 sedimentsamples has been determined. Two separate groups of aminoacids could be isolated by successive treatment of the same rock with different acids i. e. rather loosely bound aminoacids isolated by 6 N HCl hydrolysis and aminoacids incorporated in the kerogen, which could be recovered only upon 12 N HCl treatment. From the ratio of these groups conclusions may be drawn with respect to the thermal history and maturity of a sediment. The conclusions have been verified by thermal experiments and may be explained by a modification of the way of compound of the aminoacids with the kerogen. With increasing thermal influence the strongly combined aminoacid fraction becomes relatively predominant. At the same time the ratio of neutral and other aminoacids in these fractions decreases.

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Résumé Le rendement de l'extraction des amino-acides présents dans la roche est fonction de la solubilité de la roche, donc de la pétrographie des échantillons. C'est pourquoi on déminéralise la roche d'abord à l'aide d'acide chlorhydrique, puis d'acide fluorhydrique; on élimine ensuite les constituants bitumineux à l'aide d'acide formique. Le kérogène ainsi isolé fait l'objet de l'hydrolyse proprement dite, laquelle est entreprise par traitements successifs à l'HCl 6 N et à l'HCl 12 N. Ce double traitement a pour effet de séparer des fractions faiblement et fortement combinées.La fraction obtenue par hydrolyse à l'HCl 6 N représente les amino-acides liés au kérogène par adsorption superficielle; la fraction 12 N HCl contient les amino-acides qui étaient intimement incorporés dans le kérogène, en faisant partie de la structure. Cette dernière fraction devient relativement de plus en plus importante avec l'âge et la maturation croissantes; par traitement thermique d'échantillons récents, traitement simulant le vieillissement et la maturation, on constate la même chose. La part des amino-acides neutres diminue, avec la température et la profondeur croissantes, dans la fraction 12 N; elle augmente dans la fraction 6 N.Des échantillons mésozoiques provenant d'un forage profond d'Aquitaine ont été analysés. Les concentrations totales en amino-acides sont en corrélation avec les concentrations en fossiles. D'autre part, dans le partie inférieure du forage (donc la partie dont on peut penser qu'elle est la plus évoluée), on voit le rapport amino-acides neutres/amino-acides totaux diminuer avec la profondeur. Il est à noter que des changements nets dans ce rapport coïncident avec des limites stratigraphiques.

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. 45 , 16 . : 1) 6 HCI II) 12 HCI. .

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Herrn Professor Dr.Roland Brinkmann zum 70. Geburtstag gewidmet.

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Der Direktion derSocièté Nationale Des Pétroles D'Aquitaine, Pau, danke ich für die Ermöglichung dieser Arbeiten und die Genehmigung ihrer Veröffentlichung, den Herren Doktoren G.Kulbicki und B.van der Weide für die vielseitigen Anregungen und Diskussionen. Herrn Prof. Dr. E. T.Degens bin ich für die Durchsicht des Manuskriptes sehr dankbar.     

Eocene-Pliocene time scale and stratigraphy of the Upper Rhine Graben (URG) and the Swiss Molasse Basin (SMB)

We present a general stratigraphic synthesis for the Upper Rhine Graben (URG) and the Swiss Molasse Basin (SMB) from Eocene to Pliocene times. The stratigraphic data were compiled both from literature and from research carried out by the authors during the past 6 years ; an index of the stratigraphically most important localitites is provided. We distinguish 14 geographical areas from the Helvetic domain in the South to the Hanau Basin in the North. For each geographical area, we give a synthesis of the biostratigraphy, lithofacies, and chronostratigraphic ranges. The relationships between this stratigraphic record and the global sea-level changes are generally disturbed by the geodynamic (e.g., subsidence) evolution of the basins. However, global sea-level changes probably affected the dynamic of transgression–regression in the URG (e.g., Middle Pechelbronn Beds and Serie Grise corresponding with sea-level rise between Ru1/Ru2 and Ru2/Ru3 sequences, respectively) as well as in the Molasse basin (regression of the UMM corresponding with the sea-level drop at the Ch1 sequence). The URGENT-project (Upper Rhine Graben evolution and neotectonics) provided an unique opportunity to carry out and present this synthesis. Discussions with scientists addressing sedimentology, tectonics, geophysics and geochemistry permitted the comparison of the sedimentary history and stratigraphy of the basin with processes controlling its geodynamic evolution. Data presented here back up the palaeogeographic reconstructions presented in a companion paper by the same authors (see Berger et al. in Int J Earth Sci 2005).     

The Water Framework Directive: Can more information be extracted from groundwater data? A case study of Seewinkel,Burgenland, eastern Austria

Water protection is one of the most important goals in environmental protection. The Clean Water Act in the USA and the Water Framework Directive (WFD) in Europe are the legal frameworks to facilitate the achievement of this goal. The question is raised of whether more information can be extracted from WFD-related groundwater data. To answer it, a methodology has been developed that is easy to use and could be implemented into official practice. A case study is presented in which the groundwater data of a sodic area in Austria (Seewinkel) is assessed. Eighteen parameters in groundwater sampled from 23 wells (1991–2011) were analyzed. With basic statistics, trend-, cluster-, Wilks’ λ and spatial sampling density analysis, local phosphorus and boron phenomena were described, along with the determining role of sulphate, groundwater flow, and the oxygen gradient in the area. As a final step, the spatial sampling density was determined. Regarding the current set of parameters, all the sampling sites are necessary and only in the case of certain parameters (Ca²⁺, Mg²⁺, K⁺, NO₃ ^?, pH) could one sampling site be abandoned. The methodology applied brings a new perspective to exploring groundwater data collected according to the requirements of the WFD.     

Fifteen days of continuous activity survey at Stromboli volcano, Italy, in late September 2000: Doppler radar, seismicity, infrared, soil humidity, and mapping of the crater region

The intention of our study was to gain new insight into the complex interplay between different types of eruption of the Stromboli volcano by combining detailed field observation with different geophysical methods. We recorded more than 600 eruptions by use of continuous Doppler radar measurements. We detected the onset of the seismic precursor and the beginning of the visible eruption by use of seismic and infrared data. Two soil samples per day were used to monitor the effect of humidity on the eruptive style. We mapped the crater region as a reference base for the long-term morphological changes of the active region and for the exact positions of our measurement systems. Two distinct types of eruption were distinguished from each other on the basis of seismic and radar data - short, wide-angle Strombolian explosions and pulsating, sharp angle fountain-like eruptions. Data and visual observations imply that weather conditions significantly effect volcanic activity. We also interpret the intensification of eruptive activity during our field study as replenishment of the reservoir with a new batch of magma in late September 2000.     

Multi-stage reaction history in different eclogite types from the Pakistan Himalaya and implications for exhumation processes

Metabasites were sampled from rock series of the subducted margin of the Indian Plate, the so-called Higher Himalayan Crystalline, in the Upper Kaghan Valley, Pakistan. These vary from corona dolerites, cropping out around Saif-ul-Muluk in the south, to coesite–eclogite close to the suture zone against rocks of the Kohistan arc in the north. Bulk rock major- and trace- element chemistry reveals essentially a single protolith as the source for five different eclogite types, which differ in fabric, modal mineralogy as well as in mineral chemistry. The study of newly-collected samples reveals coesite (confirmed by in situ Raman spectroscopy) in both garnet and omphacite. All eclogites show growth of amphiboles during exhumation. Within some coesite-bearing eclogites the presence of glaucophane cores to barroisite is noted whereas in most samples porphyroblastic sodic–calcic amphiboles are rimmed by more aluminous calcic amphibole (pargasite, tschermakite, and edenite). Eclogite facies rutile is replaced by ilmenite which itself is commonly surrounded by titanite. In addition, some eclogite bodies show leucocratic segregations containing phengite, quartz, zoisite and/or kyanite. The important implication is that the complex exhumation path shows stages of initial cooling during decompression (formation of glaucophane) followed by reheating: a very similar situation to that reported for the coesite-bearing eclogite series of the Tso Morari massif, India, 450 km to the south-east.