Petrogenetic relationships of acid and basic rocks in iceland: Sr-isotopes and rare-earth elements in late and postglacial volcanics

Strontium isotope ratios and rare-earth element abundances have been measured in acid, intermediate and basic rocks from three late to postglacial volcanic complexes, and several other postglacial basalts in Iceland. Late and postglacial basalts in Iceland have been generated from a source region which is essentially homogeneous with respect to⁸⁷Sr/⁸⁶Sr. The mean⁸⁷Sr/⁸⁶Sr ratio for the basalts analysed is 0.70328 and the range is from 0.70317 ± 6to0.70334 ± 5 (2σ).Acid rocks from the Kerlinganfjöll and Namafjall volcanic complexes have⁸⁷Sr/⁸⁶Sr ratios which are indistinguishable from analysed basalts from the same complexes. However, intermediate and acid rocks from the Torfajökull complex have significantly higher⁸⁷Sr/⁸⁶Sr ratios and could not have been derived by fractional crystallization from basaltic magmas similar to those found in the same complex. These latter rocks have most probably been produced by remelting of Tertiary gabbroic rocks in Layer 3. Most of the basalts analysed have higher total rare-earth element abundances than typical dredged ocean-ridge tholeiites, and show less light rare-earth depletion. Intermediate and acid compositions show overall higher abundances and light rare-earth enrichments. The measured rare-earth abundances are compared with abundances generated by differential partial melting of various model source regions.It is shown that both the tholeiitic and alkali basalt compositions could be generated from the same source material by different degrees of partial melting. Variable partial melting of gabbroic material may account for the rare-earth element abundances of both the rhyolitic rocks (small degrees of melting) and the intermediate rocks (more extensive melting).     

Extraktion und Verteilung der Aminosäuren in einigen kretazischen Kernproben

Zusammenfassung In 45 Sedimentproben wurde die Verteilung von 16 Aminosäuren quantitativ bestimmt. Durch aufeinanderfolgende Hydrolysen des gleichen Gesteins mit verschiedenen Säuren ließen sich zwei Arten von Aminosäurenverbindungen ermitteln. Aus den Verhältniswerten dieser löslichen, bereits mit 6-N-Salzsäure freisetzbaren Aminosäuren und der kerogengebundenen mit 12 N HCl zugänglichen Komponente lassen sich über die thermische Beanspruchung und den Reifungszustand eines Sedimentes Schlüsse ziehen. Diese stimmen mit den Ergebnissen der durchgeführten Thermalversuche überein und erklären sich durch eine Änderung der Bindungsform der Aminosäuren am Kerogen. Durch zunehmende thermische Beanspruchung erhöht sich der kerogengebundene Aminosäurenanteil, während das Verhältnis zwischen neutralen und nicht neutralen Aminosäuren abnimmt.

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The distribution of 16 aminoacids in 45 sedimentsamples has been determined. Two separate groups of aminoacids could be isolated by successive treatment of the same rock with different acids i. e. rather loosely bound aminoacids isolated by 6 N HCl hydrolysis and aminoacids incorporated in the kerogen, which could be recovered only upon 12 N HCl treatment. From the ratio of these groups conclusions may be drawn with respect to the thermal history and maturity of a sediment. The conclusions have been verified by thermal experiments and may be explained by a modification of the way of compound of the aminoacids with the kerogen. With increasing thermal influence the strongly combined aminoacid fraction becomes relatively predominant. At the same time the ratio of neutral and other aminoacids in these fractions decreases.

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Résumé Le rendement de l'extraction des amino-acides présents dans la roche est fonction de la solubilité de la roche, donc de la pétrographie des échantillons. C'est pourquoi on déminéralise la roche d'abord à l'aide d'acide chlorhydrique, puis d'acide fluorhydrique; on élimine ensuite les constituants bitumineux à l'aide d'acide formique. Le kérogène ainsi isolé fait l'objet de l'hydrolyse proprement dite, laquelle est entreprise par traitements successifs à l'HCl 6 N et à l'HCl 12 N. Ce double traitement a pour effet de séparer des fractions faiblement et fortement combinées.La fraction obtenue par hydrolyse à l'HCl 6 N représente les amino-acides liés au kérogène par adsorption superficielle; la fraction 12 N HCl contient les amino-acides qui étaient intimement incorporés dans le kérogène, en faisant partie de la structure. Cette dernière fraction devient relativement de plus en plus importante avec l'âge et la maturation croissantes; par traitement thermique d'échantillons récents, traitement simulant le vieillissement et la maturation, on constate la même chose. La part des amino-acides neutres diminue, avec la température et la profondeur croissantes, dans la fraction 12 N; elle augmente dans la fraction 6 N.Des échantillons mésozoiques provenant d'un forage profond d'Aquitaine ont été analysés. Les concentrations totales en amino-acides sont en corrélation avec les concentrations en fossiles. D'autre part, dans le partie inférieure du forage (donc la partie dont on peut penser qu'elle est la plus évoluée), on voit le rapport amino-acides neutres/amino-acides totaux diminuer avec la profondeur. Il est à noter que des changements nets dans ce rapport coïncident avec des limites stratigraphiques.

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. 45 , 16 . : 1) 6 HCI II) 12 HCI. .

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Herrn Professor Dr.Roland Brinkmann zum 70. Geburtstag gewidmet.

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Der Direktion derSocièté Nationale Des Pétroles D'Aquitaine, Pau, danke ich für die Ermöglichung dieser Arbeiten und die Genehmigung ihrer Veröffentlichung, den Herren Doktoren G.Kulbicki und B.van der Weide für die vielseitigen Anregungen und Diskussionen. Herrn Prof. Dr. E. T.Degens bin ich für die Durchsicht des Manuskriptes sehr dankbar.     

Zur Theorie der sogenannten Kopfwellen mit unendlich kleinen Amplituden

Zusammenfassung der mathematischen Ergebnisse Die von uns erhaltenen annäherndD' Alembert'schen Lösungsformen der Wellengleichung (1) sind mit den Formeln (11), (14) und (25) dargestellt; die Bedingungen für ihre Existenz sind im Hauptsatz gegeben.

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Summary Case of two reflected waves in Seismology and in general Mechanics. Four types of waves near to a surface. The general properties of the concept «wave». Thermic and geometric extinction of a wave. Conditions a) that an aggregate of waves has the properties of a wave, and b) that the so formed aggregate has no more these properties. A new case of solution near to the type ofD' Alembert; some applications. Interference of two waves and impossibility of such interference of two ensembles of waves, in the general case.

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Resumé Deux ondes réflechies en Séismologie et en Mécanique générale. Quatro types des ondes près d'une surface. Les propriétés générales de la notion d' «onde». Amortissement thermique et géométrique d'une onde. Les conditions où un agrégat des ondes fornie une onde et où cet agrégat n'est pas une onde. Un nouvel cas de la solution de l'équation d'ondes proche à la solution deD' Alembert. Quelques applications. L'interférence de deux ondes et l'impossibilité de l'interference dans le cas général de deux ensembles des ondes.

     

Investigation of Image Fusion Between High—Resolution Image and Multi—Spectral Image

On the basis of a thorough understanding of the physical characteristics of remote sensing image,this paper employs the theories of wavelet transform and signal sampling to develop a new image fusion algorithm.The algorithm has been successfully applied to the image fusion of SPOT PAN and TM of Guangdong province, China The experimental results show that a perfect image fusion can be built up by using the image analytical solution and reconstruction in the image frequency domain based on the physical characteristics of the image formation.The method has demonstrated that the results of the image fusion do not change spectral characteristics of the original image.     

Similar single-difference model and its algorithm for solving GPS monitoring deformation directly at single epoch

A new similar singledifference mathematical model ( SS-DM) and its corresponding algorithm are advanced to solve the deformation of monitoring point directly in single epoch. The method for building the SSDM is introduced in detail, and the main error sources affecting the accuracy of deformation measurement are analyzed briefly, and the basic algorithm and steps of solving the deformation are discussed. In order to validate the correctness and the accuracy of the similar single-difference model, the test with five dual frequency receivers is carried out on a slideway which moved in plane in Feb. 2001. In the test, five sessions are observed. The numerical results of test data show that the advanced model is correct.     

SAR image classification based on its texture features

SAR images not only have the characteristics of all-ay, all-eather, but also provide object infor-mation which is different from visible and infrared sensors. However, SAR images have some faults, such as more speckles and fewer bands. The au-thors conducted the experiments of texture statistics analysis on SAR im-age features in order to improve the accuracy of SAR image interpretation.It is found that the texture analysis is an effective method for improving the accuracy of the SAR image interpreta-tion.