The correlation between geochemical data and SPOT satellite imagery of lateritic terrain in southern Mali

Detailed geochemical mapping of superficial lateritic formations is compared with recent high-resolution SPOT satellite images in the Dagadamou prospect in southern Mali.The two main landscape features standing out in SPOT images are expressed by thematic indices derived from multispectral data. They reflect the distribution of vegetation cover and the distinction between silty clay soils in the valleys and ferruginous duricrust exposed on the plateaus. Geochemical differentiation factors are closely related to the nature of sampled materials and reflect the relative amounts of major constituent minerals estimated by normative calculation.Duricrust samples with high Fe and Al content are also enriched in trace elements, P, V, Cr, As, Mo, Nb and Cu, immobilized in the weathering profile with secondary oxihydroxide minerals.Soils of flats are composed mainly of quartz and kaolinite; they also concentrate heavy minerals characterized by high contents of Zr, Ti, Ce and Y.Accumulation of detrital material at the periphery of duricrust plateaus is marked by a geochemical halo of higher contents in Zr and quartz at their periphery. This feature is clearly visible on SPOT imagery as a zone of high reflectance, devoid of vegetation.The density of vegetation on duricrust is related to its kaolinite content. Its distribution is characterized by a striped pattern, which is probably controlled by bedrock lithological structures preserved in the lateritic cover.This study shows the relationships, both direct and indirect, existing between spectral reflectance and geochemical composition of superficial lateritic formations. Many other landscape features identified with high resolution on SPOT images provide complementary information, which could be very helpful at various stages of geological and mineral exploration in lateritic terrain.     

Vibrational spectroscopy of beryllium aluminosilicates: Heat capacity calculations from band assignments

Far-infrared, mid-IR, and Raman powder spectra were measured on six phases (bromellite, chrysoberyl, phenakite, bertrandite, beryl, and euclase) in the system BeO-Al₂O₃-SiO₂-H₂O. A single-crystal absorption spectrum of IR fundamentals in beryl is also presented, which more closely resembles the powder absorption spectrum than it does absorption spectra calculated from single-crystal reflection data. Assignments of the SiO₄ and BeO₄ internal vibrations are made in accordance with each mineral's symmetry and composition and by comparison to structural analogs. Heat capacities C _v calculated for these partial band assignments agree with C _v derived from experimental C _p for all six phases, provided that Kieffer's (1979c) model is slightly modified to correctly enumerate both Si-O and Be-O stretching modes in the high frequency region (>750 cm^?1). Si-O stretching bands were found to out-number Be-O stretching modes in the high-energy region of the vibrational spectra with two exceptions: (1) For those phases containing oxygen ions not coordinated to silicon, vibrations occurring at v>1,080 cm^?1 that are attributable to Be-O (H) stretching must be treated separately in the model in order to calculate C _v accurately. (2) Minerals consisting entirely of interlocking Si and Be tetrahedra (i.e., phases without Al or OH) can be modeled by one optic continuum representing all optical modes. These results, along with the occurrence of very low energy lattice vibrations for Be-silicates within Al, suggests that although Be-O bonds are generally weaker than neighboring Si-O bonds, Be mimics the network-forming characteristic of Si to a limited extent.     

On the climate response of the low-latitude Pacific Ocean to changes in the global freshwater cycle

Under global warming, the predicted intensification of the global freshwater cycle will modify the net freshwater flux at the ocean surface. Since the freshwater flux maintains ocean salinity structures, changes to the density-driven ocean circulation are likely. A modified ocean circulation could further alter the climate, potentially allowing rapid changes, as seen in the past. The relevant feedback mechanisms and timescales are poorly understood in detail, however, especially at low latitudes where the effects of salinity are relatively subtle. In an attempt to resolve some of these outstanding issues, we present an investigation of the climate response of the low-latitude Pacific region to changes in freshwater forcing. Initiated from the present-day thermohaline structure, a control run of a coupled ocean–atmosphere general circulation model is compared with a perturbation run in which the net freshwater flux is prescribed to be zero over the ocean. Such an extreme experiment helps to elucidate the general adjustment mechanisms and their timescales. The atmospheric greenhouse gas concentrations are held constant, and we restrict our attention to the adjustment of the upper 1,000 m of the Pacific Ocean between 40°N and 40°S, over 100 years. In the perturbation run, changes to the surface buoyancy, near-surface vertical mixing and mixed-layer depth are established within 1 year. Subsequently, relative to the control run, the surface of the low-latitude Pacific Ocean in the perturbation run warms by an average of 0.6°C, and the interior cools by up to 1.1°C, after a few decades. This vertical re-arrangement of the ocean heat content is shown to be achieved by a gradual shutdown of the heat flux due to isopycnal (i.e. along surfaces of constant density) mixing, the vertical component of which is downwards at low latitudes. This heat transfer depends crucially upon the existence of density-compensating temperature and salinity gradients on isopycnal surfaces. The timescale of the thermal changes in the perturbation run is therefore set by the timescale for the decay of isopycnal salinity gradients in response to the eliminated freshwater forcing, which we demonstrate to be around 10–20 years. Such isopycnal heat flux changes may play a role in the response of the low-latitude climate to a future accelerated freshwater cycle. Specifically, the mechanism appears to represent a weak negative sea surface temperature feedback, which we speculate might partially shield from view the anthropogenically-forced global warming signal at low latitudes. Furthermore, since the surface freshwater flux is shown to play a role in determining the ocean’s thermal structure, it follows that evaporation and/or precipitation biases in general circulation models are likely to cause sea surface temperature biases.     

Petrology and oxygen isotopic compositions of clasts in HED polymict breccia NWA 5232

Northwest Africa (NWA) 5232, an 18.5 kg polymict eucrite, comprises eucritic and exogenic CM carbonaceous chondrite clasts within a clastic matrix. Basaltic clasts are the most abundant eucritic clast type and show a range of textures and grain size, from subophitic to granoblastic. Other eucritic clast types present include cumulate (high‐En pyroxene), pyroxene‐lath, olivine rich with symplectite intergrowths as a break‐down product of a quickly cooled Fe‐rich metastable pyroxferroite, and breccia (fragments of a previously consolidated breccia) clasts. A variable cooling rate and degree of thermal metamorphism, followed by a complex brecciation history, can be inferred for the clasts based on clast rounding, crystallization (and recrystallization) textures, pyroxene major and minor element compositions, and pyroxene exsolution. The range in δ¹⁸O of clasts and matrix of NWA 5232 reflects its origin as a breccia of mixed clasts dominated by eucritic lithologies. The oxygen isotopic compositions of the carbonaceous chondrite clasts identify them as belonging to CM group and indicate that these clasts experienced a low degree of aqueous alteration while part of their parent body. The complex evolutionary history of NWA 5232 implies that large‐scale impact excavation and mixing was an active process on the surface of the HED parent body, likely 4 Vesta.     

Palaeoflood activity and climate change over the last 1400 years recorded by lake sediments in the north‐west European Alps

A high‐resolution sedimentological and geochemical study of a high‐altitude proglacial lake (Lake Blanc, Aiguilles Rouges, 2352 m a.s.l.) revealed 195 turbidites, 190 of which are related to flood events over the last 1400 years. We used the coarsest sediment fraction of each turbidite as a proxy for the intensity of each flood event. Because most flood events at this locality are triggered by localized summer convective precipitation events, the reconstructed sedimentary record reveals changes in the frequency and intensity of such events over the last millennium. Comparisons with other temperature, palaeohydrological and glacier reconstructions in the region suggest that the most intense events occurred during the warmest periods, i.e. during the Medieval Climate Anomaly (AD 800–1300) and the current period of global warming. On a multi‐decadal time scale, almost all the flood frequency peaks seem to correspond to warmer periods, whereas multi‐centennial variations in flood frequency appear to follow the regional precipitation pattern. Consequently, this new Alpine flood record provides further evidence of a link between climate warming and an increase in the frequency and intensity of flooding on a multi‐decadal time scale, whereas the centennial variability in flood frequencies is related to regional precipitation patterns. Copyright © 2013 John Wiley & Sons, Ltd.     

Devitrite (Na2Ca3Si6O16)—structural, spectroscopic and computational investigations on a crystalline impurity phase in industrial soda-lime glasses

Single crystals of devitrite (Na₂Ca₃Si₆O₁₆) were synthesized as pale-yellow transparent needle shaped crystals using a Na₂MoO₄-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K₂MoO₄-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-K_α radiation, 2θ_max.?=?25.34°, R_int?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) ų, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO₆-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations.     

Earthquake swarms preceding the 2000 eruption of Miyakejima volcano, Japan

The first sign of magma accumulating beneath Miyakejima, an island volcano in the northern Izu islands, Japan, came at around 18:00 on 26 June 2000, when a swarm of earthquakes was detected by a volcano seismic network on the island. Earthquakes occurred initially beneath the southwest flank near the summit and gradually migrated west of the island, where a submarine eruption occurred the next morning. Earthquakes then migrated further to the northwest between Miyakejima and Kozushima, another volcanic island and developed to the most intense earthquake swarm ever observed in and around Japanese archipelago. To better image how the initial magma intrusion occurred, we relocated hypocenters by using a station-correction method and a double-difference method. The relocated epicenters are generally concentrated near the upper bound of dyke intrusions inferred from geodetic studies throughout the initial stages of the 2000 eruption at Miyakejima from 26 to 27 June 2000. As for seismic activity westward off Miyakejima in the morning on 27 June, hypocenters from both a nationwide seismic network that were relocated by the double-difference method, and those from the volcano seismic network relocated by the station-correction method, formed a very shallow cluster that ascended slowly with time as it propagated northwestward from Miyakejima. This suggests that the dykes have both a radial and upward component of movement.Editorial responsibility: S. Nakada, T. Druitt     

Effects of historical and projected land use/cover change on runoff and sediment yield in the Netravati river basin,Western Ghats,India

In this study, the effects of changes in historical and projected land use land cover (LULC) on monthly streamflow and sediment yield for the Netravati river basin in the Western Ghats of India are explored using land use maps from six time periods (1972, 1979, 1991, 2000, 2012, and 2030) and the soil and water assessment tool (SWAT). The LULC for 2030 is projected using the land change modeller with the assumption of normal growth. The sensitivity analysis, model calibration, and validation indicated that the SWAT model could reasonably simulate streamflow and sediment yield in the river basin. The results showed that the spatial extent of the LULC classes of urban (1.80–9.96%), agriculture (31.38–55.75%), and water bodies (1.48–2.66%) increased, whereas that of forest (53.04–27.03%), grassland (11.17–4.41%), and bare land (1.09–0.16%) decreased from 1972 to 2030. The streamflow increased steadily (7.88%) with changes in LULC, whereas the average annual sediment yield decreased (0.028%) between 1972 and 1991 and increased later (0.029%) until 2012. However, it may increase by 0.43% from 2012 to 2030. The results indicate that LULC changes in urbanization and agricultural intensification have contributed to the increase in runoff, amounting to 428.65 and 58.67 mm, respectively, and sediment yield, amounting to 348 and 43 ton/km², respectively, in the catchment area from 1972 to 2030. The proposed methodology can be applied to other river basins for which temporal digital LULC maps are available for better water resource management plans.     

Flory-Huggins' formulation,its validity and implications in retrieval of equilibrium temperature of binary and ternary systems at higher pressures,using liquid silicate data and 1 bar liquidus temperature

For a pure phase at equilibrium with a polycomponent melt, two sets of expressions can be derived; one expressing its activity as a function of enthalpy, entropy, heat capacity and temperature, and the other by coupling a Flory-Huggins' polymerisation model with the van Laar heat of mixing term. Interaction parameters for binary and ternary systems have been computed at 1 bar by equating these two expressions. Assuming the interaction parameter to be independent of temperature, equilibrium temperatures at higher pressures can be calculated by an iterative procedure. Such retrieval calculations were carried out in simple eutectic, volatile-free systems like CaAl₂Si₂O₈-CaMgSi₂O₆, Mg₂SiO₄-TiO₂, MgSiO₃-TiO₂, Mg₂SiO₄-CaMgSi₂O₆, NaAlSi₃O₈-SiO₂ and CaAl₂Si₂O₈-CaMgSi₂O₆-Mg₂SiO₄. The close agreement between the theoretically retrieved and the experimentally determined equilibrium temperatures testifies to the validity of the model at higher pressures. The successful application of the model to simple eutectic, binary and ternary systems involving vastly dissimilar phases without imposing added constraints implies that it can be possibly extended to hitherto unknown systems provided the thermodynamic parameters of the phases involved are known.