Progress in isotope paleohydrology using lake sediment cellulose

Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced by studies conducted over the past 15 years that span Holocene and pre-historical timescales.     

Calibration of the high-pressure cohesive strength meter (CSM)

Coastal erosion is an immense economic and social problem that has been receiving increased attention in recent years. A number of devices have been developed to determine the sediment stability in coastal areas: laboratory and field flumes; a range of different erosion devices; shear vanes and fall cone penetrometers. The cohesive strength meter (CSM) erosion device was developed to determine in situ the temporal and spatial variations in the erosion threshold of muddy intertidal sediments. Technological developments have enabled considerable improvements to be made to the original design over the last 15 years.     

The gas content and buoyancy of strombolian ash plumes

Plinian plumes erupt with a bulk density greater than that of air, and depend upon air entrainment during their gas-thrust phase to become buoyant; if entrainment is insufficient, the column collapses into a potentially deadly pyroclastic flow. This study shows that strombolian ash plumes can be erupted in an initially buoyant state due to their extremely high initial gas content, and in such cases are thus impervious to column collapse. The high gas content is a consequence of decoupled gas rise in the conduit, in which particles are ultimately incidental. The relations between conduit gas flow, eruption style and plume density are explored here for strombolian scenarios and contrasted with conventional wisdom derived from plinian eruptions. Considering the inherent relation between gas content and initial plume density together with detailed measurements of plume velocities can help unravel ambiguities surrounding conduit processes, eruption styles and hazards at poorly understood volcanoes. Analysis of plume dynamics at Santiaguito volcano, Guatemala adds further support for a model involving decoupled gas rise in the conduit.     

Rheology and geodynamic modelling: the next step forward

The application of continuum mechanics and microstructural analysis to geological studies over the past 30 years has spurred earth scientists to reassess fundamental tectonic processes such as subduction, collision and rifting in terms of dynamics. Armed with new analytical methods, geologists have returned to the field to look at rock structures with more mechanistic eyes. The advent of sophisticated computers, programs, and laboratory deformation equipment has facilitated the simulation of geodynamic processes that range in scale from the grain to the lithosphere. The result has been specialization, with the concomitant opening of communication gaps between geodynamicists, field geologists and rock mechanicists. Partly, these gaps reflect differences of perception and approach. In order to bridge these gaps, a workshop was organized after the DRM conference to debate how field and laboratory studies of deformed rocks can improve our understanding of lithospheric rheology, and in turn, how this understanding can be used to refine dynamic models of orogenesis. The workshop hosted participants with backgrounds in structural geology, experimental rock mechanics, metamorphic petrology and both numerical and analogue modelling. This paper summarizes the main controversies and conclusions reached during the workshop. For the sake of brevity, referencing in this summary is restricted to literature referred to during the oral presentations and to comments made by speakers themselves (names italicized).     

Use of deuterated water as a conservative artificial groundwater tracer

Conservative tracers are necessary to obtain groundwater transport velocities at the field scale. Deuterated water is an effective tracer for this purpose due to its similarity to water, chemical stability, non-reactivity, ease of handling and sampling, relatively neutral buoyancy, and reasonable price. Reliable detection limits of 0.1 mg deuterium/L may be obtained in field tests. A field example is presented in which deuterated water, bromide, and pentafluorobenzoic acid are used as groundwater tracers. Deuterated water appeared to be transported conservatively, producing almost identical breakthrough curves as that of other soluble tracers. Electronic Publication     

Relating experimental and geological rheology

This paper is concerned with the question of how to relate laboratory measurements of the rheology of rocks to the rheological assumptions that need to be made in geodynamic modelling. First, there is a brief resumé of the principal types of rheological behaviour that have been studied in the laboratory, both pressure-dependent, strain rate-independent and pressure-independent, strain-rate-dependent. Then, the generalization of the results from the relatively simple stress states of the experiments to general stress states is discussed, followed by consideration of the extrapolation of the experimental results to geological strains and strain rates. Finally, the problems associated with spatial scale are considered, leading to the question of how to model the rheological behaviour of large-scale rock masses, using the rheological measurements of laboratory specimens and taking into account the heterogeneity of geological-scale rock masses.     

Thermal evolution of the Tertiary Shimanto Belt, Muroto Peninsula, Shikoku, Japan

Abstract The Shimanto accretionary complex on the Muroto Peninsula of Shikoku comprises two major units of Tertiary strata: the Murotohanto Sub-belt (Eocene-Oligocene) and the Nabae Sub-belt (Oligocene-Miocene). Both sub-belts have been affected by thermal overprints following the peak of accretion-related deformation. Palaeotemperatures for the entire Tertiary section range from ～ 140 to 315°C, based upon mean vitrinite reflectance values of 0.9–5.0%R_m. Values of illite crystallinity index are consistent with conditions of advanced diagenesis and anchimetamorphism. Illite/mica b₀ lattice dimensions indicate that burial pressures were probably no greater than 2.5kbar. In general, levels of thermal maturity are higher for the Murotohanto Sub-belt than for the Nabae Sub-belt. The Eocene-Oligocene strata also display a spatial decrease in thermal maturity from south to north and this pattern probably was caused by regional-scale differential uplift following peak heating. Conversely, the palaeothermal structure within the Nabae Sub-belt is fairly uniform, except for the local effects of mafic intrusions at the tip of Cape Muroto. There is a paleotemperature difference of ～ 90°C across the boundary between the Murotohanto and Nabae Sub-belts (Shiina-Narashi fault), and this contrast is consistent with approximately 1200 m of post-metamorphic vertical offset. Subduction prior to Middle Miocene probably involved the Kula or fused Kula-Pacific plate and the background geothermal gradient during the Eocene-Oligocene phase of accretion was ～ 30–35°C/km. Rapid heating of the Shimanto Belt evidently occurred immediately after a Middle Miocene reorganization of the subduction boundary. Hot oceanic lithosphere from the Shikoku Basin first entered the subduction zone at ～ 15 Ma; this event also coincided with the opening of the Sea of Japan and the rapid clockwise rotation of southwest Japan. The background geothermal gradient at that time was ～ 70°C/km. Whether or not all portions of the inherited (Eocene-Oligocene) palaeothermal structure were overprinted during the Middle Miocene remains controversial.     

Groundwater storage change detection from in situ and GRACE-based estimates in major river basins across India

ABSTRACT

India has been the subject of many recent groundwater studies due to the rapid depletion of groundwater in large parts of the country. However, few if any of these studies have examined groundwater storage conditions in all of India’s river basins individually. Herein we assess groundwater storage changes in all 22 of India’s major river basins using in situ data from 3420 observation locations for the period 2003–2014. One-month and 12-month standardized precipitation index measures (SPI-1 and SPI-12) indicate fluctuations in the long-term pattern. The Ganges and Brahmaputra basins experienced long-term decreasing trends in precipitation in both 1961–2014 and the study period, 2003–2014. Indeterminate or increasing precipitation trends occurred in other basins. Satellite-based and in situ groundwater storage time series exhibited similar patterns, with increases in most of the basins. However, diminishing groundwater storage (at rates of >0.4 km³/year) was revealed in the Ganges-Brahmaputra River Basin based on in situ observations, which is particularly important due to its agricultural productivity.     

Isotopic and molecular distributions of biochemicals from fresh and buried <Emphasis Type="Italic">Rhizophora mangle</Emphasis> leaves†

Rhizophora mangle L. (red mangrove) is the dominant species of mangrove in the Americas. At Twin Cays, Belize (BZ) red mangroves are present in a variety of stand structures (tall >5 m in height, transition ~2–4 m and dwarf ~1–1.5 m). These height differences are coupled with very different stable carbon and nitrogen isotopic values[1] (mean tall δ ¹³C = -28.3‰, δ ¹⁵N = 0‰; mean tall δ ¹³C = -25.3‰, δ ¹⁵N = -10‰). To determine the utility of using these distinct isotopic compositions as 'biomarkers' for paleoenvironmental reconstruction of mangrove ecosystems and nutrient availability, we investigated the distribution and isotopic (δ ¹³C and δ ¹⁵N) composition of different biochemical fractions (water soluble compounds, free lipids, acid hydrolysable compounds, individual amino acids, and the residual un-extractable compounds) in fresh and preserved red mangrove leaves from dwarf and tall trees. The distribution of biochemicals are similar in dwarf and tall red mangrove leaves, suggesting that, regardless of stand structure, red mangroves use nutrients for biosynthesis and metabolism in a similar manner. However, the δ ¹³C and δ ¹⁵N of the bulk leaf, the biochemical fractions, and seven amino acids can be used to distinguish dwarf and tall trees at Twin Cays, BZ. The data support the theory that the fractionation of carbon and nitrogen occurs prior to or during uptake in dwarf and tall red mangrove trees. Stable carbon and nitrogen isotopes could, therefore, be powerful tools for predicting levels of nutrient limitation at Twin Cays. The δ ¹³C and δ ¹⁵N of biochemical fractions within preserved leaves, reflect sedimentary cycling and nitrogen immobilization. The δ ¹⁵N of the immobilized fraction reveals the overlying stand structure at the time of leaf deposition. The isotopic composition of preserved mangrove leaves could yield significant information about changes in ecosystem dynamics, nutrient limitation and past stand structure in mangrove paleoecosystems.     

A spatially and temporally adaptive solution of Richards’ equation

Efficient, robust simulation of groundwater flow in the unsaturated zone remains computationally expensive, especially for problems characterized by sharp fronts in both space and time. Standard approaches that employ uniform spatial and temporal discretizations for the numerical solution of these problems lead to inefficient and expensive simulations. In this work, we solve Richards’ equation using adaptive methods in both space and time. Spatial adaption is based upon a coarse grid solve and a gradient error indicator using a fixed-order approximation. Temporal adaption is accomplished using variable order, variable step size approximations based upon the backward difference formulas up to fifth order. Since the advantages of similar adaptive methods in time are now established, we evaluate our method by comparison with a uniform spatial discretization that is adaptive in time for four different one-dimensional test problems. The numerical results demonstrate that the proposed method provides a robust and efficient alternative to standard approaches for simulating variably saturated flow in one spatial dimension.