Bioaccumulation of nitroarenes in bivalves at Osaka Bay, Japan

This paper reports for the first time the detection and occurrence of nitroarenes (NPAHs) in marine organisms. Mussels and oysters collected from Osaka Bay, Japan, had total NPAHs concentrations that ranged from 2380 to 24,688 pg/g dry and 2672 to 25,961 pg/g dry, respectively. Relatively higher concentrations were detected in sampling sites located near the central district and suburbs of Osaka City implying that the most probable sources of NPAHs in the two bivalves are exhaust gases and smokes emitted by automobiles and industrial plants. Bivalves had relatively higher residues of 1-nitronaphthalene, 2-nitronaphthalene, 3-nitrophenanthrene, and 9-nitrophenanthrenes. Residues of 2-nitrofluorene, 1-nitropyrene, 4-nitropyrenes, and 6-nitrochrysene were much lower compared to nitronaphthalenes and nitrophenanthrenes. Inter-species differences was only observed for 2-nitronaphthalene with oysters exhibiting significantly higher residues than mussels.     

Chemistry and Occurrences of Native Tellurium from Epithermal Gold Deposits in Japan

The chemistry and mode of occurrences of native tellurium in the epithermal gold ores from Teine, Kobetsuzawa, Mutsu, Kawazu, Suzaki and Iriki in Japan are examined. Mineral assemblages in contact with native tellurium are: quartz‐sylvanite at Teine, quartz‐hessite‐sylvanite‐tellurantimony at Kobetsuzawa, quartz at Mutsu, quartz‐stutzite‐hessite‐sylvanite‐tetradymite at Kawazu, quartz at Suzaki, and quartz‐goldfieldite at Iriki. The peak patterns of XRD for native tellurium from these six ores are nearly identical to that of JCPDS 4–554. Their chemical compositions of Te range from 98.16 to 100.73 wt.%, showing nearly pure tellurium. Other elements detected are: Se of 0–0.85 and Cu of 0–0.74 at Teine, Sb of 0.45–0.47 and Se of 0.19–0.27 at Kawazu, Se of 0.22–1.11 and Sb of 0–0.49 at Suzaki, and Cu of 0.69–0.98, As of 0.22–0.28 and Bi of 0–0.22 wt.% at Iriki. No other elements are detected in the ores of Kobetsuzawa and Mutsu. The ranges of associated minor compositions are consistent with those of the experimental phase. The differences would be related to associate minerals. The mineral assemblages in these ores agree well with the previously proposed experimental phase relations in Au‐Ag‐Te ternary system for 120–280°C. The Suzaki ore has high Te‐Au assemblage: from calaverite‐sylvanite‐krennerite via native tellurium to petzite, with changing mineralization stage, whereas the Kobetsuzawa and the Kawazu ores have high Te‐Ag assemblage of tellurium‐hessite, and native tellurium‐stutzite‐hessite‐sylvanite, respectively. The Teine ore has intermediate assemblage of native tellurium‐sylvanite. The mineral assemblages in the Au‐Ag‐Te system are related to the hydrothermal environment especially to the pH condition, i.e. Au rich assemblages under acidic and Ag rich assemblages under intermediate pH conditions, being supported by alteration mineral species. The other telluriferous epithermal gold deposits not in association with native tellurium such as Agawa, Date, Takeno, Chugu, Chitose, Sado and Kushikino are estimated to have been formed under higher pH conditions as adularia and calcite occur in these deposits. The pH‐Eh diagram for aqueous tellurium species and tellurium minerals at 250°C indicates that the region of native tellurium occurs between those of aqueous telluride and tellurous species at lower pH, being consistent with their mineral assemblages in ores and alteration envelopes.     

Time-varying sources derived from EUV spectroheliograms of the quiet Sun

Activity in the chromosphere-corona transition region of the quiet Sun is found both at network boundaries and in cell interiors using a time series of the EUV spectroheliograms obtained with the Harvard experiment on Skylab. We identify time-varying sources by subtracting the minimum count at each pixel in the time series from the counts at any time. Larger flux enhancements in emission lines occur only at the network boundary, though the cell interiors also have variable intensities. Time-varying sources in the cell interior appear often in the shape of streaks which seem to originate from sources at the network boundary, or as expanding network boundary sources. It is likely that the sources in the cell interior come from the transition sheaths of chromospheric inhomogenities. A multi-temperature analysis shows that two types of sources occur in the quiet Sun. One is due to heating of cool chromospheric inhomogenities like dark mottles. Sometimes cool matter is heated to coronal temperatures. The typical mass of the coronal material produced is 10¹¹-10¹²g. The other type seems to be due to draining of transition region material at the network boundary as the result of thermal instabilities. This quiet Sun activity is compatible with the time-varying sources at 6 cm wavelength.     

Heat flux estimate of warm water flow in a low-temperature diffuse flow site, southern East Pacific Rise 17°25′ S

A low-temperature diffuse flow site associated with abundant vent fauna was found by submersible observations on the southern East Pacific Rise at 17°25′ S in 1997. This site was characterized by thin sediment covered pillow and sheet lavas with collapsed pits up to ∼15 m in diameter. There were three warm water vents (temperature: 6.5 to 10.5 °C) within the site above which the vented fluids rise as plumes. To estimate heat flux of the warm water vents, a temperature logger array was deployed and the vertical temperature distribution in the water column up to 38 m above the seafloor was monitored. A stationary deep seafloor observatory system was also deployed to monitor hydrothermal activity in this site. The temperature logger array measured temperature anomalies, while the plumes from the vents passed through the array. Because the temperature anomalies were measured in only specific current directions, we identified one of the vents as the source. Heat flux from the vent was estimated by applying a plume model in crossflow in a density-stratified environment. The average heat flux from September 13 to October 18, 1997 was 39 MW. This heat flux is as same order as those of high-temperature black smokers, indicating that a large volume flux was discharged from the vent (1.9 m³/s). Previous observations found many similar warm water flow vents along the spreading axis between 17°20′ S–30′ S. The total heat flux was estimated to be at least a few hundred mega-watts. This venting style would contribute to form effluent hydrothermal plumes extended above the spreading axis.     

Growth inhibition of a red tide flagellate,Chattonella antiqua by copper

Journal of Oceanography - Copper toxicity inChattonella antiqua (Raphidophyceae) was examined using an artificial seawater medium. The growth rate (Μ) was found to be a unique function of...     

Mixed layer depth front and subduction of low potential vorticity water in an idealized ocean GCM

It is known that there is a front-like structure at the mixed layer depth (MLD) distribution in the subtropical gyre, which is called the MLD front, and is associated with the formation region of mode water. In the present article, the generation mechanism of the MLD front is studied using an idealized ocean general circulation model with no seasonal forcing. First, it is shown that the MLD front occurs along a curve where u _g ·∇T _s = 0 is satisfied (u _g is the upper ocean geostrophic velocity vector, T _s is the sea surface temperature and ∇ is the horizontal gradient operator). In other words, the front is the boundary between the subduction region (u _g ·∇T _s > 0) and the region where subduction does not occur (u _g ·∇T _s < 0). Second, we have investigated subduction of low potential vorticity water at the MLD front, which has been pointed out by past studies. Since u _g ·∇T _s = 0 at the MLD front, the water particles do not cross the outcrop at the MLD front. The water that is subducted at the MLD front has come from the deep mixed layer region where the sea surface temperature is higher than that at the MLD front. The temperature of the water in the deep mixed layer region decreases as it is advected eastward, attains its minimum at the MLD front where u _g ·∇T _s = 0, and then subducts under the warmer surface layer. Since the deep mixed layer water subducts beneath a thin stratified surface layer, maintaining its thickness, the mixed layer depth changes abruptly at the subduction location.     

Wavelength-dependence of EUV continuum absorption

The weakening of EUV line emission due to continuum absorptions of neutral hydrogen and neutral helium is investigated to examine its wavelength-dependence. After convolving the intensities predicted from multilevel calculations over an instrumental profile, we found a systematic, linear weakening for lines shortward of 912 Å, which can be attributed to Lyman continuum absorption in the cool chromospheric cloud. The degree of the weakening at the quiet Sun seems to be constant in the temperature range of 4.3 < log T < 5.4. We also find that the lines shortward of 504 Å are somewhat weakened by He i continuum absorption. From the comparison of both weakenings the temperature of the absorber is estimated to be rather low (T _e 7 × 10³ K).     

Further evaluation of the Sim-ReSET model for ET estimation driven by only satellite inputs

Abstract

A simple remote sensing evapotranspiration (ET) model (Sim-ReSET) has been proposed but only tested using field measurements at a site with a semi-arid climate. Its performance for mapping ET using only satellite data remained unknown. In this study, the Sim-ReSET model was further evaluated for ET estimation driven by only MODIS data products. The estimated ET rates were compared with ground-based observational data from a variety of ecosystems and climates across China. The results show that MODIS-based ET estimates are consistent with both the ET measurements from eddy covariance flux towers and those from the Penman-Monteith method combined with micrometeorological data. Evaporation fraction (EF) is indicative of land surface moisture. The derivative EF maps demonstrate that the proposed ET data set obtained from the Sim-ReSET model and MODIS data is capable of capturing the spatio-temporal pattern of land surface moisture for different land covers with different climates.

Editor Z.W. Kundzewicz

Citation Sun, Z.G., Wang, Q.X., Matsushita, B., Fukushima, T., Ouyang, Z., Watanabe, M., and Gebremichael, M., 2013. Further evaluation of the Sim-ReSET model for ET estimation driven by only satellite inputs. Hydrological Sciences Journal, 58 (5), 994–1012.     

Generation of greenhouse effect gases from different landfill types

Recently much attention is focussed on the problems of global warming due to greenhouse effect gases, notably carbon dioxide and methane. Because these gases cause important problems to the global environment, their generation from landfill sites containing solid wastes has drawn attention and their environmental impact is causing concern.

Generally, the gases associated with a greenhouse effect include carbon dioxide, methane and nitrous oxide. However, there are no general basic data available concerning gases generated from biodegradation of solid wastes in landfill sites. Specifically, no assessment has been made concerning greenhouse effect gases from different landfill types.

This paper proposes a quantitative model for estimating the gasification rate by different landfill types. The model is based on measurement data for a long-term material balance for an aerobic landfill and an anaerobic landfill, obtained with two types of large-scale lysimeters.

This paper will also give an estimate for the amount of greenhouse effect gases by for different types of landfill and propose countermeasures for their reduction.