Metamorphic record of the Asemi‐gawa eclogite unit in the Sanbagawa belt,southwest Japan: Constraints from inclusions study in garnet porphyroblasts

The Sanbagawa belt is one of the famous subduction‐related high‐pressure (HP) metamorphic belts in the world. However, spatial distributions of eclogite units in the belt have not yet satisfactorily established, except within the Besshi region, central Shikoku, southwest Japan because most eclogitic rocks were affected by lower pressure overprinting during exhumation. In order to better determine the areal distribution of the eclogite units and their metamorphic features, inclusion petrography of garnet porphyroblasts using a combination of electron probe microanalyser and Raman spectroscopy was applied to pelitic and mafic schists from the Asemi‐gawa region, central Shikoku. All pelitic schist samples are highly retrogressed, and include no index HP minerals such as jadeite, omphacite, paragonite, or glaucophane in the matrix. Garnet porphyroblasts in pelitic schists occur as subhedral or anhedral crystals, and show compositional zoning with irregular‐shaped inner segments and overgrown outer segments, the boundary of which is marked by discontinuous changes in spessartine. This feature suggests that a resorption process of the inner segment occurred prior to the formation of the outer segment, indicating discontinuous crystallization between the two segments. The inner segment of some composite‐zoned garnet grains displays Mn oscillations, implying infiltration of metamorphic fluid during the initial exhumation stage. Evidence for an early eclogite facies event was determined from mineral inclusions (e.g., jadeite, paragonite, glaucophane) in the garnet inner segments. Mafic schists include no index HP minerals in the matrix as with pelitic schists. Garnet grains in mafic schists show simple normal zoning, recording no discontinuous growth during crystal formation. There are no index HP mineral inclusions in the garnet, and thus no evidence suggesting eclogite facies conditions. Quartz inclusions in garnet of the pelitic and mafic schists show residual pressure values (?ω₁) of >8.5 cm^?1 and <8.5 cm^?1 respectively. The combination of Raman geobarometry and conventional thermodynamic calculations gives peak P–T conditions of 1.6–2.1 GPa at 460–520°C for the pelitic schists. The ?ω₁ values of quartz inclusions in mafic schists are converted to a metamorphic pressure of 1.2–1.4 GPa at 466–549°C based on Raman geothermometry results. These results indicate that a pressure gap definitely exists between the mafic schists and the almost adjacent pelitic schists, which have experienced a different metamorphic history. Furthermore, the peak P–T values of the Asemi‐gawa eclogite unit are compatible with those of Sanbagawa eclogite unit in the Besshi region of central Shikoku, suggesting that these eclogite units share a similar P–T trajectory. The Asemi‐gawa eclogite unit exists in a limited area and is composed of mostly pelitic schists. We infer that these abundant pelitic schists played a key role in buoyancy‐driven exhumation by reducing bulk rock density and strength.     

An Important Ornithischian Tracksite in the Early Jurassic of the Shenmu Region,Shaanxi, China

A large track site with multiple,well-preserved trackways of an Early Jurassic quadrupedal ornithischian dinosaur is the first report of Moyenisauripus-like trackways from Asia,herein named Shenmuichnu...     

The Upper Jurassic–Lower Cretaceous of eastern Heilongjiang, northeast China: stratigraphy and regional basin history

In eastern Heilongjiang, the Upper Jurassic is marine and restricted to the Suibin and Dong’an areas, where it is characterized faunally by Callovian–Volgian (Tithonian) bivalves and florally by dinoflagellates. The Lower Cretaceous is widely distributed in eastern Heilongjiang, and characterized faunally by Berriasian–Valanginian bivalves, Barremian–Albian ammonites and Aucellina, and florally by dinoflagellates. To the west, the marine facies grade into non-marine beds. Thus, in the east, for example in the Dong’an and Dajiashan areas, near the northwestern Palaeo-Pacific, the Lower Cretaceous is marine; westward, in the Yunshan, Longzhaogou, Peide, and Zhushan areas, marine and non-marine deposits alternate, whereas further west still, e.g. in the Jixi Basin, non-marine facies are intercalated with marine beds. This regional distribution is indicative of a large, shallow embayment opening eastwards to the Palaeo-Pacific; during the Early Cretaceous successive transgressive-regressive events influenced the climate and biota of eastern Heilongjiang and northeastern China. Many of the Lower Cretaceous sections contain abundant coals, demonstrating that in this region the Early Cretaceous was an important coal-forming period. Some non-marine bivalve species are common to the Lower Cretaceous Jixi Group of eastern Heilongjiang, the Jehol Group of western Liaoning and the Transbaikalian Group of Siberia, suggesting that these groups are of comparable Early Cretaceous age.     

Calorimetric study of the stability of spinelloids in the system NiAl2O4-Ni2SiO4

Enthalpies of solution in molten 2 PbO · B₂O₃ at 974 K were measured for four spinelloids, phases I (0.75 NiAl₂O₄ · 0.25 Ni₂SiO₄), II (0.60 NiAl₂O₄ · 0.40 Ni₂SiO₄), III and IV (0.50 NiAl₂O₄ · 0.50 Ni₂SiO₄) in the system NiAl₂O₄ · Ni₂SiO₄. The enthalpies (in cal per 4-oxygen mol) of formation from NiAl₂O₄ and Ni₂SiO₄ spinels are: phase I, 945±366; phase II, 1072±360; phase III, 2253±390; phase IV, 3565±544. Using these enthalpy data in combination with phase relations at high pressure at 1373 K, positive entropies of formation of the spinelloids from NiAl₂O₄ and Ni₂SiO₄ spinels were estimated (in cal mol^?1 K^?1): phase I, 1.2; phase II, 1.5; phase III, 2.0–2.3; phase IV, 3.0–3.1. The thermochemical data obtained above suggest that the spinelloids are “entropy-stabilized” phases with partially disordered cation distributions. The configurational entropies of the spinelloids were calculated based on the observed cation distribution in each spinelloid phase. The positive entropies of formation of the spinelloids from the spinel endmembers are due primarily to the configurational entropies although small positive vibrational entropy changes may also exist.     

Temporal variations in the abundance and sinking flux of diatoms under fast ice in summer near Syowa Station, East Antarctica

To investigate the fate of ice algae released from sea ice, we investigated the abundance, species composition, and sinking flux of diatoms in the water column under fast ice near Syowa Station, Antarctica during the summer of 2005/2006. The diatom assemblage in the water column consisted of chain-forming planktonic species, in contrast to the under-ice assemblage dominated by pennate species reported from this site in the past; this dissimilarity suggests the presence of an unconsolidated platelet ice layer under the congelation ice, within which planktonic species can bloom. Among the dominant diatoms, Porosira pseudodenticulata and Pseudo-nitzschia cf. turgiduloides were dominant in the water column, and their water column stocks were higher than their mass sedimentation. These species apparently maintain their populations in the surface layer, as their production remains in the water column. In contrast, Fragilariopsis kerguelensis and Thalassiosira australis were scarce in the water column but rich in the flux, indicating active sinking and export of their production to the benthic ecosystem. This distinction in buoyancy control and sinking characteristics of the dominant diatoms on release from the fast ice influences the diatom species composition and carbon flow under the ice.     

Characteristics of variations of water properties and density structure around the Kuroshio in the East China Sea

Quarterly data of CTD at the PN line in the East China Sea during 1988–94 were analyzed to examine the variations of water properties and density structure in relation to the Kuroshio. The Kuroshio flows over the continental slope at the PN line. Water properties in the surface layer less than 100 db change greatly and show a clear seasonal cycle, while those in the subsurface layer are much less variable. The small isobaric variations in the subsurface layer are almost due to the vertical movement of isopycnals, on which the water properties vary little. The subsurface variations of salinity, temperature and isopycnal depth are classified into four groups occurring in the four regions, divided vertically by the middle of the main pycnocline and horizontally by the offshore edge of the Kuroshio, named Groups 1 (upper Kuroshio), 2 (upper offshore region), 3 (lower Kuroshio), and 4 (lower offshore region). The difference in averaged isopycnal depth between Groups 1 and 2 (3 and 4) is highly correlated with the vertical shear of the Kuroshio velocity in the upper (lower) pycnocline. The isopycnal depth of Groups 1 and 3 has little annual cycle (with large intraseasonal variations in Group 3), while that of Groups 2 and 4 shows a clear seasonal variation with the minimum in fall. As a result, the Kuroshio velocity is smallest in fall almost every year, although the amplitude of seasonal variation and the season of maximum velocity are different from year to year. Interannual variations of isopycnal depth are characterized by a large amplitude of Group 2 and an opposite phase between Groups 3 and 4, so that the variations of difference in isopycnal depth between Groups 1 and 2 and Groups 3 and 4, i.e., the upper and lower shear of the Kuroshio velocity, are comparably significant.     

Spectral properties of sea level and time scales of Kuroshio path variations

Spectral properties of sea levels at Naze, Nishinoomote, Kushimoto, Uragami, Miyake-jima and HachijÔ-jima are examined for the non-large-meander (February 1964 – May 1975) and large-meander (October 1975 – December 1979) periods, and the periodicity of variation of the Kuroshio path is clarified.The large meander of the Kuroshio occurs with a primary period of about 20 years and secondary period of 7 to 8. 5 years. During the non-large-meander period, the Kuroshio alternately takes the nearshore and offshore non-large-meander paths with a primary period of 1. 6–1. 8 years. This variation is moreover composed of 110-day, around 195-day and annual periods. The 110-day variation of the Kuroshio path appears to have influence on the coastal sea levels between the Kii Peninsula and the Izu Ridge;i. e., the coastal sea levels rise and fall with one-month time lag after the Kuroshio has begun to approach and leave the Japanese coast. During the large-meander period, the 70 and 110-day variations are remarkable in sea levels south of Japan except Miyake-jima and HachijÔ-jima. The 70-day variation is highly coherent throughout the south coast of Japan; the coherent area of the 110-day variation seems to be smaller.The sea-level variations at Naze and Nishinoomote are not significantly coherent for any of the periods except for annual and semiannual cycles during both the non-large-meander and large-meander periods. That is, the sea-level variations are incoherent between the onshore and offshore sides of the Kuroshio, except for seasonal variation.