High-pressure phase relations in the system TiO2–ZrO2 to 12?GPa: stability of αPbO2-type srilankite solid solutions of (Ti1?x , Zr x )O2 (0?≤?x?≤?0.6)

Phase relations in the system TiO₂–ZrO₂ were examined in the pressure range of 3.5–12?GPa at 1,800?°C, using multianvil apparatus. At 1,800?°C, TiO₂ rutile transforms to αPbO₂ structure at 10?GPa, and the αPbO₂-type solid solution is stable in compositional range between TiO₂ and about (Ti_0.6, Zr_0.4)O₂ at 3.5–12?GPa. Combination of the present results with the published data at 0–3?GPa demonstrates that continuous solid solution with the αPbO₂-type structure is stable between TiO₂ and (Ti_1?x , Zr _x )O₂ (x?≈?0.6) at 0–12?GPa. This indicates that both the αPbO₂-type TiO₂ and srilankite Ti₂ZrO₆ with the same structure belong to the continuous solid solution system though the two phases have been regarded as different minerals. With increasing ZrO₂ content, lattice parameters of a- and c-axes of the αPbO₂-type solid solution increase, but b-axis is almost constant or slightly decreases. At higher pressure, the αPbO₂-type solid solution dissociates into two phases, αPbO₂-type phase and tetragonal zirconia. Srilankite with more TiO₂-rich composition than Ti₂ZrO₆ might be found in natural rocks derived from the deep upper mantle.     

Desorption kinetics of hydrophobic organic contaminants from marine plastic pellets

This study investigated the desorption behavior of polychlorinated biphenyls (PCBs) from marine plastic pellets. Long-term desorption experiments were conducted using field-collected polyethylene (PE) pellets. The results indicate that the desorption kinetics highly depends on the PE-water partition coefficients of PCB congeners. After 128 d of the experiment, the smallest congener considered (CB 8) had desorbed nearly completely (98%), whereas major fractions (90–99%) of highly chlorinated congeners remained in the pellets. An intraparticle diffusion model mostly failed to reproduce the desorption kinetics, whereas an aqueous boundary layer (ABL) diffusion model well approximated the data. The desorption half-lives are estimated to 14 d to 210 years for CB 8 to CB 209 in an actively stirred solution (ABL thickness: 30 μm). Addition of methanol to water enhanced the desorption to a large extent. A need for further work to explore roles of organic matter in facilitating solute transfer is suggested.     

Infiltration and solute transport under a seasonal wetland: bromide tracer experiments in Saskatoon,Canada

In the northern glaciated plain of North America, the duration of surface water in seasonal wetlands is strongly influenced by the rate of infiltration and evaporation. Infiltration also plays important roles in nutrient exchange at the sediment–water interface and groundwater recharge under wetlands. A whole‐wetland bromide tracer experiment was conducted in Saskatchewan, Canada to evaluate infiltration and solute transport processes. Bromide concentrations of surface water, groundwater, sediment pore water and plant tissues were monitored as the pond water‐level gradually dropped until there was no surface water. Hydraulic head gradients showed strong lateral flow from under the wetland to the treed riparian zone during the growing season. The bromide mass balance analysis showed that in early spring, almost 50% of water loss from the wetland was by infiltration, and it increased to about 70% in summer as plants in and around the wetland started to transpire more actively. The infiltration contributed to recharging the shallow, local groundwater under the wetland, but much of it was taken up by trees without recharging the deeper groundwater system. Emergent plants growing in the wetlands incorporated some bromide, but overall uptake of bromide by vegetation was less than 10% of the amount initially released. After one summer, most of the subsurface bromide was found within 40–80 cm of the soil surface. However, some bromide penetrated as deep as 2–3 m, presumably owing to preferential flow pathways provided by root holes or fractures. Copyright © 2004 Crown in the Right of Canada. Published by John Wiley & Sons, Ltd.     

Global scale evaluation of coastal fresh groundwater resources

This paper presents a simplified approach to assess the effects of global warming on global coastal groundwater resources over the next century based on the smallest but necessary number of elements such as rainfall, temperature, hydraulic conductivity of the aquifers, and population changes regarding the consumption of groundwater. The positive aspect in this approach is that there is availability of the above elements in the majority of the planet. Methodology includes a sharp interface concept model and simplified estimation of groundwater recharge using limited climate data. The evaluation shows that the future climate changes would decrease fresh groundwater resources in Central American, South American, South African and Australian regions whereas most of the areas in Asia, except South-East Asia. Combinations of fresh groundwater loss and global population are considered to state the vulnerability of future fresh groundwater supply. Vulnerability assessment shows that South Asia, Central America, North Africa and the Sahara, South Africa and the Middle East countries are highly vulnerable whereas, Northern Europe, Western part of South America, New Zealand and Japan are less vulnerable with respect to future fresh groundwater supply. Further, this paper highlights the necessity Integrated Coastal Management (ICM) practices in these vulnerable coastal regions to ensure the sustainable development in coastal regions.     

Large‐scale erosion and overbank deposition caused by the July 2013 flood of the Abu River,Yamaguchi City,Japan

This paper reports on the erosion, transport, and deposition processes associated with an overbank deposit formed by the flooding of the Abu River on July 28, 2013, in Yamaguchi City, Japan. At the study site, river flows overtopped the levee revetment upstream of a meander bend cutting it off and flowing back into the main channel downstream. In this sequential process, it deposited large amounts of sediments, ranging from mud to cobbles, on the floodplain. The surface of paddy fields adjacent to a railway line, located at the center of the affected floodplain, was severely eroded by the flood flows. Overbank deposits composed of both upstream finer sediments and eroded coarser terrestrial sediments are laid down in the affected area. Large amounts of pebbles and cobbles originating from the eroded terrestrial area formed a gravelly pile on top of the sand and gravel sediments derived from the river. This finding indicates that sands and gravels were deposited prior to the formation of the gravelly pile, probably before and during peak flood flows. An inverse grading structure is evident in the lower to middle part of these comparatively thick deposits, most likely due to differences in transport pattern between entrained terrestrial gravels and upstream finer sediments.     

Water masses and decadal variability in the East Sea (Sea of Japan)

Water masses in the East Sea are newly defined based upon vertical structure and analysis of CTD data collected in 1993–1999 during Circulation Research of the East Asian Marginal Seas (CREAMS). A distinct salinity minimum layer was found at 1500 m for the first time in the East Sea, which divides the East Sea Central Water (ESCW) above the minimum layer and the East Sea Deep Water (ESDW) below the minimum layer. ESCW is characterized by a tight temperature–salinity relationship in the temperature range of 0.6–0.12 °C, occupying 400–1500 m. It is also high in dissolved oxygen, which has been increasing since 1969, unlike the decrease in the ESDW and East Sea Bottom Water (ESBW). In the eastern Japan Basin a new water with high salinity in the temperature range of 1–5 °C was found in the upper layer and named the High Salinity Intermediate Water (HSIW). The origin of the East Sea Intermediate Water (ESIW), whose characteristics were found near the Korea Strait in the southwestern part of the East Sea in 1981 [Kim, K., & Chung, J. Y. (1984) On the salinity-minimum and dissolved oxygen-maximum layer in the East Sea (Sea of Japan), In T. Ichiye (Ed.), Ocean Hydrodynamics of the Japan and East China Seas (pp. 55–65). Amsterdam: Elsevier Science Publishers], is traced by its low salinity and high dissolved oxygen in the western Japan Basin. CTD data collected in winters of 1995–1999 confirmed that the HSIW and ESIW are formed locally in the Eastern and Western Japan Basin. CREAMS CTD data reveal that overall structure and characteristics of water masses in the East Sea are as complicated as those of the open oceans, where minute variations of salinity in deep waters are carefully magnified to the limit of CTD resolution. Since the 1960s water mass characteristics in the East Sea have changed, as bottom water formation has stopped or slowed down and production of the ESCW has increased recently.     

Continental basalts in the accretionary complexes of the South-west Japan Arc: Constraints from geochemical and Sr and Nd isotopic data of metadiabase

Abstract The Ryoke Belt is one of the important terranes in the South‐west Japan Arc (SJA). It consists mainly of late Cretaceous granitoid rocks, meta‐sedimentary rocks (Jurassic accretionary complexes) and mafic rocks (gabbros, metadiabases; late Permian–early Jurassic). Initial ?_Sr (+ 25– + 59) and ?_Nd (? 2.1–?5.9) values of the metadiabases cannot be explained by crustal contamination but reflect the values of the source material. These values coincide with those of island arc basalt (IAB), active continental margin basalt (ACMB) and continental flood basalt (CFB). Spiderdiagrams and trace element chemistries of the metadiabases have CFB‐signature, rather than those of either IAB or ACMB. The Sr–Nd isotope data, trace element and rare earth element chemistries of the metadiabases indicate that they result from partial melting of continental‐type lithospheric mantle. Mafic granulite xenoliths in middle Miocene volcanic rocks distributed throughout the Ryoke Belt were probably derived from relatively deep crust. Their geochemical and Sr–Nd isotopic characteristics are similar to the metadiabases. This suggests that rocks, equivalent geochemically to the metadiabases, must be widely distributed at relatively deep crustal levels beneath a part of the Ryoke Belt. The geochemical and isotopic features of the metadiabases and mafic granulites from the Ryoke Belt are quite different from those of mafic rocks from other terranes in the SJA. These results imply that the Ryoke mafic rocks (metadiabase, mafic granulite) were not transported from other terranes by crustal movement but formed in situ. Sr–Nd isotopic features of late Cretaceous granitoid rocks occurring in the western part of the Japanese Islands are coincident with those of the Ryoke mafic rocks. Such an isotopic relation between these two rocks suggests that a continental‐type lithosphere is widely represented beneath the western part of the Japanese Islands.     

Geochronological characterization and petrogenesis of granitoids in the Ryoke belt, Southwest Japan Arc: constraints from K–Ar, Rb–Sr and Sm-Nd systematics

Abstract Rb–Sr and K–Ar chronological studies were carried out on granitic and metamorphic rocks in the Ina, Awaji Island and eastern Sanuki districts, Southwest Japan to investigate the timing of intrusion of the granitoids in the Ryoke belt. Intrusions of 'younger' Ryoke granitic magmas took place in the Ina district between 120 Ma and 70 Ma, and cooling began immediately after the emplacement of the youngest granitic bodies. Igneous activity in Awaji Island was initiated at 100 Ma and continued to 75 Ma. Along-arc variations of Rb–Sr whole-rock isochron ages suggest that magmatism began everywhere in the Ryoke and San-yo belts at almost the same time ( ca 120 Ma). The last magmatism took place in the eastern part of both belts. Rb–Sr and K–Ar mineral ages for the granitoids young eastwards. The age data suggest that the Ryoke belt was uplifted just after the termination of igneous activity. Initial Sr and Nd isotopic ratios for the Ryoke granitoids indicate that most were derived from magmas produced in the lower crust and/or upper mantle with uniform Sr and Nd isotopic compositions. Several granitoids, however, exhibit evidence of assimilation of Ryoke metamorphic rocks or older Precambrian crustal rocks beneath the Ryoke belt.     

High-pressure phase transitions of CaRhO<Subscript>3</Subscript> perovskite

High-pressure phase transitions of CaRhO₃ perovskite were examined at pressures of 6–27 GPa and temperatures of 1,000–1,930°C, using a multi-anvil apparatus. The results indicate that CaRhO₃ perovskite successively transforms to two new high-pressure phases with increasing pressure. Rietveld analysis of powder X-ray diffraction data indicated that, in the two new phases, the phase stable at higher pressure possesses the CaIrO₃-type post-perovskite structure (space group Cmcm) with lattice parameters: a = 3.1013(1) Å, b = 9.8555(2) Å, c = 7.2643(1) Å, V _m  = 33.43(1) cm³/mol. The Rietveld analysis also indicated that CaRhO₃ perovskite has the GdFeO₃-type structure (space group Pnma) with lattice parameters: a = 5.5631(1) Å, b = 7.6308(1) Å, c = 5.3267(1) Å, V _m  = 34.04(1) cm³/mol. The third phase stable in the intermediate P, T conditions between perovskite and post-perovskite has monoclinic symmetry with the cell parameters: a = 12.490(3) Å, b = 3.1233(3) Å, c = 8.8630(7) Å, β = 103.96(1)°, V _m  = 33.66(1) cm³/mol (Z = 6). Molar volume changes from perovskite to the intermediate phase and from the intermediate phase to post-perovskite are –1.1 and –0.7%, respectively. The equilibrium phase relations determined indicate that the boundary slopes are large positive values: 29 ± 2 MPa/K for the perovskite—intermediate phase transition and 62 ± 6 MPa/K for the intermediate phase—post-perovskite transition. The structural features of the CaRhO₃ intermediate phase suggest that the phase has edge-sharing RhO₆ octahedra and may have an intermediate structure between perovskite and post-perovskite.     

An unusual theropod track assemblage from the Cretaceous of the Zhucheng area, Shandong Province, China

More than 125 footprints of theropods from the Cretaceous Longwangzhuang Formation have been mapped in a preliminary study at a site in the Zhucheng region of China. The tracks represent at least three morphotypes. The largest morphotype is a large theropod (footprint length ∼30 cm) represented by a single trackway and an isolated natural cast. At least 10 trackways assigned to the new ichnospecies Corpulentapus lilasia represent a medium-sized biped (footprint length ∼13 cm) with very short, wide, robust, ‘tulip-shaped’ tracks and long steps (∼5 × footprint length), and a short central digit (III) indicating weak mesaxony. Corpulentapus trackways are narrow and theropod-like even though track morphology is convergent with the footprints of some ornithopods. The third morphotype, made by a medium-sized grallatorid track maker (ichnogenus Paragrallator), is about the same size (∼13 cm) as the robust morphotype, but far more elongate and gracile, with an elongate central digit (III) indicating strong mesaxony. This ichnotaxon requires detailed comparison with Grallator sensu stricto. The contrast in morphology between the two common morphotypes is striking and demonstrates that two distinct medium-sized taxa of presumed theropod affinity frequented the same habitat in significant numbers.