On the limits of using combined U-series/ESR method to date fossil teeth from two Early Pleistocene archaeological sites of the Orce area (Guadix-Baza basin,Spain)

The combined U-series/electron spin resonance (ESR) dating method was applied to nine teeth from two Early Pleistocene archaeological sites located in the Orce area (Guadix-Baza Basin, Southern Spain): Fuente Nueva-3 (FN-3) and Barranco León (BL). The combination of biostratigraphy and magnetostratigraphy places both sites between the Olduvai and Jaramillo subchrons (1.78–1.07 Ma).Our results highlight the difficulty of dating such old sites and point out the limits of the combined U-series/ESR dating method based on the US model. We identified several sources of uncertainties that may lead to inaccurate age estimates. Seven samples could not be dated because the dental tissues had (²³⁰Th/²³⁴U) activity ratios higher than equilibrium, indicating that uranium had probably leached from these tissues. It was however possible to calculate numerical estimates for two of the teeth, both from FN-3. One yielded a Middle Pleistocene age that seems to be strongly underestimated; the other provided an age of 1.19 ± 0.21 Ma, in agreement with data obtained from independent methods. The latter result gives encouragement that there are samples that can be used for routine dating of old sites.     

Database extension for digital soil mapping using artificial neural networks

Cost and time are the two most important factors conditioning soil surveys. Since these surveys provide basic information for modelling and management activities, new methods are needed to speed the soil-mapping process with limited input data. In this study, the polypedon concept was used to extend the spatial representation of sampled pedons (point data) in order to train artificial neural networks (ANNs) for digital soil mapping (DSM). The input database contained 97 soil profiles belonging to 7 different soil series and 15 digital elevation model (DEM) attributes. Pedons were represented in raster format as one-cell areas. The corresponding polypedons were then spatially represented by neighbouring raster cells (e.g. 2 × 2, … up to 6 × 6 cells). The primary database contained 97 pedons (97 cells) that were extended up to 3492 cells (in the case of 6 × 6-cell regions). This approach employed test and validation areas to calculate the respective accuracies of data interpolation and extrapolation. The results showed increased accuracies in training and interpolation (test area) but a poor level of accuracy in the extrapolation process (validation area). However, the overall precision of all predictions increased considerably. Using only topographic attributes for extrapolation was not sufficient to obtain an accurate soil map. To improve prediction, other soil-forming factors, such as landforms and/or geology, should also be considered as input data in the ANN. The proposed method could help to improve existing soil maps by using DSM results in areas with limited soil data and to save time and money in soil survey work.     

Geochemical modeling and low-frequency geoelectrical methods to evaluate the impact of an open dump in arid and deltaic environments

In Mexico, open dumps that are maintained by the municipality but provide no covering of waste are not uncommon. Further, disposal at these sites is often performed by burning. The aim of this study was to determine the leachate plume from an open dump located in a depositional deltaic environment, with arid climate, low rainfall and where the water table is about 2 m below the surface. The methodology comprised analysis of groundwater monitoring wells and geophysical and geochemical prospecting techniques. The 3D geoelectric interpretation shows a typical area of these depositional environments with low resistive values (10–20 Ω-m) associated with the presence of sands and clays interbedded. However, there is a very low resistivity zone associated with the dump’s impact which reaches values below 5 Ω-m, and it is located where the disposal and burning of wastes occurred. Another zone with values above 16 Ω-m appears as a limit for the advance of the saline. This is interpreted as a sandy lenses area. These sandy lenses with higher porosity transport aquifer’s water. Thus the dump is in direct contact by this conduct with clean groundwater. Piper diagrams constructed with the chemical data analysis reveal that the groundwater in the area corresponds to the chlorinated and/or sulfated sodium type, showing the impact caused by the dump. The monitoring well (NP8, on-site) with the highest dissolved solids content behaves anomalously and belongs to the more conductive zone according to the geoelectric profiles. The subsoil geochemical behavior is influenced by the seasonal water table variations provoking the dissolution of burned and unburned wastes, but the effects of slow flows in the direction of the regional flow are not discarded. Although the most impacted area within the dump is characterized to a depth of 10 m, there is a slow flow in the direction of the regional flow that has been moving pollutants out of the dumpsite during its almost 20 years of operation. The results of this study provide valuable information for the authorities to carry out an appropriate restoration project.     

Growth of accretionary wedges and pulsed ophiolitic mélange formation by successive subduction of trench‐parallel volcanic elevations

Fault‐bounded coherent belts alternating with belts of mélanges are common in accretionary wedges and are usually interpreted as a result of imbrication along subduction zone megathrusts. Using the Neoproterozoic/early Cambrian Blovice accretionary complex (BAC), Bohemian Massif, as a case example, we present a new model for the origin of alternating belts through the repetition of several cycles of (1) offscraping and deformation of trench‐fill sediments to form the coherent units, interrupted by (2) arrival and subduction of linear, trench‐parallel volcanic elevations. The latter process leads to an increase in the wedge taper, triggering mass‐wasting and formation of olistostromes. At the same time, ophiolitic mélanges form by disruption of an upper part of the volcanic ridge and incorporation of the disrupted ocean‐floor succession into the olistostromes. Specifically, the BAC represents a complete section across an accretionary wedge and records three such major pulses of ophiolitic mélange formation through subduction of an outboard back‐arc basin.     

Influence of hydraulic retention time on heterotrophic biomass in a wastewater moving bed membrane bioreactor treatment plant

Wastewater treatment using moving bed membrane bioreactor technology was tested with real urban wastewater at a pilot plant, combining moving bed treatment as a biological process with hybrid biomass (suspended and fixed) and the advantages of a membrane separation system. The evolution of the kinetic constants of the hybrid biomass and organic matter removal were studied in a pilot plant under different operational conditions, by varying hydraulic retention time (HRT), mixed liquor suspended solids (MLSS) and temperature, and considering the attached biomass of the carrier and the dispersed biomass of the flocs to reproduce real treatment conditions. The rates of organic matter removal were 97.73 ± 0.81 % of biochemical oxygen demand (BOD₅), 93.44 ± 2.13 % of chemical oxygen demand (COD), 94.41 ± 2.26 % of BOD₅ and 87.62 ± 2.47 % of COD using 24.00 ± 0.39 and 10.00 ± 0.07 h of HRT, respectively. The influence of the environmental variables and operational conditions on kinetic constants was studied; it was determined that the most influential variable for the decay coefficient for heterotrophic biomass was HRT (0.34 ± 0.14 and 0.31 ± 0.10 days^?1 with 10.00 ± 0.07 and 24.00 ± 0.39 h of HRT, respectively), while for heterotrophic biomass yield, this was temperature (0.61 ± 0.04 and 0.52 ± 0.06 with 10.00 ± 0.07 and 24.00 ± 0.39 h of HRT, respectively). The results show that introducing carriers in an MBR system provides similar results for organic matter removal, but with a lower concentration of MLSS.     

Hydrogeochemistry and isotope techniques to determine water interactions in groundwater-dependent shallow lakes,Wet Pampa Plain,Argentina

This paper gives an account of the implementation of hydrochemical and isotopic techniques to identify and explain the processes that govern solute exchange in two groundwater-dependent shallow lakes in the Southeastern Pampa Plain of Argentina. Water samples (lakes, streams, spring water and groundwater) for hydrochemical and stable isotopic determination were collected and the main physical–chemical parameters were measured. The combination of stable isotope data with hydrogeochemical techniques was used for the identification of sources and preferential recharge areas to these aquatic ecosystems which allowed the explanation of the lake water origin. The hydrochemical processes which explain Los Padres Lake water chemistry are evaporation from groundwater, CO₂ input, calcite dissolution, Na⁺ release by Ca²⁺ and Mg²⁺ exchange, and sulfate reduction. The model that best aligns with La Brava Lake hydrochemical constraints includes: mixing, CO₂ and calcite dissolution, cationic exchange with Na⁺ release and Mg²⁺ adsorption, and to a lesser extent, Ca/Na exchange. This model suggests that the fractured aquifer contribution to this water body is greater than 50 %. An isotopic-specific fingerprint for each lake was identified, finding a higher evaporation rate for La Brava Lake compared to Los Padres Lake. Isotopic data demonstrate the importance of these shallow lakes as recharge areas to the regional aquifer, becoming areas of high groundwater vulnerability. The Tandilia Range System, considered in many hydrogeological studies as the impermeable bedrock of the Pampean aquifer, acts as a fissured aquifer in this area, contributing to low salinity waters and with a fingerprint similar to groundwater isotopic composition.