Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.     

遥感技术在煤炭地质中的应用现状及前景

介绍了遥感技术在煤炭资源调查和评价、煤矿区地质灾害调查和评估、生态环境及污染调查评价和监测以及煤矿三维可视化仿真规划系统建设方面的应用研究现状及所取得的主要成果，并结合遥感技术的发展方向，展望了其在煤炭地质中的应用前景。     

Comparison of magnetic parameters with vehicular Br levels in urban roadside soils

Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg⁻¹ and a range of 2.4–8.7 mg kg⁻¹. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg⁻¹. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ _LF), susceptibility of anhysteretic remanent magnetization (χ _ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils.     

Interpreting tracer breakthrough tailing in a conduit-dominated karstic aquifer

Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at     

REE characteristics of the Fanshan alunite deposit in Zhejiang Province, China

1 Introduction Alunite [KAl3(SO4)2(OH)6] is a very important non-ferrous metal resource, so many countries throughout the world have made great investments in research on the mechanism of its formation, its geological characteristics and applications. O…     

工程测量平面坐标系统的建立

本文讨论了地面长度投影到参考椭球面及椭球面长度投影到高斯平面所引起的长度变形,并结合实例给出了几种平面直角坐标系统的实现方法,对解决平面控制测量中的投影变形问题有很好的指导意义.     

PKI数字证书在WEB系统中的安全应用

本文主要对加密和身份认证技术进行了简要分析,并就如何利用证书解决WEB应用中 的信息对传输的保密性、完整性和不可否认性以及用户身份认证问题提出了安全解决 方案。     

基于GIS的城镇土地定级信息系统建模方法探讨

基于GIS的城镇土地定级信息系统在建设过程中,定级方法确定、定级单元大小确定和定级因素/子权重值的生成是关键,且三者都具有不同的确定方法,因此选择什么样的方法决定了系统建立的优劣。本文着重归纳、总结了城镇土地定级信息系统定级方法,通过对比分析,探讨了最优定级方法、最优网格单元大小划分方法和最优因素/子权重值计算方法。