Hillslope soil water flowpaths and the dynamics of roadside soil cation pools influenced by road deicers

Over the past 60 years, road deicers (i.e. road salt) have been applied to roadways in high latitudes to improve road conditions in winter weather. However, the dissolution of road deicers in highway runoff creates waters with high concentrations of sodium, which can mobilize soil metals via soil cation‐exchange reactions. While several studies have detailed the interactions of road salt‐rich solutions and surface and ground waters, less attention has been given to how local hydrologic flowpaths can impact the delivery of these solutions to near‐road soils. Between 2013 and 2014, soil water samples were collected from a roadside transect of lysimeter nests in Pittsburgh, Pennsylvania (USA). Soil water samples were analysed for metal concentrations and resulting data used to examine cation dynamics. While patterns in soil water calcium and magnesium concentrations follow patterns in soil water sodium concentrations, additional processes influence patterns in soil water potassium concentrations. Specifically, we observe the highest calcium and magnesium concentrations in the deepest lysimeters, suggesting divalent cations are mobilized to, and potentially accumulate in, deeper soil horizons. In contrast, soil water potassium concentrations do not follow this pattern. Additionally, in all examined elements (Ca, Mg, K, Na, and Cl), the timing of concentration peaks appears be influenced by a combination of both distance from the roadside and sampling depth. These relationships not only suggest that multiple soil water flowpaths interact with our study transect but also confirm that road salt plumes persist and migrate following the road salting season. Characterizing the interactions of sodium‐rich solutions and roadside soil cation pools clarifies our understanding of metal dynamics in the roadside environment. A deeper understanding of these processes is necessary to effectively restore and manage watersheds as high total dissolved solid solutions (e.g. road deicing melt, unconventional natural gas brines, and marginal irrigation water) continue to influence hydrological systems. Copyright © 2016 John Wiley & Sons, Ltd.     

The distribution of stably trapped magnetospheric plasma as determined from Pi2 micropulsations and the auroral electrojet index, AE

The distribution of stably trapped plasma is determined as a function of equatorial geocentric distance, R. Observed Pi2 micropulsation periods and the magnitudes of their associated magnetic bays, measured by the auroral electrojet index, AE, are used in determining this distribution. Plasma density is found to vary inversely as approximately the sixth power of R. When Pi2 period-AE relations are studied for varying time lags, the pulsation periods are found to define prolonged intervals of abnormal AE levels. Thus the periods may be potentially useful in forecasting geomagnetic disturbances or abnormally quiet intervals. A qualitative physical model is proposed to explain the observational relations.     

Die Messung des luftelektrischen Feldes mit radioaktiven Potentialsonden

Zusammenfassung Auf Grund der Tatsache, daß das Prinzip der radioaktiven Potentialsonde infolge des begrenzten Isolationswiderstandes in der Praxis nicht erfüllt ist, werden die sich aus den Änderungen der Isolation, Luftbewegung und Aktivität des -Strahlers ergebenden abweichenden Meßergebnisse diskutiert.

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Summary Starting from the fact that, on account of the limited resistance of isolation, the principle of the radioactive potential sonde is not fully valid when applied in practice, the errors of measurement caused by variations of isolation, air movement and activity of the -radiator are discussed.

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Résumé Partant du fait que le principe de la sonde potentielle radio-active n'est pas réalisé en pratique à cause de la résistance limitée d'isolation, on discute l'inexactitude des résultats de mesures provenant des modifications de l'isolation, du mouvement de l'air et de l'activité du radiateur .

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Mit 15 Textabbildungen.     

Inferring protoliths of high-grade metamorphic gneisses of the Erzgebirge using zirconology,geochemistry and comparison with lower-grade rocks from Lusatia (Saxothuringia,Germany)

Protoliths of highly metamorphosed gneisses from the Erzgebirge are deduced from the morphology, age and chemistry of zircons as well as from whole rock geochemistry and are compared with lower-grade rocks of Lusatia. Gneisses with similar structural appearance and/or geochemical pattern may have quite different protoliths. The oldest rocks in the Erzgebirge are paragneisses representing meta-greywackes and meta-conglomerates. The youngest group of zircon of meta-greywackes that did not undergo Pb loss represents the youngest igneous component for source rocks (about 575 Ma). Similar ages and zircon morphology reflect the subordinate formation of new zircon grains or only zircon rims in the augengneiss from Bärenstein and Wolkenstein, which probably represent metamorphic equivalents to Lower Cambrian two-mica granodiorites from Lusatia. Bulk rock chemistry, intense fracturing and high U and Th concentrations of zircons suggest deformation-induced and fluid-enhanced recrystallisation of zircon grains. Temperatures during tectonic overprinting—too low to reset zircon ages—indicate mid- or upper crustal levels for shearing recorded in these augengneisses. Lower Cambrian (~540 Ma) granodiorites are widespread in Lusatia but are exclusively represented by the Freiberg gneiss dome in the Eastern Erzgebirge. Ordovician protolith ages were recorded by zircons from the augengneisses of the Reitzenhain–Catherine dome and the Schwarzenberg dome (Western Erzgebirge) documenting significant regional differences between the eastern and the western Erzgebirge (~540 vs. ~490 Ma). In the Western Erzgebirge, most meta-volcanic rocks (muscovite gneisses) and meta-granites (mainly red augengneisses) yield Ordovician zircon ages, whereas in the Eastern part, similar rocks mainly recorded Lower Cambrian protolith ages. Zircon overprinting was highest within discrete tectonic zones where the combination of fluid infiltration and deformation induced variable degrees of recrystallisation and formation of a new augengneiss structure. Variable degrees of Pb loss caused age shifts that do not correspond to changes in zircon morphology but may be associated with U and Th enrichments. Major changes in bulk rock composition appear to be restricted to discrete zones and to (U)HP nappes, whereas gneisses with a MP–MT metamorphic overprint basically show no geochemical modifications.     

Estimation of the needed accuracy for the calibration of the VIRGO interferometer in relation to the detection of coalescing binaries

In this paper we report a study – based on simulated data – performed to assess the level of accuracy needed in the process of calibrating the output of the VIRGO gravitational wave detector. A simple algorithm searching for signals from coalescing binaries is applied on data containing simulated signals and noise. Two kinds of calibration errors are then assumed to affect the data. The sensitivity of the algorithm to these errors is evaluated, both in terms of the signal-to-noise ratio and the estimation of the signal arrival time.     

Assessing climatic exposure of grassland-based livestock systems with seasonal-scale indicators

Research aiming to reduce the vulnerability of agricultural systems to climate variability and change requires practical appraisal of their climatic exposure. We propose a method to map local climatic conditions over a given period to a set of productivity and management-related indicators that are specific to grassland-based livestock systems. Our method based on a reference system balances herbage production and feed requirements over a long period (≥ 30 years) and provides boundaries for productivity-defined seasons and indicators for surplus or shortage of herbage at seasonal and annual scales. This exposure-assessment method was applied to five climatically contrasting locations in south-western France. The trends and variability of the exposure indicators were analysed for past (1980–2010) and future (2035–2065) periods, considering the A1B scenario of the IPCC. Despite high year-to-year variability and the heterogeneity of the climatic situations studied, we show that climate change can modify the boundaries of productivity-defined seasons and seasonal herbage surplus or shortage. Moreover, the exposure indicators succeed in detecting climate-induced changes and distinguishing situations where a classical exposure indicator, such as annual forage production, could not. The exposure indicators highlight the forage productivity and the timing of production associated with local climatic conditions. These features fit the temporal scale at which farmers consider farm management and are highly suitable for identifying adaptation strategies that reduce the vulnerability of grassland-based livestock systems.     

Assessing Mix Layer Amplitude in 3D Decelerating Interface Experiments

We present data from recent high-energy-density laboratory experiments designed to explore the Rayleigh–Taylor instability under conditions relevant to supernovae. The Omega laser is used to create a blast wave structure that is similar to that of the explosion phase of a core-collapse supernova. An unstable interface is shocked and then decelerated by the planar blast wave, producing Rayleigh–Taylor growth. Recent experiments were performed using dual, side-on, x-ray radiography to observe a 3D “egg crate” mode and an imposed, longer-wavelength, sinusoidal mode as a seed perturbation. This paper explores the method of data analysis and accurately estimating the position of important features in the data.     

Improved provenance tracing of Asian dust sources using rare earth elements and selected trace elements for palaeomonsoon studies on the eastern Tibetan Plateau

The Asian Monsoon forms an important part of the earth’s climate system, yet our understanding of the past interactions between its different sub-systems, the East Asian and Indian monsoons, and between monsoonal winds and other prevailing wind currents such as the Westerly jet, is limited, particularly in central Asia. This in turn affects our ability to develop climate models capable of accurately predicting future changes in atmospheric circulation patterns and monsoon intensities in Asia. Provenance studies of mineral dust deposited in terrestrial settings such as peat bogs can address this problem directly, by offering the possibility to examine past deposition rates and wind direction, and hence reconstruct past atmospheric circulation patterns. However, such studies are challenged by several issues, most importantly the identification of proxies that unambiguously distinguish between the different potential dust sources and that are independent of particle size. In addition, a single analytical method that is suitable for sample preparation of both dust source (i.e. desert sand, soil) and receptor (i.e. dust archive such as peat or soil profiles) material is desirable in order to minimize error propagation derived from the experimental and analytical work. Here, an improved geochemical framework of provenance tracers to study atmospheric circulation patterns and palaeomonsoon variability in central Asia is provided, by combining for the first time mineralogical as well as major and trace elemental (Sc, Y, Th and the rare earth elements) information on Chinese (central Chinese loess plateau, northern Qaidam basin and Taklamakan, Badain Juran and Tengger deserts), Indian (Thar desert) and Tibetan (eastern Qinghai-Tibetan Plateau) dust sources.Quartz, feldspars and clay minerals are the major constituents of all studied sources, with highly variable calcite contents reflected in the CaO concentrations. Chinese and Tibetan dust sources are enriched in middle REE relative to the upper continental crust and average shale but the Thar desert has a REE signature distinctly different from all other dust sources. There are significant differences in major, trace and REE compositions between the coarse and fine fractions of the surface sands, with the finest <4 μm fraction enriched in Al₂O₃, Fe₂O₃, MnO, MgO and K₂O and the <32 μm fractions in Sc, Y, Th and the REE relative to the coarse fractions. The <4 μm fraction best represents the bulk REE geochemistry of the samples. The provenance tracers Y/∑REE, La/Er, La/Gd, Gd/Er, La/Yb, Y/Tb, Y/La, Y/Nd and to a certain extent the europium anomaly Eu/Eu^∗ (all REE normalized to post-Archean Australian shale, PAAS) are particle size-independent tracers, of which combinations of Y/∑REE, La/Yb, Y/Tb, Y/La and Eu/Eu^∗ can be used to distinguish the Thar desert, the Chinese deserts, the Chinese loess plateau and the Tibetan soils. Their independence upon grain size means that these tracers can be applied to the long-range provenance tracing of Asian dust even when only bulk samples are available in the source region. Combinations of La/Th, Y/Tb, Y/∑REE, Sc/La and Y/Er distinguish the Tibetan soils from the Chinese loess plateau and the Chinese deserts. La/Th and notably Th/∑REE isolate the signature of the Badain Juran desert and the combination of Sc/La and Y/Er that of the Taklamakan desert. The similarity in all trace and REE-based provenance tracers between the northern Qaidam basin and Tengger desert suggests that these two deposits may have a common aeolian source.     

Late Cenozoic tectonic activity and its significance in the Northern Junggar Basin,Northwestern China

The Dingshan area located in the northern part of the Junggar Basin of northwestern China is a significant prospect area for sandstone-type uranium deposits in China, where mainly Cenozoic rocks were deposited. The Cenozoic strata can be divided into four units according to the prior data and our own field observation. Sedimentary studies indicate that most Cenozoic strata were deposited under a hot and arid climate in a continental environment. The sedimentary facies are alluvial-fan, meandering-fluvial, and fluvio-lacustrine. Field investigation and interpretation of satellite images suggest that Cenozoic tectonics in the area is characterized by reactivation of early deep-seated thrusts, resulting in extensional fractures and formation of many small depressions in the shallow crustal level. Measurement of joint orientations suggests that regional shortening direction trends in north–south in the middle Pleistocene as indicated by the ESR (Electronic Spin Resonance) age of 0.1–0.4 Ma obtained from fault gouge and gypsum deposits. A four-stage sedimentation-tectonic evolution model of the northern Junggar Basin during the Late Cenozoic can be established based on reconstruction of sedimentary filling processes and Cenozoic tectonic movements. We suggest that landform evolution and groundwater movement are controlled by active tectonics, indicating that Late Cenozoic tectonic activities may also play important roles in the formation of sandstone-type uranium deposits. Therefore, a new metallogenic model for sandstone-type uranium deposits is proposed.