Anomalous archaeomagnetic directions and site formation processes at archaeological sites in Israel

As part of a program to investigate archaeomagnetic secular variation in Israel and implications for archaeomagnetic dating, we have identified “anomalous” results that have yielded information about site formation processes. Stereonets, vector demagnetization diagrams, and sample location maps are most useful in examining stability of magnetization and consistency of archaeomagnetic directions with each other and with what would be expected from normal secular variation. A collection of examples is presented, including: strong and hard remanence due to vitrification, unstable magnetization due to lightning strikes, superimposed thermal magnetizations, chemical remagnetization, magnetization of a hearth fragment before falling, magnetization of a hot brick after falling, and mechanical deformation of an archaeomagnetic feature. © 1999 John Wiley & Sons, Inc.     

Stable Sulfur Isotopic Evidence for Historical Changes of Sulfur Cycling in Estuarine Sediments from Northern Florida

Data on abundance and isotopic composition of porewater and sedimentary sulfur species are reported for relatively uncontaminated and highly contaminated fine-grained anoxic sediments of St. Andrew Bay, Florida. A strong contrast in amount and composition of sedimentary organic matter at the two sites allows a comparative study of the historical effects of increased organic loading on sulfur cycling and sulfur isotopic fractionation. In the contaminated sediments, an increase in organic loading caused increased sedimentary carbon/sulfur ratios and resulted in higher rates of bacterial sulfate reduction, but a lower efficiency of sulfide oxidation. These differences are well reflected in the isotopic composition of dissolved sulfate, sulfide, and sedimentary pyrite. Concentration and isotopic profiles of dissolved sulfate, organic carbon, and total sulfur suggest that the anaerobic decomposition of organic matter is most active in the upper 8cm but proceeds at very slow rates below this depth. The rapid formation of more than 90% of pyrite in the uppermost 2 cm which corresponds to about 3 years of sediment deposition allows the use of pyrite isotopic composition for tracing changing diagenetic conditions. Sediment profiles of the sulfur isotopic composition of pyrite reflect present-day higher rates of bacterial sulfate reduction and lower rates of sulfide oxidation, and record a profound change in the diagenetic cycling of sulfur in the contaminated sediments coincident with urban and industrial development of the St. Andrew Bay area.     

Results from regional vibroseis profiling: Appalachian ultra-deep core hole site study

Summary. In 1985, 180 km of regional vibroseis profiles were acquired in the Carolinas and Georgia, southeastern United States, as part of the Appalachian Ultra-Deep Core Hole (ADCOH) Site Study. The data quality is excellent, with large-amplitude reflections from faults and crystalline rocks, lower Palaeozoic shelf strata and from within autochthonous Grenville basement. The profiles image the subsurface more clearly than other available data and allow the possibility of alternative interpretations of important elements of the tectonic framework of the southern Appalachians.
The major points in the interpretation are: 1) The Blue Ridge master decollement is at a depth of 2-3 km beneath the Blue Ridge. This thrust increases in dip just NW of the Brevard fault zone. 2) The Brevard fault zone appears to splay from the master decollement at 6 km (2.2 s) near Westminster, S.C., and defines the base of the crystalline Inner Piedmont allochthon. 3) Below the Blue Ridge thrust sheet are images of duplex and imbricate structures ("duplex tuning wedges") connected by other thrust faults that duplicate shelf strata to a thickness of 4–5 km. 4) Subhorizontal reflections from depths of 6 to 9 km may be from relatively undisturbed lower Palaeozoic strata as suggested by others. 5) Eocambrian-Cambrian(?) rift basins in the Grenville basement are also imaged.
The ADCOH data were originally recorded with 14–56 Hz bandwidth and 8 s length, but an extended Vibroseis correlation was used to produce 17 s data length revealing reflections from within the upper crust. Below 8 s, reflections from within the Grenville basement become weak, but are observable as late as 13 s; however, these Moho (?) reflections are generally short segments.     

Absolute calibration of a photoelectric condensation nucleus counter at low values of nucleus concentration

Summary A new absolute condensation nucleus counter was constructed to investigate the accuracy of the calibration widely used with the Pollak-Nolan photoelectric condensation nucleus counter. An attempt was made to standardize the conditions affecting calibration and, using the new counter, to recalibrate the photoelectric counter at values of extinction less than 16%.Over this extinction range, the present work indicates nucleus concentrations which are higher by about 30% than those given by the calibration ofPollak andMetnieks [8]³). In view of the great natural variability of Aitken nucleus concentrations, this discrepancy, if real, is of little meteorological importance.     

A Gibbs–Pitzer function for high-salinity seawater thermodynamics

A high-salinity Gibbs function for seawater is derived from Pitzer equations of the sea salt components, in conjunction with the 2003 Gibbs function of seawater for low salinities. Various properties, computed from both formulations by thermodynamic rules, are compared with each other, and with high-salinity measurements. The new Gibbs–Pitzer function presented in this paper is valid in the range 0–110 g kg⁻¹ in absolute salinity, −7 to +25 °C in temperature, and 0–100 MPa in applied pressure. The formulation is expressed in the International Temperature Scale 1990 (ITS-90), and is consistent with the International Standard for Fluid Water (IAPWS-95), and with the 2005/2006 equations of state of ice Ih.     

Al speciation in tropical podzols of the upper Amazon Basin: A solid-state Al MAS and MQMAS NMR study

In the upper Amazon Basin, aluminum previously accumulated in lateritic formations is massively remobilised in soils by podzolization and exported in waters. We have investigated the speciation of aluminum in the clay-size fractions of eight horizons of waterlogged podzols lying in a depression of a plateau. The horizons illustrate the main steps involved in the podzolization of laterites. They belong to eluviated topsoil A horizons and illuviated subsoil Bhs, Bh and 2BCs horizons of weakly and better-expressed podzols located at the margin and centre of the depression. For the first time, aluminum speciation is quantitatively assessed in soils by spectroscopic methods, namely FTIR, ²⁷Al magic angle spinning (MAS) and multiple-quantum magic angle spinning (MQMAS), nuclear magnetic resonance (NMR). The results thus obtained are compared to chemical extraction data.Solid-state ²⁷Al MAS NMR spectra enable to distinguish Al bound to organic compounds from that incorporated in secondary mineral phases detected by FTIR. MQMAS experiments additionally show that both chemical shifts and quadrupolar constants are distributed for Al nuclei linked with organic compounds. Similar amounts of chelated Al are obtained from NMR spectra and chemical extractions. The study enables to highlight three major steps in the fate of aluminum. (i) Aluminum is first released by mineral weathering, feeds complexing sites of organic matter and accumulates in subsurface Bhs horizons of weakly expressed podzols (acidocomplexolysis). (ii) Complexes of aluminum with organic matter (Al-OM) then migrate downwards in sandy horizons of better-expressed podzols and accumulate at depth in less permeable 2BCs horizons. (iii) The minor amounts of aluminum present in the 2BCs horizon of the downslope podzol show that aluminum is eventually exported towards the river network, either complexed with organic matter or as Al³⁺ ions after desorption from organic compounds, due to decreasing pH or biodegradation of organic ligands. The direct spectroscopic determination of Al-speciation during the formation of podzolic soils opens new perspectives to trace metal loads in the rivers of the upper Amazon Basin.     

High resolution simulation of recent Arctic and Antarctic stratospheric chemical ozone loss compared to observations

Simulations of polar ozone losses were performed using the three-dimensional high-resolution (1^∘ × 1^∘) chemical transport model MIMOSA-CHIM. Three Arctic winters 1999–2000, 2001–2002, 2002–2003 and three Antarctic winters 2001, 2002, and 2003 were considered for the study. The cumulative ozone loss in the Arctic winter 2002–2003 reached around 35% at 475 K inside the vortex, as compared to more than 60% in 1999–2000. During 1999–2000, denitrification induces a maximum of about 23% extra ozone loss at 475 K as compared to 17% in 2002–2003. Unlike these two colder Arctic winters, the 2001–2002 Arctic was warmer and did not experience much ozone loss. Sensitivity tests showed that the chosen resolution of 1^∘ × 1^∘ provides a better evaluation of ozone loss at the edge of the polar vortex in high solar zenith angle conditions. The simulation results for ozone, ClO, HNO₃, N₂O, and NO _y for winters 1999–2000 and 2002–2003 were compared with measurements on board ER-2 and Geophysica aircraft respectively. Sensitivity tests showed that increasing heating rates calculated by the model by 50% and doubling the PSC (Polar Stratospheric Clouds) particle density (from 5 × 10⁻³ to 10⁻² cm⁻³) refines the agreement with in situ ozone, N₂O and NO _y levels. In this configuration, simulated ClO levels are increased and are in better agreement with observations in January but are overestimated by about 20% in March. The use of the Burkholder et al. (1990) Cl₂O₂ absorption cross-sections slightly increases further ClO levels especially in high solar zenith angle conditions. Comparisons of the modelled ozone values with ozonesonde measurement in the Antarctic winter 2003 and with Polar Ozone and Aerosol Measurement III (POAM III) measurements in the Antarctic winters 2001 and 2002, shows that the simulations underestimate the ozone loss rate at the end of the ozone destruction period. A slightly better agreement is obtained with the use of Burkholder et al. (1990) Cl₂O₂ absorption cross-sections.     

Modeling aqueous ferrous iron chemistry at low temperatures with application to Mars

Major uncertainties exist with respect to the aqueous geochemical evolution of the Martian surface. Considering the prevailing cryogenic climates and the abundance of salts and iron minerals on Mars, any attempt at comprehensive modeling of Martian aqueous chemistry should include iron chemistry and be valid at low temperatures and high solution concentrations. The objectives of this paper were to (1) estimate ferrous iron Pitzer-equation parameters and iron mineral solubility products at low temperatures (from < 0 °C to 25 °C), (2) incorporate these parameters and solubility products into the FREZCHEM model, and (3) use the model to simulate the surficial aqueous geochemical evolution of Mars.Ferrous iron Pitzer-equation parameters were derived in this work or taken from the literature. Six new iron minerals [FeCl₂·4H₂O, FeCl₂·6H₂O, FeSO₄·H₂O, FeSO₄·7H₂O, FeCO₃, and Fe(OH)₃] were added to the FREZCHEM model bringing the total solid phases to 56. Agreement between model predictions and experimental data are fair to excellent for the ferrous systems: Fe-Cl, Fe-SO₄, Fe-HCO₃, H-Fe-Cl, and H-Fe-SO₄.We quantified a conceptual model for the aqueous geochemical evolution of the Martian surface. The five stages of the conceptual model are: (1) carbonic acid weathering of primary ferromagnesian minerals to form an initial magnesium-iron-bicarbonate-rich solution; (2) evaporation and precipitation of carbonates, including siderite (FeCO₃), with evolution of the brine to a concentrated NaCl solution; (3) ferrous/ferric iron oxidation; (4) either evaporation or freezing of the brine to dryness; and (5) surface acidification.What began as a dilute Mg-Fe-HCO₃ dominated leachate representing ferromagnesian weathering evolved into an Earth-like seawater composition dominated by NaCl, and finally into a hypersaline Mg-Na-SO₄-Cl brine. Weathering appears to have taken place initially under conditions that allowed solution of ferrous iron [low O₂(g)], but later caused oxidation of iron [high O₂(g)]. Surface acidification and/or sediment burial can account for the minor amounts of Martian surface carbonates. This model rests on a large number of assumptions and is therefore speculative. Nevertheless, the model is consistent with current understanding concerning surficial salts and minerals based on Martian meteorites, Mars lander data, and remotely-sensed spectral analyses.     

High resolution seismic imaging of faults beneath Limón Bay, northern Panama Canal, Republic of Panama

High-resolution seismic reflection profiles from Limón Bay, Republic of Panama, were acquired as part of a seismic hazard investigation of the northern Panama Canal region. The seismic profiles image gently west and northwest dipping strata of upper Miocene Gatún Formation, unconformably overlain by a thin (<20 m) sequence of Holocene muds. Numerous faults, which have northeast trends where they can be correlated between seismic profiles, break the upper Miocene strata. Some of the faults have normal displacement, but on many faults, the amount and type of displacement cannot be determined. The age of displacement is constrained to be Late Miocene or younger, and regional geologic considerations suggest Pliocene movement. The faults may be part of a more extensive set of north- to northeast-trending faults and fractures in the canal region of central Panama. Low topography and the faults in the canal area may be the result of the modern regional stress field, bending of the Isthmus of Panama, shearing in eastern Panama, or minor deformation of the Panama Block above the Caribbean subduction zone. For seismic hazard analysis of the northern canal area, these faults led us to include a source zone of shallow faults proximal to northern canal facilities.