Distribution and chronology of Pleistocene permafrost features in France: Database and first results

Numerous periglacial features (polygons, nets, soil stripes, ice‐wedge pseudomorphs and sand‐wedge casts, involutions) have been recorded in France by examining bibliographical sources and aerial photographs. These data show that a large part of France was affected by permafrost during the Pleistocene and only the southern Aquitaine Basin and Languedoc seem to have been beyond its maximum extent. The first OSL ages obtained from the aeolian infill of wedge structures indicate that at least two phases of thermal contraction cracking occurred in southwestern France between ～25 and 36 ka. Chronostratigraphical data from loess in northern France indicate that these episodes correspond to the formation of ice‐wedge networks associated with tundra gleys. In the latter region, two additional permafrost episodes probably occurred during the Last Glacial, the older one corresponding to the end of Marine Isotope Stage (MIS) 4 around 60 ka and the more recent one to MIS 2 around 19–16 ka. Although stratigraphical data indicate that these episodes were relatively short (about one millennium), relict permafrost may have existed for longer periods in northern France.     

The impact of climate changes during the Holocene on vegetation in northern French Guiana

The impact of climatic changes that occurred during the last glacial maximum and the Holocene on vegetation changes in the Amazon Basin and the Guiana Shield are still widely debated. The aim of our study was to investigate whether major changes in vegetation (i.e. transitions between rainforests and C₄ savannas) occurred in northern French Guiana during the Holocene. We measured variations in the δ¹³C of soil organic matter at eight sites now occupied by forest or savannah. The forest sites were selected to cover two regions (forest refugia and peneplains) which are thought to have experienced different intensities of disturbance during the latest Pleistocene and the Holocene. We found that none of the forest sites underwent major disturbances during the Holocene, i.e. they were not replaced by C₄ savannahs or C₄ forest savannahs for long periods. Our results thus suggest that tropical rainforests in northern French Guiana were resilient to drier climatic conditions during the Holocene. Nevertheless, geographical and vertical variations in the ¹³C of SOM were compatible with minor changes in vegetation, variations in soil processes or in soil physical properties.     

Coral skeletal delta(15)N reveals isotopic traces of an agricultural revolution

This study introduces a new method of tracing the history of nutrient loading in coastal oceans via delta(15)N analysis of organic nitrogen preserved in the skeleton of the massive Porites coral. Four coral cores were collected in Bali, Indonesia, from reefs exposed to high levels of fertilizers in agricultural run-off, from lagoonal corals impacted by sewage, and from a reef located 30 km offshore. Skeletal delta(15)N in the agriculturally exposed coral declined from 10.7+/-0.4 per thousand in 1970-1971, when synthetic fertilizers (-0.8 per thousand+/-0.2 per thousand) were introduced to Bali, to a depleted "anthropogenic" baseline of 3.5 per thousand+/-0.4% in the mid-1990s. delta(15)N values were negatively correlated with rainfall, suggesting that marine delta(15)N lowers during flood-bourn influxes of waste fertilizers. Reef cores exposed to untreated sewage in terrestrial discharge were enriched (7.8 and 7.3+/-0.4 per thousand), while the offshore core reflected background oceanic signals (6.2+/-0.4 per thousand). delta(15)N, N concentration, and C:N systematics indicate that the N isotopic composition of skeletal organic matter was generally well preserved over 30 years. We suggest that skeletal organic delta(15)N can serve as a recorder of past nitrogen sources. In Bali, this tracer suggests that the intensification of Western style agricultural practices since 1970 are contributing to the degradation of coastal coral reefs.     

Simultaneous and Sensitive HPLC Determination of Mono‐ and Disaccharides,Uronic Acids,and Amino Sugars after Derivatization by Reductive Amination

The reductive amination of low‐molecular‐weight saccharides, uronic acids, and amino sugars, followed by a separation of the derivates by means of ion‐pair chromatography or RP‐HPLC, offers an interesting alternative to HPAEC‐PAD for the environmental analysis of these compounds. Under this aspect various potential amination reagents, i.e., p‐amino‐benzoic acid (p‐AMBA), p‐AMBA propyl ester, 1‐aminopyrene, 2‐(2‐aminophenyl)indole, and 4‐aminoazobenzene, were tested with regard to the formation of derivates and to the chromatographic properties of the formed derivates. p‐AMBA, p‐AMBA propyl ester and 4‐aminoazobenzene proved to be especially suited, because they facilitate the amination of all carbohydrate reference components together with a complete separation and sensible detection (detection limits < 0.5 mg/L) of the derivates. Mainly the following elution sequence was ascertained: amino sugars (hexosamines) / disaccharide(s) / monosaccharides (hexoses) / hexuronic acid(s) / N‐acetyl‐D‐glucosamine. Detection limits down to 0.1 μmol/L were realized using p‐AMBA as reagent, facilitating the determination of the target compounds in landfill leachates and lysimeter percolates. Applying the p‐AMBA propyl ester for derivatization, chromatographic interferences with weakly retained derivates and the coelution of the reagent with its galactosamine derivate can be avoided, since the ester elutes after its derivates unlike p‐AMBA itself.     

Low signal-to-noise event detection based on waveform stacking and cross-correlation: application to a stimulation experiment

We study the microseismicity (M _L ?<?2) in the region of Landau, SW Germany. Here, due to thick sediments (~3?km) and high cultural seismic noise, the signal-to-noise ratio is in general very low for microearthquakes. To gain new insights into the occurrence of very small seismic events, we apply a three-step detection approach and are able to identify 207 microseismic events (?1?<?M _L ?<?~1) with signal-to-noise ratios smaller than 3. Recordings from a temporary broadband network are used with station distances of approximately 10?km. First, we apply a short-term to long-term average detection algorithm for data reduction. The detection algorithm is affected severely by transient noise signals. Therefore, the most promising detections, selected by coinciding triggers and high-amplitude measures, are reviewed manually. Thirteen seismic events are identified in this way. Finally, we conduct a cross-correlation analysis. As master template, we use the stacked waveforms of five manually detected seismic events with a repeating waveform. This search reveals additional 194 events with a cross-correlation coefficient exceeding 0.65 which ensures a stable identification. Our analysis shows that the repeating events occurred during the stimulation of a geothermal reservoir within a source region of only about 0.5?km³. Natural background seismicity exceeding our detection level of M _L ?~?0.7 is not found in the region of Landau by our analysis.     

New igneous zircon Pb/Pb and metamorphic Rb/Sr ages in the Yaounde Group (Cameroon, Central Africa): implications for the Central African fold belt evolution close to the Congo Craton

Three meta-igneous bodies from the Yaounde Group have been analyzed for their petrography, geochemistry, and ²⁰⁷Pb/²⁰⁶Pb zircon ages. According to their geochemical patterns, they represent meta-diorites. The meta-plutonites yielded identical zircon ages with a mean of 624?±?2?Ma interpreted as their intrusion age. This age is in agreement with previously published zircon ages of meta-diorites from the Yaounde Group. The meta-diorites derived mainly from crustal rocks with minor contribution from mantle material. The ⁸⁷Rb/⁸⁶Sr isochron ages of one meta-diorite sample and three meta-sedimentary host rocks are significantly younger than the obtained intrusion age. Therefore, they are not related to igneous processes. ⁸⁷Rb/⁸⁶Sr isochron ages differ from sample to sample (599?±?3, 572?±?4, 554?±?5, 540?±?5?Ma) yielding the oldest Neoproterozoic age (~600?Ma) for a paragneiss sample at a more northern location. The youngest Rb/Sr isochron age (~540?Ma) was obtained for a mica schist sample at a more southern location closer to the border of the Congo Craton. The ⁸⁷Rb/⁸⁶Sr whole rock-biotite ages are interpreted as cooling ages related to transpressional processes during exhumation. Therefore, several discrete metamorphic events related to the exhumation of the Yaounde Group were dated. It could be shown by Rb/Sr dating for the first time that these late tectonic processes occurred earlier at more distant northern locations of the Yaounde Group and lasted at least until early Cambrian (~540?Ma) more closely to the border of the Congo Craton.     

Magmatische und metasomatische Prozesse in Graniten,insbesondere Zweiglimmergraniten

Ohne Zusammenfassung     

Equal-mobility bed load transport in a small, step-pool channel in the Ouachita Mountains

Equal-mobility transport (EMT) of bed load is more evident than size-selective transport during near-bankfull flow events in a small, step-pool channel in the Ouachita Mountains of central Arkansas. Bed load transport modes were studied by simulating five separate runoff events with peak discharges between 0.25 and 1.34 m³/s (1.0- to 1.6-year recurrence intervals) in a natural channel using controlled releases from a storage tank. EMT occurrence was investigated using four different bed load relationships suggested by previous research. With each of these approaches, the relationship of a given bed load characteristic (D_max, distribution percentile, displacement distance and skewness) to some independent factor (τ_c*, τ and grain size) was assessed to determine which transport mode was evident. Regression models derived using combinations of these four relationships with different datasets provide seven separate tests. Five of the seven tests indicate that EMT occurred or was predominant. Several reasons may explain the apparent contradictory results, but the confounding effects of changes in the structural arrangements of bed material prior to or during the events seem particularly important.     

Interference processes on scouring at bed sills

The local scouring downstream of bed sills forming a sequence for bed stabilization in steep channels has been investigated in a laboratory flume. The initial bed slopes ranged from 0·078 to 0·148. The bed alluvium was characterised by a non‐uniform grain size distribution. The results show that when the ratio between the critical water depth h_c and the sill spacing L rises above a characteristic value the scouring dynamics become heavily affected by the presence of the downstream sill, associated with the onset of a form of “interference” which renders the scouring process less effective. The difference with an “undisturbed” case is demonstrated. Self‐affinity of scour holes is confirmed and the scour length appears to be the reference parameter from which the scour depth might be evaluated. Copyright © 2003 John Wiley & Sons, Ltd.